LEVEL WISE QUESTION PAPER MADE BY

FACULTY – DHIRENDRA KUMAR

A RENAUD FACULTY OF CHEMISTRY FROM VARANASI CITY (UP)

More than 5 years of experience in teaching.

Done PHD. From BHU (Varanasi - UP)

Currently worked at – A+MRS Educare Institute in Varanasi UP.

ORGANIC CHEMISTRY
ISOMERISM

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This is the Level Wise Practice Sheet Made by Mr. Dhirendra Kumar (Chemistry Faculty at A+MRS
Educare). There are three levels and one more section for assertion – reason types of question.

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CHEMISTRY
PRACTICE SHEET
 Organic Chemistry
ISOMERISM
Q.1. The compound C4H10O can show :
(a) metamerism (b) functional isomerism (c) position isomerism (d) all of three

Q.2. Which of the following compounds is optically active:

(a) CH3CH2OH (b) (CH3)2CHCH2OH (c) CH3CHOHC2H5 (d) CCl2F2

Q.3. A compound contains two dissimilar asymmetric carbon atoms. The number of stereoisomers are :
(a) 2 (b) 4 (c) 3 (d) 1

Q.4. Optical isomerism is shown by :

(a) oxalic acid (b) acetic acid (c) benzoic acid (d) lactic acid

Q.5. During debromination of meso dibromobutane, the major compound formed is :

(a) n-butane (b) trans-2-butene (c) 1-butane (d) cis-2-butene

Q.6. Which of the following will exhibit chirality?

(a) neopentane (b) 3-methylhexane (c) isopentane (d) 2-methylhexane

Q.7. Which of the following will not show cis-trans isomerism?

H2
(a) H 3C  C  HC  C  CH 3 (b) H 3CH 2C  HC  C  CH 2CH 3
H
CH 3

(c) H 3C  CH  HC  C  CH 2 CH 3 (d) H 3C  HC  C  CH 2CH 3

H H
CH 3
Q.8. The number of possible enantiomeric pairs that canbe produced during monochlorinationof 2-methylbutane is:
(a) 2 (b) 4 (c) 3 (d)

Q.9. Which of the following compounds will show geometrical isomerism?

(a) 2-butene (b) 1-phenyl propene (c) propene (d) 2-methyl-2-butene

Q.10. Tautomarism is not exhibited by :

O O O
O
(a) (b) (c) (d)
CH O
HC O

CH
Q.11. An enantiomerically pure acid is treated with racemic mixture of an alcohol having one chiral carbon. The ester
formed will be:
(a) optically active mixture(b) meso compound
(c) pure enantiomer (d) racemic mixture

Q.12. The optically active tartaric acid is named as D-(+)-tartaric acid because it has a positive:
(a) optical rotation and is derived from D-glucose
(b) optical rotation and is derived from D-(+)-glyceraldehyde
(c) pH in organic solvent
(d) optical rotation only when substituted by deuterium

Q.13. How many cyclic isomers of C5H10 are possible?

(a) 4 (b) 3 (c) 2 (d) 5
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CHEMISTRY Practice Sheet - 1 LEARNAF INC.
COOH

Q.14. The compounds given below are :

OH
(a) enantiomers (b) regiomers (c) identical (d) diastereomers

Q.15. Which of the following compounds will exhibit geometrical isomerism?

(a) 1-phenyl-2-butene (b) 2-phenyl-1-butene (c) 3-phenyl-1-butene (d) 1, 1-diphenyl-1-propene

Q.16. Which of the following does not show geometrical isomerism ?

(a) 1, 2-dichloro-1-pentene (b) 1, 1-dichloro-1-pentene
(c) 1, 3-dichloro-2-pentene (d) 1, 4-dichloro-2-pentene

Q.17. Which of the following is most likely to show optical isomerism?

H H H

CH 2 H
C CH 2
(a) C C (b) C (c) C (d)
Cl
Cl Cl Cl

Q.18. Which one of the following will have a meso-isomer also?

(a) 2-chlorobutane (b) 2, 3-chloropentane
(c) 2, 3-dichlorobutane (d) 2-hydroxypropanoic acid

Q.19. On monochlorination of 2-methylbutane, the total number of chiral compounds is :

(a) 2 (b) 6 (c) 4 (d) 8

Q.20. No of structural isomers for C6H14 is :

(a) 3 (b) 5 (c) 4 (d) 6

Q.21. Which of the following will show geometrical isomerism?

(a) C2H5Br (b) (CH)2(COOH)2 (c) CH2(COOH)2 (d) C2H6

Q.23. Number of primary amines of the formula C4H11N is :

(a) 1 (b) 3 (c) 2 (d) 4

Q.24. Geometrical isomerism is possible in :

(a) isobutene (b) benzophenone-oxime
(c) acetone-oxime (d) acetophenone-oxime

Q.25. Which of the following structures represent 'meso' form :

H
OH OH H 3C CH 3
H H CH 3
OH C
(a) OH (b) H (c) H (d)
C
H
H 3C H
Br
Q.26. Select the same molecule among the following :

Br Br H3C CH 3
(a) H 3C C C CH 3 (b) H C C H
H H Br Br

Br
H 3C H
(c) (d) All are the same
H 3C H
Br
2
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CHEMISTRY Practice Sheet - 1 LEARNAF INC.

