Para el sistema metanol(1)/acetato de metilo(2), las siguientes ecuaciones dan una correlación razonable para los coeficientes

ln⁡〖� _1⁡ 〗 =𝐴𝑥_2^2⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡ln⁡〖� _2⁡ 〗 =𝐴𝑥_1^2⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡𝐴=2.771−0.00523⁡�

Además, las ecuaciones de Antoine proporcionan las presiones de vapor siguientes:

ln⁡〖� _1^𝑠𝑎𝑡⁡ 〗 =16.59158−3643.31/(�−33.424)⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡⁡ln⁡〖� _2^𝑠𝑎𝑡⁡ 〗 =14.25326−2

donde T es en kelvins y las presiones de vapor están en kPa. Suponiendo la validez de la ecuación:

�_𝑖⁡�=𝑥_𝑖⁡�_𝑖⁡�_𝑖^𝑠𝑎𝑡
calcule:

a) P y {yi} para T=318.15 K

b) T y {yi} para P=101.325 kPa
n razonable para los coeficientes de actividad

⁡⁡⁡ln⁡〖� _2^𝑠𝑎𝑡⁡ 〗 =14.25326−2665.54/(�−53.424)

PARAMETROS OBTENIDOS EN
http://ddbonline.ddbst.de/AntoineCalculation/AntoineCalculationCGI.exe

http://www.echeguru.com/html_data_files/Antoine_Constants.html
 Metanol (1) Acetato de metilo (2)
T (°C)= 45 A= 8.08097 A= 4.26398
P1sat (mmHg)= 333.653169 B= 1582.27 B= 1194.58
P 2
sat
(mmHg)= 492.689247 C= 239.7 C= 223.656
A= 1.1070755

x1 x2 gamma1 gamma2 P (kPa) y1 y2

0 1 3.02549738 1 492.689247 0 1
0.05 0.95 2.71593327 1.00277152 514.660996 0.08803657 0.91196343
0.1 0.9 2.45157618 1.01113226 530.15421 0.15429023 0.84570977
0.15 0.85 2.22523393 1.02522202 540.716941 0.20596442 0.79403558
0.2 0.8 2.03100008 1.04527815 547.527765 0.24753068 0.75246932
0.25 0.75 1.86400979 1.07164218 551.473127 0.28194156 0.71805844
0.3 0.7 1.72024547 1.10476959 553.205273 0.31125807 0.68874193
0.35 0.65 1.59638133 1.14524289 553.18495 0.33699975 0.66300025
0.4 0.6 1.48965892 1.19378876 551.711899 0.36035432 0.63964568
0.45 0.55 1.39778709 1.25129972 548.945297 0.38231358 0.61768642
0.5 0.5 1.31886151 1.31886151 544.915605 0.40377108 0.59622892
0.55 0.45 1.25129972 1.39778709 539.528667 0.42560308 0.57439692
0.6 0.4 1.19378876 1.48965892 532.562414 0.44874898 0.55125102
0.65 0.35 1.14524289 1.59638133 523.656019 0.47430764 0.52569236
0.7 0.3 1.10476959 1.72024547 512.290846 0.5036727 0.4963273
0.75 0.25 1.07164218 1.86400979 497.762002 0.53874664 0.46125336
0.8 0.2 1.04527815 2.03100008 479.138673 0.5823122 0.4176878
0.85 0.15 1.02522202 2.22523393 455.210616 0.63873355 0.36126645
0.9 0.1 1.01113226 2.45157618 424.417258 0.7154062 0.2845938
0.95 0.05 1.00277152 2.71593327 384.754558 0.82610848 0.17389152
1 0 1 3.02549738 333.653169 1 0
 600

550

500
P (mmHg)

450
x1
y1

400

350

300
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1, y1
 Metanol (1)
P (mmHg)= 760 P (bar)= 1.01325 A=
T1sat (°C)= 64.5735402 T1 (K)=
sat
337.72354 B=
T 2
sat
(°C)= 56.8762009 T 2
sat
(K)= 330.026201 C=

