Aits 1819 Jeea FT Xi Paper 2 Sol

FIITJEE
ALL INDIA TEST SERIES

FULL TEST – XI
JEE (Advanced)-2019
PAPER – 2
TEST DATE: 13-05-2019
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. A, B, D
Sol. There will be no normal reaction between rod and ring, because rod is 3/5
massless. The motion of ring will be free fall under gravity.
Velocity of ring when it leaves contact with rod
4 8g 4/5
 2  g  
5 5
Angular momentum
3 8g 72g3
=m m
5 5 125
2. C, D
Sol. P0A + kx0 = PiA P0A
P0A + k(x0 + x) = PA
k
P  P0  (x0  x)
A
Volume = v 0  (x  x0 )A
k PiA kx0
P  P0  (V  V0 )
A2 P0A + kx0 = PiA
kV  kV 
P  2   P0  20 
A  A 
P = mV + C
2
nRT = mV + CV
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AITS-FT-XI (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2
3. A, D
330
Sol. f  640
(330  10)
330
  640  660 Hz
320
4. A, B, C
 
Sol. q  q0 sin  t  
 6

i  q0  cos
6
q0 3 24
  q0  8 3
2 2 3
Alternatively
q02 1 (4 3 )2 1
   2  (6)2
2C 2 2 2
q0  8 3
2
1 2 q0
Li0   i0  4 3
2 2C
5. A, D
Sol. Td = dm2R
Td = 2R2
1
K.E. = (.2R)R2 2 T T
2
=  R32
Elastic potential energy d
1 (stress)2
=   volume
2 Y
1 2R2  2R2
= .A  2R
2 YA 2
2 4R5
=
yA
6. A, D
0 i
Sol. d = adr
2r
 ia
 = 0 ln2
2
7. D
V
Sol. 3g  Vg  T
2
V g
T
2
3 AITS-FT-XI (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
8. B
 i
Sol. Magnetic field due to long wire is given by B  0 nˆ , where n̂ is determined by right hand thumb
2r
rule.
9. D
Sol. V   x2 y  5
V(5, 2 1) = 45 V
V(1, 1, 1) = +4 V
V(2, 1, 1) = 1 V
V(1, 2, 1) = 3 V
10. B
Sol. ( - 1)t = x
t
= x
2
2
 = x


 = t
600
SECTION – D
11. 00000.11
Sol. kx = mg + m 0g – Av2
dx dm dv
k.  .g  A.2v.
dt dt dt
500  (5  1) 1 dm
 
30  60 10 dt
2000 1
= =  0.11 .
30  60  10 9
12. 00060.00
R A
Sol. sin 53 = 530
OA
5R
OA =
4
9R
AB = 53
0
4 O
BC
tan53 =
AB R
9R 4
 BC = 
4 3 B C
 BC = 3R = 60 cm
13. 01000.00
Sol. Potential difference across resistor = iR = 10  100 = 1000 V
Which is equal to potential difference across capacitor.
14. 00001.50
4
Sol. 
2
3 P0
P = P sin /3 =
2
v 3 p 3 3
 =  103
v 2B 2  100
3 -5
 105 = 1.5  10 .
2
15. 08000.00

Sol. acm  (2iˆ  4ˆj)

F1 = m acm
F12 = 20  400
= 8000
16. 00005.00
Sol. A = A0 (1 – 0.19)
A = A0e t
0.81 = et
 = ln(0.81)
= 20.10 = 0.20
1 1
  5hours
 0.20
17. 02528.00
u2 2
Sol.  4  u = 4g
g
2GM
v 2c 
R2
4
Ve2  241. R
3
GM 4
u2 = 4. = 4.G R3
R2 3
 R2 = Re
18. 00006.00
2 1
Sol. Velocity of image : 8    6cm / s
4/3 2
Chemistry PART – II
SECTION – A
19. B, D
2
Sol. Cu2  4NH3 
 Cu NH3 4 
2
Cd2  4NH3  Cd NH3  4 
CdS and CuS both are insoluble in yellow ammonium sulphide.
20. A, C, D
Sol. CH3 CH3
CH C Sia 2B H,THF
  CH HC

