TALLER 1 DE PROCESOS AMBIENTALES

1.

T (días) C (gr/m^3) Ln© 1/C

0 12 2,5 0,08
1 10,7 2,4 0,09
3 9 2,2 0,11
5 7,1 2,0 0,14
10 4,6 1,5 0,22
15 2,5 0,9 0,40
20 1,8 0,6 0,56

Orden 0  R=0,936

Orden 1  R=0,995

Orden 2  R=0,958

|
𝑑𝐶
= −𝐾𝐶 𝑛
𝑑𝑡
𝑑𝐶
= −𝐾𝐶 1
𝑑𝑡
𝑑𝐶
= −𝐾𝐶
𝑑𝑡
𝑐 𝑡
𝑑𝐶
∫ = −𝐾 ∫ 𝑑𝑡
𝑐𝑜 𝐶 𝑡=0

ln(𝐶)𝐶𝐶𝑜 = −𝑘𝑡𝑡=0
𝑡

ln(𝐶) − ln(𝐶𝑜) = −𝐾𝑡

𝐶
ln ( ) = − 𝐾𝑡
𝐶𝑜
ln(𝐶) − ln(𝐶𝑜) = −𝐾𝑡
ln(𝐶) = −Kt + ln⁡(Co)
𝑌 = −0,0972𝑋 + 2,4701
 2.

REACCIÓN CONSTITUYENTE CINÉTICA ϒ

A B
AB -1 +1 K*A

ϒA=-K*A

ϒB=K*A
𝑑𝐴
𝑉 = 𝑄𝑒 ∗ 𝐶𝑒 − 𝑄𝑠 ∗ 𝐶𝑠 − 𝐾𝐶𝑠𝑉
𝑑𝑡
𝑄 ∗ 𝐶𝑒 𝑄 ∗ 𝐶𝑠
0= − − 𝐾𝐶𝑠
𝑉 𝑉
𝑄 𝑄𝐶𝑒
𝐶𝑠 ( − 𝐾) =
𝑉 𝑉
𝑄
∗ 𝐶𝑒
𝐶𝑠 = (𝑉 )
𝑄
𝑉+𝐾
1
𝑇 ∗ 𝐶𝑒
𝐶𝑠 = ( )
1
𝑇 + 𝐾

1
𝐶𝑠 = ( ) ∗ 𝐶𝑒
1 + 𝐾𝑡
1
0,5⁡𝐶𝑒 = ( ) ∗ 𝐶𝑒
1 + 𝐾𝑡
0,5(1 + 𝐾𝑡) = 1
1
1 + 𝐾𝑡 =
0,5
1
𝐾𝑡 = −1
0,5
1
−1
0,5
𝐾=
𝑡
1
−1
0,5
𝐾=
18⁡𝑑 −1
𝐾 = 0,05⁡𝑑−1

3. K= 0,4 𝑑−1
 𝑑𝐴
𝑉 = 𝑄𝐶1 𝑒 − 𝑄𝐶2 − 𝐾𝐶2 𝑉
𝑑𝑡
𝑄 𝑄
0 = 𝐶1−2 − 𝐶2 − 𝐾𝐶2
𝑉 𝑉
𝑄 𝑄
𝐶2 (− − 𝐾) = 𝐶1−2
𝑉 𝑉
𝑄
⁡𝐶1−2
⁡𝐶2 = (𝑉𝑄 )
+𝐾
𝑉
1
𝐶1−2
⁡𝐶2 = (𝑇1 )2 ∗ 𝐶𝑒
+𝐾𝑡
𝑇
1
𝐶
0,99 𝐶2 = (1 𝑇
)2
2 +𝐾𝑡
𝑇

1
𝑇
√0,99 = (√ 1 +𝐾𝑡 )2 =
𝑇

1
𝑇
√0,99 = 1
+𝐾𝑡
𝑇
1
√0,99 = 1+𝐾𝑡
1
1 + 𝐾𝑡 =
√0,99
1
−1
𝑡 = √0,99
𝐾
1
−1
√0,99
𝑡= 0,4⁡𝑑 −1

𝑡 = 0,0125⁡𝑑−1
4.
𝑄 𝑄 𝑄
∗𝐶𝑒 −( +𝐾)∗𝑡 −( +𝐾)∗𝑡
𝑉
𝐶=( 𝑄 ) ∗ (1 − 𝑒 𝑉 ) + 𝐶𝑜 ∗ 𝑒 𝑉
+𝐾
𝑉

