REACTION KINETICS

CH322 AND REACTOR DESIGN Imran

Abbas
 INTRODUCTION
Imran Abbas

MS Clean Energy and Chemical Engineering

Korea Institute of Science and Technology, UST Korea

E-mail: imran.abbas@giki.edu.pk; imran.icet@gmail.com

Office: M06, FMCE

Meeting hours: 15:00-17:00 (Monday to Friday)

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 CLASS TIMINGS
TIMING DAY Lecture Hall
12:30-13:20 p.m TUESDAY LH3
10:30-11:20 p.m WEDNESDAY LH2
12:00-12:50 p.m FRIDAY LH3

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 COURSE LEARNING OUTCOMES (CLO)
Students will be able
 to explain the basic principles involved in analysis of experimental
data to derive rate laws for batch, semi-continuous and flow reactors
 to develop the stoichiometry of reaction and apply the algorithm for
designing of reactors
 to understand mechanism of multiple reactions in different type of
reactors
 to understand the fundamentals of catalytic reactors including
internal and external mass transport, catalyst deactivation, catalyst
dispersion
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 * SYLLABUS Pre-requisite(s):CH201, CH321
Kinetics of chemical reactions: Rate of reactions, Molecularity and order
of reaction, Various chemical reaction and their kinetic laws including
multiple reaction, Elementary reactions, Complex and multiple reactions,
Uncatalyzed and Catalyzed (both homogenous and heterogeneous) reactions,
Analysis of kinetic data, Evolution of rate of reaction, Empirical and
mechanistic models, Equilibrium and effect of heat on reactions, Reaction
mechanism, Thermodynamics dictating reversibility of the reaction, Polymer
reaction processes,
Design of Chemical Reactors: Mass and energy balance in reactors,
Various types of reactors and their deriving equations especially catalytic
reactors, Kinetic rate laws incorporation in reactors operation,
Thermodynamics dictating adiabatic and non-adiabatic operations, Rate
controlling steps and Quasi state equilibriums
* Adapted from GIK Institute prospectus v.2018
10/02/2015 6
 Lecture wise Course Breakage
Topic

Week # Lecture #
Introductory lecture about course content, meeting and contact time, text book, CLOs, Motivation for the
1 1, 2, 3
subject, Basics of reaction Kinetics and Reactor Design, Reversibility, Molecularity and order of reaction
2 4, 5, 6 Michael Mortimer Part I
3 7, 8, 9 Michael Mortimer Part I, Fogler Ch.1
4 10, 11, 12 Fogler Ch.1, Ch2
5 13, 14, 15 Fogler Ch.2,Ch3
6 16, 17, 18 Fogler Ch.3, Ch4
7 19, 20, 21 Fogler Ch4
8 22, 23, 24 Fogler Ch5

9 25, 26, 27 Fogler Ch,6

10 28, 29, 30 Fogler Ch.6

11 31, 32, 33 Fogler Ch.7

12 34, 35, 36 Fogler Ch.8

13 37, 38, 39 Fogler Ch.8

14 40, 41, 42 Fogler Ch.10

7
15 43, 44, 45 Fogler Ch.10
COURSE
BOOKS

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 TEXT
BOOKS
1. Fogler H. Scott. “Elements of
Chemical Reaction Engineering”
4th Edition 2005, Prentice Hall,
ISBN: 9780130473943

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 TEXT BOOKS
2. Michael Mortimer and Peter
Taylor. Chemical Kinetics and
Mechanism, 2002, The Open
University. ISBN: 9780854046706

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 TEXT BOOKS
3. Levenspiel Octave. “Chemical
Reaction Engineering” 3rd Ed.
2006, Wiley India Pvt. Limited,
ISBN: 9788126510009

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 REFERENCE BOOKS
1. Davis, Mark E. and Davis, Robert J. (2003) Fundamentals of
chemical reaction engineering. McGraw-Hill Higher Education , New
York, NY. ISBN 0-07-245007
2. Ronald W. Missen, Charles A. Mims, Bradley A. Saville.
“Introduction to Chemical Reaction Engineering and Kinetics” 1999,
John Wiley & Sons, Inc. ISBN: 9780471163398
Smith J. M. “Chemical Engineering Kinetics” 1980, McGraw-Hill.
ISBN: 9780070587106
3. 4. Latest Journal articles (AIChe, ACS and RSC publications)