H2O2 , OH
 Q
CH3 CH3
BSia 2
CH3 CH3
Hg OAc 2  THF  CH3 OH NaBH4 /OH

 CH C CH3  CH HC
HgOAc CH3
OCH3 OCH3
21. A, C, D
22. B, C
Sol. Since intermolecular forces are zero hence potential energy increases with decreasing distance,
while Z increases by increasing pressure.
23. B, C, D
Sol. -hydroxy ketones and aldehydes give +ve Tollen’s test hence are reducing sugar.
24. A, C
Sol. SNNGP path hence retention of configuration.
25. B
Sol. [Co(NH3)4(H2O)Cl]Br → shows cis-trans isomerism, paramagnetic.
sp3d2 hybridization, shows ionization isomerism.
K3[Cr(Ox)2Cl2] → shows cis-trans isomerism, paramagnetic,
2 3
shows optical isomerism d sp hybridization
3 2
[Ni(H2O)6]Cl2 → sp d hydridization, paramagnetic
[Pt(NH3)2Cl2] → Geometrical isomerism, dsp2 hybridization, diamagnetic
26. C
27. B
Sol. NH2 OH OH
CH2OH
 i NaNO2 /HCl
 ii H2O
HCHO/ OH
 

O O
OH OH
CN
H 
HCHO /OH H
  HCN, OH
 

H H  COOH

CH2OH
CH2OH CH2OH
OH
O
NH2
NaNO 2/HCl
0 - 5o C
CHO COO COOH

OH

  H 
  O
CHO CH2OH CH2OH
O
28. B
SECTION – D
29. 00003.50
2 2
Sol. Ni NH3 6  ,O2 , Ti H2O 5 Cl NO3 ,S2 ,Se, Mn H2O 6  ,S
     
30. 00000.80
Sol. Leucine form N-terminal then possible combination
Leu – Ala – Phe – gly Leu – Phen – Ala – gly
Leu – Ala – Gly – Phe Leu – Phen – Gly – Ala
31. 00001.50
Sol. 2A  s   2A n  2ne 
B2n  2ne  
B
2A  s   B2naq 
 2A naq

  B s
Go  nFEo
9.5
Eo 
2nF
n 2
RT  A 
EE  o
n 2n
nF B 
103 9.5  103 2500
   2  0.7
F 2nF 2nF
2n  6, n  3
32. 08250.00
Sol. 

A 3B6  g  
 3AB 2  g 
1
1- 3
nT  1  2
VD1 n2

VD2 n1
2  1  2
 = 1/2
1
3
PAB2  2  4  3 atm
2
1
4
PA 3B6  2  1 atm
2
3
3  3
KP   3 
1
3
r G  RTn  3 
o
= - 2500 × 3 × 1.1 = - 8250 J.
33. 00020.00
Sol. PV = nRT
8.21 × 3 = n × 0.0821 × 300
n=1
2KI  O3  H2O  2KOH  I2  O 2
I2  2Na2S 2O3  2NaI  Na2S 4O 6
1
Moles of O3  moles of hypo solution
2
1 200  2
   0.2
2 1000
0.2
Mole %   100  20
1
34. 00140.00
P1
Sol. WABC  PVn WCDBEA  WDB  WEA
P2
 2n4 = 1.2 × 2.5 + 0.3 × 4
= -2 × 2 × 0.7 = - 2.8 atm L = 4.2 L atm
W net = -2.8 + 4.2 = 1.4 L atm
= 140 J
U  q  W
W=-q
q = - 140 J.
35. 00050.40
Sol. 1
H2O2     H2O     O2  g
2
a
ax x x/2
2.303 a
K log
t ax
0.693 2.303 a
 log
180 360 ax
a
4
ax
3a = 4x
3 3 9
x a   6   4.5
4 4 2
Volume of O2 at S.T.P. = 4.5 × 11.2 L = 50.4 litre.
36. 00001.60
Sol. Mohr’s salt, Oxalic acid, Ferrous oxalate, Sodium nitrite, Sodium thiosulphate, Ethyl alcohol,
Hydrogen sulphide, Stannous chloride.
Mathematics PART – III
SECTION – A
37. D
2
 n n   n  n 
Sol.  r Cr     r 2   n Cr 
 r 1   r 1  r 1 
38. A, B
2
  ai  1
Sol. S   a1  a3  ..... a2  a4  .....   
 2  4
 