Q.28. Number of isomer represented by molecular formula C4H10 O

(a) 6 (b) 4 (c) 7 (d) 8
Q.29. Type of isomerism shown by the product of the reaction between benjaldehyde anhydroxyl amine is
(a) cis-trans (b) E-Z (c) syn-anti (d) d-l
Q.30. Number of stereoisomer for pent-3-en
(a) 3 (b) 4 (c) 5 (d) 6
Q.31. The number of enantiomers and meso form for the compound
HOOC - CH (CH3 ) - CHOH - CHBr - CHOHCH (CH3) - COOH
(a) 12, 2 (b) 12, 4 (c) 8, 4 (d) 8, 2
Q.32. The correct statement about the comopound given below is
H
Cl
C H3
H3C
H
Cl
(a) compound is optically active (b) compound possesses center of symmetry
(c) compound possesses plane of symmetry (d) compound is optically inactive
Q.33. The correct statement concerning the structure E, F, G is/are

H3 C O H3C OH H 3C CH 3
E F C
H 3C CH3 H3C CH 3 H3C OH
(1) E, F and G are resonance structure (2) E F and E G are tautomer
(3) F and G are geometrical isomer (4) F G are diastereomer
(a) 1, 2, 4 (b) 2, 4 (c) 2, 3, 4 (d) 3, 4
Q.34. Geometrical isomerism is shown by

CH2 CH 2 CHCl CHCl

(a) (b) (c) (d)

Q.36. Which of the following Fischer projection formula is identical to D-glyceraldehyde?

CH 2OH CH 2OH CHO CHO

(a) HO CHO (b) H OH (c) HO CH2 OH (d) H CH2 OH

H CHO H OH

Q.37. The R-isomer among the following is :-

CHO H CH3 COOH

(a) HO H (b) O OH (c) H OH (d) H NH 2
C H2 OH CH 3 C2 H5 H

Q.38. The most stable conformation of n - pentane is

C2 H 5 C 2H 5 C2 H 5
H H H CH 3 CH 3
(c)
(a) (b) (d) None

H H H H
CH 3 H H
3
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CHEMISTRY Practice Sheet - 1 LEARNAF INC.
Q.39. Assign the correct R- S notation to the following structures :

COOH COOH COOH COOH

H Br Br H H Br Br Br
A. B. C. D.
H Cl Cl H H H Cr H

CH 3 CH 3 CH3 CH 3

1. 2S, 3S 2. 2R, 3R 3. 3S, 2R 4. 2R, 3S

(a) A - 1, B - 2, C - 3, D - 4 (b) A - 2, B - 1, C - 4, D - 3
(c) A - 3, B - 4, C - 1, D - 2 (d) A - 2, B - 1, C - 4, D - 3
Q.40. Arrange Ce +3, Pm +3 and Yb+3 in increasing order of their ionic radii.
(a) Yb +3 < Pm +3 < Ce+3 La +3 (b) Ce+3 < Yb+3 < Pm+3 < La +3
(c) Yb +3 < Pm +3 < La+3 < Ce+3 (d) Pm+3 < La +3 < Ce +3 < Yb +3

Q.41. Which one of the following is an amphoteric oxide?

(a)ZnO (b) Na2O (c) SO2 (d) B2O3

Q.42. Which one of the following substances has the highest proton affinity?
(a) H 2O (b) H2S (c) NH3 (d) PH 3

Q.43. Among Al2O 3 , SiO2 , P2O 3 and SO2 the correct order of acid strength is?
(a) Al 2O3 < SiO2 < SO2 < P2O3 (b) SiO2 < SO 2 < Al 2O3 < P2 O3

(c) SO 2 < P2O 3 < SiO2 < Al2O3 (d) Al2O 3 < SiO 2 < P2 O3 < SO2

Q.44. In which of the following arrangements the ordr is NOT according to the property indicated against it?
(a) Al 3+ < Mg2+ < Na+ < F - - increasing ionic size
(b) B < C < N < O < P - increasing first ionisation enthalpy
(c) l < Br < F < Cl - increasing electron gain enthalpy (with negative sign)
(d) Li < Na < K < Rb - increasing metallic radius

Q.45. The increasing order of the first ionization enthalpies of the elements B, P, S and F (lowest first) is :
(a) F < S < P < B (b)P < S < B < F (c) B < P < S < F (d)B < S < P < F
Q.46. In which of the following arrangements, the sequence is not strictly according to the property written against it ?
(a) HF < HCl < HBr < Hl : increasing acid strength
(b) NH 3 < PH3 < AsH3 < SbH3 : increasing basic strength
(c) B < C < O < N : increasing first ionization enthalpy
(d) CO 2 < SiO2 < SnO2 < PbO 2 : increasing oxidising power

Q.47. The correct sequence which shows decreasing order of the ionic radii of the elements is:
(a) Al 3+ > Mg2+ > Na+ > F- > O 2- (b) Na+ > Mg2+ > Al3+ > O2- > F -
(c) Na 2+ > F - > Mg2+ > O2- > Al 3+ (d)O 2- > F - > Na + > Mg 2+ > Al3+
Q.48. The set representing the correct order of ionic radius is :
(a) Na + > Li+ > Mg2+ > Be 2+ (b) Li+ > Na + > Mg2+ > Be2+

(c) Mg 2+ > Be 2 > Li + > Na+ (d) Li+ > Be2+ > Na+ > Mg2+

Q.49. Among the following which one can have meso form?
(a) CH 3CH(OH)CH(Cl)C2H 5 (b) C2 H5CH(OH)CH(OH)CH 3

(c) CH 3CH(OH)CH(OH)C2H 3 (d) HOCH2CH(Cl)CH3

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