EXPECTED TO: a.Find the amount of substances used and produced in a chemical reaction b.Find the percent yield of a reaction c. Determine the limiting reactant in a reaction STOICHIOMETRY ➢Concerned with finding the relative quantities of reactants and products in a chemical reaction ➢The guiding principle to find quantities of substances in a reaction is the law of conservation of mass which says that matter is neither created in a chemical reaction ➢The total mass of the reactants is equal to the total mass of products MOLE ➢The standard unit of measurement in chemistry for communicating how much of a substance is present ➢An amount of a substance that contains Avogadro’s number of atoms, ions, molecules, or any other chemical unit ➢1 mole has 6.02x1023 atoms, ions, molecules or any other chemical unit MOLE ➢1 mole of basketballs has 6.02x1023 basketballs ➢1 mole of ping-pong balls has 6.02x1023 ping-pong balls ➢1 mole of basket balls and 1 mole of ping-pong balls imply that there are as many balls in 1 mole of basketballs as there are balls in 1 ping-pong balls ➢But since we know that basketballs are heavier than ping- pong balls implies that 1 mole of basketball and 1 mole of ping-pong balls have vastly different masses MOLE ➢Avogadro’s number is HUGE!!! ➢1 mole of basketball = 6.02x1023 basketballs ➢That’s 602,000,000,000,000,000,000,000 basketballs! It would fill a bag the size of Earth! MOLAR MASS ➢What is the molar mass of one atom of iron? ➢Fortunately, periodic table of elements displays this information ➢The atomic mass of an element tells us the mass in grams of 1 mole of that element ➢For Fe, it is 55.85 grams per mole ➢Put differently 1 mole of Fe has a mass of 55.85 grams EXAMPLE 1. FINDING THE MOLAR MASS OF ELEMENTS Find the molar mass of the following elements. a.Ti b.N2 c. Zn d.3Zn EXAMPLE 1. FINDING THE MOLAR MASS OF ELEMENTS Solution: a. Go to the periodic table of elements and check the atomic mass of Tin. It is 47.88 grams per mole (47.88g/mol) b. How many atoms of nitrogen does N2 has? It has 2. Since the atomic mass of nitrogen is 14.01, its molar mass is 14.01g/mol. For N2 it is 14.01g N2 𝟐𝟖.𝟎𝟐𝐠 𝐍𝟐 2x = 1 mol 𝟏 𝐦𝐨𝐥 EXAMPLE 1. FINDING THE MOLAR MASS OF ELEMENTS Solution: c. The atomic mass of Zn is 65.39 grams per mole. Its molar mass is 65.39 g/mol d. There are 3 atoms of Zn in 3Zn. The molar mass of 3Zn is 65.39 g Zn 𝟏𝟑𝟎.𝟕𝟖 𝐠 𝐙𝐧 3x = 1 mol 𝟏 𝐦𝐨𝐥 EXAMPLE 2. FIND THE MASS IN GRAMS Find the mass in grams of the following substances a. 7.50 moles of aluminum b. 4.46 moles of zinc c. 5.01 moles of Cl2 EXAMPLE 2. FIND THE MASS IN GRAMS Solution We shall solve these problems using the conversion factor approach a. Molar mas of Al is 26.98 g/mol. Using the conversion factor approach, we are led to 26.98 g 7.50 mol Al x 1 mol = 7.50 x 26.98 g Al = 202.35 g Al EXAMPLE 2. FIND THE MASS IN GRAMS Solution b. Molar mass of Zn is 65.39 g/mol 65.39 g 4.46 mol Zn x 1 mol = 4.46 x 65.39 g Zn = 291.64 g Zn EXAMPLE 2. FIND THE MASS IN GRAMS Solution c. Molar mass of Cl2 is 2 x 35.45 g/mol or 70.90 g/mol. The weight in grams of 5.01 moles of Cl2 is 70.90 g 5.01 mol Cl2 x 1 mol = 5.01 x 70.90 g Cl2 = 355.21 g Cl2 EXAMPLE 3. FINDING THE MASS IN GRAMS
Find the mass in grams
of the following compounds a. 3.8 moles of Na Cl2 b. 5.4 moles C4H4 c. 7 moles of (NO2)3 EXAMPLE 3. FINDING MASS IN GRAMS Solution a. Find the molar mas of each element in the compound, then add them. We shall present our solution in table form No. of Mass per Mass per Element Multiply Atoms atom mole
Na 1 22.99 1 x 22.99 22.99
Cl2 2 35.45 2 x 35.45 70.90 Mass per mole of NaCl2 93.89 EXAMPLE 3. FINDING MASS IN GRAMS Solution a. Find the total mass in grams of 3.8 moles of NaCl2
Substance Solution Mass (g)
3.8 mol NaCl2 3.8 x 93.89 356.78
EXAMPLE 3. FINDING MASS IN GRAMS Solution b. Find the mass in grams of 5.4 moles of C4H4
No. of Mass per Mass per
Element Multiply Atoms atom mole
C 4 12.01 4 x 12.01 48.04
H 4 1.008 4 x 1.008 4.032 Mass per mole of C4H4 52.072 EXAMPLE 3. FINDING MASS IN GRAMS Solution b. Find the total mass in grams of 3.8 moles of NaCl2
Substance Solution Mass (g)
5.4 mol C4H4 5.4 x 52.072 281.19
EXAMPLE 3. FINDING MASS IN GRAMS Solution c. Find the mass in grams of 7 moles of (NO2)3
No. of Mass per Mass per
Element Multiply Atoms atom mole
N 3 14.01 3 x 14.01 42.03
O 6 16 6 x 16 96 Mass per mole of (NO2)3 138.03 EXAMPLE 3. FINDING MASS IN GRAMS Solution c. Total mass in grams of 7 moles of (NO2)3
Substance Solution Mass (g)
7 mol (NO2)3 7 x 138.03 966.21
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