39. A, B, C
Sol. Let the foot of the perpendicular from origin to the line be P(2 + 3, 3 + 2,  + 2)
2(2 + 3) + 3(3 + 2) + ( + 2) = 14 + 14 = 0
  = –1
 P(1, –1, 1)
 length of perpendicular is 3
2
 side (a) = 3  2
3
3 2
Area = a  3
4
2 2 1 1  2 2 2 
Circum radius =  3  , inradius =  3  , Centroid is  , , 
3 3 3 3 3 3 3
40. A, B, D
2b a2  b2  c 2
Sol. cosC    3b2 = a2 – c2
a 2ab
41. B, D
1
Sol. f  x  x tan3  x  1
3
42. A, C
1
  t
dx 1 t dt (Put t  x  1  x 2 )
Sol. In   n
  tn 2t
0
x  1 x 2
 1
 
1 t2  1 1  t n 1 t n1  n
=  dt     
2 1 tn  2 2  n  1 n  11 n2  1
43. C
 0 if x  0
x 
Sol. f1  x   tan1 x   0 if x  0
1 x2 
 0 if x  0
f 2(x) is not continuous at x = 1
  x  1 ; if x   2, 0 

f3  x    0 ; if x  0

2
 
 x  1 e x ; if x   0, 2
lim f4  x   1

x
4
44. D
2
Sol. C1 reduces to  z  z    z  z   –4y2 = 2x
C2 reduces to (3x – 2y + 3) + i(–y + 1) = 0  point where 3x – 2y + 3 = 0 and –y + 1 = 0 intersect
C3 is simply 2  distance from fixed line = distance from fixed point
C4 is similar interpretation as above however fixed point lies on the fixed line
45. A
Sol. Use slope form
46. A
x x
Sol. tan  cot  2cot x
2 2
1  2 3  2k  1  1  2k  1 
cot  k    cot 1    cot  
 4  2   2 

1 1   1 1 2 
  2k  1 2k  2k  1  2   2k  1  2k  1  2k 
k 1 k 1
   1 1 
1 1  1 1  1 1 
  4k  1 4k  1  2   4k  1  4k  1  2    x 4k 2  x 4k  dx = 
20
1  x 2
 x 4k 2 dx
k 1 k 1 k 1 0 k 1
SECTION – D
47. 00000.00
Sol. Distance of directrix from 4 3, 2 is   3 and from (2, 0) is 1
2 2

d2  4 3  2   22   3 1 
48. 00002.00
Sol. f(n, m) = n + 2m, each chord defines one segment, with each point of intersection creating 2
additional segments
49. 00008.00
Sol. The curve is symmetric in all 4 quadrants. Confining to first quadrant, curve is r2 = 4 cos 
 /2  /2
1
A  4  r 2 d  8  cos d  8
0
2 0
50. 00007.50
2 2 2
Sol. Use series expansion, L   2 
5 15 15
51. 00008.00
Sol. z max  3  1 and z min  3  1
52. 00004.00
 /2
n
Sol. In1   cos x cosnx  sin  n  1 x sin x  dx
0
 /2  /2
cosn1 x n 1
= In  sin  n  1 x   cos x cos n  1 xdx
n1 0 0
 2In + 1 = In
53. 00004.00
Sol. Curve is one arm of hyperbola with foci (2, 4) and (2, –4)
54. 00000.08
Sol. Non-adjacent numbers with 0 = 6C3·3·3!
6
Non-adjacent numbers without 0 = C44!
3  3! 6 C3  4! 6 C4 2
P 
9000 25

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Aits 1819 Jeea FT Xi Paper 2 Sol

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FIITJEE

ALL INDIA TEST SERIES

TEST DATE: 13-05-2019

ANSWERS, HINTS & SOLUTIONS

CHO COO COOH

= - 2500 × 3 × 1.1 = - 8250 J.

Mathematics PART – III

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