𝑚3 3600⁡𝑆 𝑚3
𝑄=8 ∗ = 28800
𝑆 1ℎ ℎ
𝑀𝑔 1000⁡𝐿 𝑀𝑔
𝐶𝑒 = 0,8 𝐿 ∗ 1⁡𝑚3 = 800 𝑚3

0,2⁡𝑀𝑔 1000⁡𝐿 𝑀𝑔
𝐶𝑜 = 0,2⁡𝑝𝑝𝑚 = ∗ = 200⁡
1𝐿 1𝑚3 𝑚3

𝐾 = 1,2𝑥102 ℎ−1

𝑚3 𝑚3
28800 𝑀𝑔 28800
ℎ ∗ 800⁡ −( ℎ +36⁡ℎ)∗36⁡ℎ
3 3 980000⁡𝑚3
𝐶= 980000⁡𝑚 𝑚 ∗ 1−𝑒
𝑚3
28800
ℎ 2 −1
(980000⁡𝑚3 + 1,2 ∗ 10 ℎ ) ( )
𝑚3
28800
−( ℎ +1,2∗102 ℎ−1 )∗36⁡ℎ
𝑀𝑔 980000⁡𝑚3
+ 200 ∗𝑒
𝑚3

𝑀𝑔
𝐶 = 0,195
𝑀3
5. 𝐾 = 0,45⁡𝑑−1 0,195 *1+
𝑡 = 9⁡𝑑𝑖𝑎𝑠
𝑚𝑔
𝐶 = 55⁡
𝑙
𝐶𝑜 =?
𝑑𝐶
= −𝐾𝐶
𝑑𝑡
𝑐 𝑡
𝑑𝐶
∫ = −𝐾 ∫ 𝑑𝑡
𝑐𝑜 𝐶 𝑡=0

ln(𝐶)𝐶𝐶𝑜 = −𝑘𝑡𝑡=0
𝑡

ln(𝐶) − ln(𝐶𝑜) = −𝐾𝑡

𝐶
ln( ) = −𝐾𝑡
𝐶𝑜
𝐶
𝑒 ln(𝐶𝑜) = 𝑒 −𝐾𝑡
𝐶
= 𝑒 −𝐾𝑡
𝐶𝑜
𝐶 = 𝑒 −𝐾𝑡 ∗ 𝐶𝑜
𝐶
= 𝐶𝑜
𝑒 −𝐾𝑡
𝑀𝑔
55⁡ 𝐿
= 𝐶𝑜
𝑒 −0,45∗9
𝑀𝑔
𝐶𝑜 = 3156,8⁡
𝐿
6.
𝑑𝐶
= −𝐾𝐶 𝑛
𝑑𝑡
𝑑𝐶
= −𝐾𝐶 1
𝑑𝑡
𝑑𝐶
= −𝐾𝐶
𝑑𝑡
𝑐 𝑡
𝑑𝐶
∫ = −𝐾 ∫ 𝑑𝑡
𝑐𝑜 𝐶 𝑡=0
ln(𝐶)𝐶𝐶𝑜 = −𝑘𝑡𝑡=0
𝑡

ln(𝐶) − ln(𝐶𝑜) = −𝐾𝑡

𝐶
ln ( ) = − 𝐾𝑡
𝐶𝑜
ln(𝐶) − ln(𝐶𝑜) = −𝐾𝑡
ln(𝐶) = −Kt + ln⁡(Co)
[𝑁𝐻3 ] = −𝐾𝑡 + [𝑁𝐻3 ]0
𝐿 ∗ 𝑎𝑡𝑚
𝑅 = 0,082⁡
𝑚𝑜𝑙 ∗ 𝐾
𝑡 = 900°𝐶 + 273,15 = 1173,15
𝑃 2⁡𝑎𝑡𝑚
𝑚𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 = =
𝑅𝑇 0,082⁡ 𝐿 ∗ 𝑎𝑡𝑚 ∗ 1173,15𝑘
𝑚𝑜𝑙 ∗ 𝑘
𝑃
𝑚𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 = = 0,020𝑀
𝑅𝑇
[𝑁𝐻3 ]0 0,020⁡𝑀
𝑡= =
𝑘 𝑀
1,67 ∗ 10−4 𝑚𝑖𝑛
𝑡 = 119,7⁡𝑚𝑖𝑛
7.
𝑑𝑐
= ⁡ −𝐾𝐶 𝑛
𝑑𝑡
𝑑𝑐
𝑑𝑡
= ⁡ −𝐾𝐶 2
𝑑𝑐
= −𝐾⁡𝑑𝑡
𝑐2
−2
∫𝐶 𝑑𝑐 = −𝐾 ∫ 𝑑𝑡
𝐶
𝐶 −1
−1 𝐶𝑜
= −𝐾𝑡
1𝐶
−𝐶 = −𝐾𝑡
𝐶𝑜
1 1
− 𝐶 − 𝐶𝑜 = −𝐾𝑡
1 1
𝐶𝑜
− 𝐶 = −𝐾𝑡
1 1
𝐶
= 𝐾𝑡 + 𝐶𝑜
1
𝐶= 1
𝐾𝑡+
𝐶𝑜
1
𝐶 = (𝐾𝑡 + 𝐶𝑜)−1
1 1
− +
𝐶 𝐶𝑜
𝐾= −𝑡
1 1
−
𝐶 𝐶𝑜
𝐾= 𝑡
𝐿3
𝐾=
𝑚∗𝑡
𝐾 = 𝐿3 (𝑚 ∗ 𝑡)−1