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MARKS DIVISION
Mid-Term 30 %
Final Term 40 %
[Quizzes (written/oral)][Assignments][Group Projects, Presentation] 30 %
Note:
A part of exam/Quizzes will be taken from class room discussions
to make your brain detain classroom discussion and provide supplementary
concepts, BOOK READING IS MUST
Any student getting less than 40% marks will fail the exam.
Slides will not be provided except for introductory lectures
A part of the Mid-term syllabus might also be included in the Final exam.
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QUIZZES 6 Quizzes in total(Best 5 will be counted)
No Retake of missed Quizzes until and
unless:
Quiz retake may either be an “Oral Exam”
or “Written Exam”.
Checking of any Quiz and relevant
discussion is only liable within 1 week of
result display. (after that any request
regarding checking and discussion will not
be entertained).
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GIK INSTITUTE
ATTENDENCE POLICY
45 lectures in total, No Student will be
allowed to sit in exams if he/she has more
than 9 absents
If a student’s absents reach 5, his name will
be reported to HoD and respective advisor for
further action and student’s counselling
If any student is late more than 5 minutes
then absent will be counted

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 MOTIVATION

Safe
Economical
Required products

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Kinetics of Chemical Reactions

CLASSIFICATION OF CHEMICAL REACTIONS

o Classification Based on Mechanism
Reversible or opposing Reactions
Irreversible Reactions
Simultaneous/Competing/parallel Reactions
Consecutive Reactions
o Classification based on no. of molecules (Molecularity)
Unimolecular
Bimolecular
Trimolecular

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Kinetics of Chemical Reactions

CLASSIFICATION OF CHEMICAL REACTIONS

oClassification based on Mechanism
oClassification based on no. of molecules (Molecularity)
oClassification based on operating conditions
 Isothermal Reactions
Isothermal at constant volume
Isothermal at constant pressure
 Adiabatic Reactions
Non-Adiabatic and Non-Isothermal

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Kinetics of Chemical Reactions

CLASSIFICATION OF CHEMICAL REACTIONS

oClassification based on Mechanism
oClassification based on no. of molecules (Molecularity)
oClassification based on operating conditions
oClassification based on phases involved
 Homogeneous Reactions
Liquid phase
Gaseous phase
Solid Phase
 Heterogeneous Reactions
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Kinetics of Chemical Reactions

CLASSIFICATION OF CHEMICAL REACTIONS

oClassification based on Mechanism
oClassification based on no. of molecules (Molecularity)
oClassification based on operating conditions
oClassification based on phases involved
oClassification based on Heat of Reaction
 Exothermic Reaction

 Endothermic Raction

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Kinetics of Chemical Reactions

CLASSIFICATION OF CHEMICAL REACTIONS

oClassification based on Mechanism
oClassification based on no. of molecules (Molecularity)
oClassification based on operating conditions
oClassification based on Heat of Reaction
oClassification based on phases involved
 Homogeneous Reactions
Liquid phase
Gaseous phase
Solid Phase
 Heterogeneous Reactions
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Kinetics of Chemical Reactions

CLASSIFICATION OF CHEMICAL REACTIONS

oClassification based on Mechanism
oClassification based on no. of molecules (Molecularity)
oClassification based on operating conditions
oClassification based on phases involved
oClassification based on Heat of Reaction
oClassification based on order of reaction
 Integral order
•First Order
•Second Order
•Third Order
 Fractional Order
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 Zero Order 22
Kinetics of Chemical Reactions

ORDER OF REACTION

What is the order of reaction with respect to S2O82- experimental rate of

reaction is

(a) 1
(b) 2
(c) 0
(d) 2-

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Kinetics of Chemical Reactions

ORDER OF REACTION
If experimental order of reaction with respect to [CO] and [Cl2] is 1 and 1.5
respectively, what will be the rate of expression for the reaction?

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