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1.1.1.

PORCENTAJE DE REMOCIÓN

𝑪𝒓𝟑 𝑪𝒓𝟔 + 𝟑𝒆−


Factor de dilución
Dilución (muestras)
254
𝐶1 𝑉1 = 𝐶2 𝑉2 𝐹=
5
(2000)5𝑚𝑐 = 𝐶2 (25𝑚𝑙) 𝐹 = 225
𝐶2 = 400 𝑝𝑝𝑚 𝑝𝑟𝑖𝑚𝑒𝑟𝑎 𝑚𝑢𝑒𝑠𝑡𝑟𝑎 (𝑪𝒓+𝟔 ) = (𝑪𝒓+𝟔 )𝐷𝒙 𝑭
400(5) = 𝐶3 (25)
𝐶3 = 80𝑝𝑝𝑚 𝑠𝑒𝑔𝑢𝑛𝑑𝑎 𝑚𝑢𝑒𝑠𝑡𝑟𝑎
Balance durante curtición
[𝑪𝒓 ]𝑓 = [𝑪𝒓 ]𝑜 − [𝑪𝒓 ]𝒇

1 mol Cr 2 (SO4)3 2 mol Cr 52 mol Cr


w Cr 6 = 540gr Cr 2 (SO4)3 ( 2 )( 2
)( )
392 g Cr (SO4)3 1 molCr (SO4)3 1 molCr

𝐖𝐂𝐫 𝟔 = 𝟏𝟒𝟑, 𝟐𝟔𝟓 𝐠 𝐂𝐫


143. 265x 103 mg Cr
Cr[ppm] = 5 ( )
7.2L

𝑪𝒓[𝒑𝒑𝒎] = 𝟏𝟗𝟖𝟗𝟕. 𝟗𝟐 𝒑𝒑𝒎

Concentración de cromo fijado Tratamiento


[Cr ]f = (19897.92 − Crf)x 7.2 [Cr ]R = (Cr)F1 − (Cr)F2

[Cr ]f = (19897.92 − 4000)x 7.2 [WCr ]R = [Cr]R x V

[Cr ]f = 114465.024mg 𝑪𝒓𝟔 = 1.3316 ∗ 𝑎𝑏𝑠 ∗ 0.047


[𝑪𝒓 ]𝑓 = 𝟏𝟏𝟒. 𝟒𝟔𝟓 𝒈
𝟔
256
(𝑪𝒓 )𝑓1 = 0.256𝑝𝑝𝑚 ∗
5
= 4000 𝑝𝑝𝑚
Tratamiento
Porcentaje de remoción
[Cr ]R = (Cr)F1 − (Cr)F2
4000 = 100%
[WCr ]R = [Cr]R x V
12.2 = x
𝟔
𝑪𝒓 = 1.3316 ∗ 𝑎𝑏𝑠 ∗ 0.047
x = 0.031
3
25 x = 1 − 0.031
(𝑪𝒓𝟔 )𝑓2 = 0.976𝑝𝑝𝑚 ∗ = 12.2 𝑝𝑝𝑚
5
x = 99.97 %

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