γα
x1 x2 <T>1 (K) <A>1 <γ1>1 <γ2>1 <α>1 <P1sat>1 (mmHg)
0 1 330.026201 1.04496297 2.84329323 1 0.7328835 556.9914614942
0.05 0.95 330.411068 1.04295012 2.56321538 1.00261078 0.73470903 533.4960161183
0.1 0.9 330.795935 1.04093726 2.32369637 1.01046374 0.73653583 518.0315367663
0.15 0.85 331.180802 1.03892441 2.11831907 1.02365115 0.73836388 507.9640628518
0.2 0.8 331.565669 1.03691155 1.94181556 1.04234863 0.74019318 501.6725523715
0.25 0.75 331.950536 1.0348987 1.78984767 1.06681883 0.74202373 498.1162184898
0.3 0.7 332.335403 1.03288584 1.65883254 1.09741754 0.74385552 496.6129676464
0.35 0.65 332.72027 1.03087299 1.5458035 1.13460201 0.74568854 496.7195649374
0.4 0.6 333.105137 1.02886014 1.44829883 1.17894223 0.74752279 498.1650407884
0.45 0.55 333.490004 1.02684728 1.36427248 1.23113508 0.74935826 500.8144236436
0.5 0.5 333.874871 1.02483443 1.29202222 1.29202222 0.75119494 504.6517290738
0.55 0.45 334.259738 1.02282157 1.23013186 1.36261211 0.75303284 509.7773135083
0.6 0.4 334.644604 1.02080872 1.17742446 1.444107 0.75487193 516.4186169734
0.65 0.35 335.029471 1.01879586 1.13292467 1.53793599 0.75671221 524.9567541945
0.7 0.3 335.414338 1.01678301 1.09582825 1.64579521 0.75855369 535.975804437
0.75 0.25 335.799205 1.01477016 1.06547758 1.76969676 0.76039635 550.3490245939
0.8 0.2 336.184072 1.0127573 1.04134203 1.91202841 0.76224018 569.3906594818
0.85 0.15 336.568939 1.01074445 1.02300232 2.07562614 0.76408519 595.1333340018
0.9 0.1 336.953806 1.00873159 1.01013836 2.26386287 0.76593136 630.8653510699
0.95 0.05 337.338673 1.00671874 1.00251997 2.48075677 0.76777869 682.2579819264
1 0 337.72354 1.00470588 1 2.73110389 0.76962717 760
 Acetato de metilo (2)
8.08097 A= 4.26398
1582.27 B= 1194.58
239.7 C= 223.656

<T>2 (K) <A>2 <γ1>2 <γ2>2 <α>2 <P1sat>2 (mmHg) <T>3 (K) <A>3
330.026191 1.04496302 2.84329338 1 0.73288345 556.9914246911 330.026189 1.04496303
328.989342 1.05038574 2.58047408 1.00262942 0.72797174 528.7137483362 328.77363 1.05151392
328.285824 1.05406514 2.34853743 1.0105964 0.72464438 510.0661308212 327.916564 1.05599637
327.81831 1.05651024 2.14540564 1.02405627 0.72243563 497.8088925795 327.338787 1.05901814
327.522186 1.05805897 1.96827542 1.04323072 0.7210376 489.9646595369 326.962737 1.06098489
327.353419 1.05894162 1.81421826 1.06842313 0.72024118 485.2748921187 326.735492 1.06217338
327.281777 1.05931631 1.68045567 1.10003112 0.71990317 482.9213468022 326.620754 1.06277346
327.286863 1.0592897 1.56447437 1.1385585 0.71992717 482.3757287971 326.594088 1.06291292
327.355742 1.05892947 1.46406177 1.1846279 0.72025214 483.3163535348 326.640044 1.06267257
327.481555 1.05827147 1.37730283 1.23899426 0.72084583 485.5827713143 326.750466 1.06209506
327.662794 1.05732359 1.30255914 1.30255914 0.72170132 489.1542434322 326.923598 1.06118958
327.903084 1.05606687 1.23844126 1.37638463 0.722836 494.1456756577 327.163797 1.05993334
328.211438 1.05445418 1.18377995 1.46170491 0.72429282 500.8193463547 327.481788 1.05827025
328.603015 1.05240623 1.13759884 1.55993107 0.72614403 509.614629197 327.895489 1.05610659
329.100559 1.04980407 1.09908978 1.6726413 0.72849815 521.2023809488 328.431494 1.05330329
329.736834 1.04647636 1.06759107 1.80154198 0.73151179 536.5773982378 329.127476 1.0496633
330.55868 1.0421781 1.04256823 1.94837168 0.73540953 557.2139543637 330.035833 1.04491259
331.633929 1.03655455 1.02359657 2.11469514 0.74051776 585.3304793738 331.229146 1.03867156
333.063712 1.02907678 1.0103439 2.30147954 0.74732531 624.3470439171 332.808026 1.03041402
335.005852 1.0189194 1.00255055 2.50822355 0.75659924 679.6762462726 334.911252 1.01941415
337.72354 1.00470588 1 2.73110389 0.76962717 760 337.72354 1.00470588
<γ1>3 <γ2>3 <α>3 <P1sat>3 (mmHg) T A γ1
2.8432934086 1 0.73288345 556.9914189426 330.026189 1.04496303 2.84329341
2.5831027914 1.00263224 0.72695105 527.989320979 328.740811 1.05168556 2.58350296
2.3522141149 1.01061592 0.72289966 508.8976275133 327.861988 1.0562818 2.352758
2.1492965644 1.02411406 0.72017214 496.3657411183 327.269978 1.05937802 2.14985547
1.9719646456 1.04335282 0.71839851 488.3508479592 326.884745 1.06139278 1.9724795
1.8175192572 1.06863896 0.71732732 483.5550181885 326.651692 1.06261165 1.81796738
1.6833047821 1.10037344 0.71678665 481.1360216146 326.533405 1.06323029 1.68368163
1.5668711127 1.13906395 0.71666101 480.551095825 326.504727 1.06338028 1.56718053
1.4660359498 1.18533758 0.71687754 481.4703233222 326.549781 1.06314464 1.46628512
1.3788967955 1.23995396 0.71739789 483.7294434508 326.660202 1.06256714 1.37909372
1.3038186675 1.30381867 0.71821398 487.3073933237 326.834203 1.06165712 1.30397107
1.2394112916 1.3779954 0.71934665 492.3218603813 327.076268 1.06039112 1.23952619
1.1845029552 1.46371436 0.72084694 499.0409857124 327.397401 1.05871159 1.1845866
1.1381146276 1.56237178 0.72280012 507.9132396839 327.815931 1.05652268 1.13817264
1.0994359721 1.6755117 0.72533299 519.6218513769 328.358977 1.05368255 1.0994735
1.0678037366 1.80477442 0.72862556 535.1765443519 329.06476 1.04999131 1.06782563
1.0426822753 1.95178446 0.73292917 556.066013608 329.98605 1.04517296 1.04269313
1.023645331 2.11793214 0.7385936 584.5135096916 331.195156 1.03884933 1.02364943
1.0103574107 2.30397377 0.74610668 623.9116533842 332.790868 1.03050376 1.01035832
1.0025517857 2.50934377 0.75614681 679.5702367679 334.907361 1.0194345 1.00255184
1 2.73110389 0.76962717 760 337.72354 1.00470588 1
 337

γ2 P1sat (mmHg) y1 y2
1 556.99141894 0 1
335
1.00263267 527.989320979 0.08974092 0.91025908
1.0106188 508.89762751 0.15754118 0.84245882
1.02412235 496.36574112 0.21061472 0.78938528
1.04336985 488.35084796 0.25349001 0.74650999 333

1.06866823 483.55501819 0.28917344 0.71082656

1.10041868 481.13602161 0.31976837 0.68023163

T (K)
1.13912917 480.551095825 0.34682712 0.65317288 331
1.18542711 481.47032332 0.37156462 0.62843538
1.2400725 483.72944345 0.3949983 0.6050017
1.30397107 487.30739332 0.41804917 0.58195083 329
1.37818624 492.32186038 0.44162528 0.55837472
1.46394694 499.04098571 0.4667031 0.5332969
1.56264646 507.91323968 0.4944216 0.5055784 327
1.6758231 519.62185138 0.526207 0.473793
1.80510743 535.17654435 0.56395582 0.43604418
1.95210971 556.066013608 0.61032233 0.38967767 325
2.11820417 584.51350969 0.66919261 0.33080739 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
2.30414125 623.91165338 0.74649592 0.25350408 x1, y1
2.50938985 679.57023677 0.85163049 0.14836951
2.73110389 760 1 0
 x1
y1

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1, y1