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Scuffing: From Basic Understanding

to Engine Materials Testing*

Peter J. Blau
Materials Science and Technology Division
Oak Ridge National Laboratory
Oak Ridge, Tennessee USA

DEER Conference
Detroit, MI – August 2007
* Research sponsored by DOE/ EERE / OFCVT:
“Durability of Diesel Engine Components”

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U. S. DEPARTMENT OF ENERGY
1
Definitions for Scuffing

‰ Swedish skuffa – ‘to push’

‰ Webster’s Unabridged Dictionary, 3rd ed.: “to walk without lifting


the feet; to poke or shuffle a foot in exploration or
embarrassment; to become scratched, chipped, or roughened by
wear.”

‰ ASTM Terminology standard G40: scuffing – a form of wear


occurring in inadequately-lubricated tribosystems that is
characterized by macroscopically observable changes in texture,
with features related to the direction of motion.”

Operational definition: “I’ll know it when I see it.”


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Characteristics of Scuffing

‰ Scuffing can roughen a surface with Zirconia on 304 SS (600o C)

no net loss of material (not ‘wear’).


‰ Can smooth an initially rough surface.
‰ Need not be progressive (one cycle).
‰ In machinery (engines), scuffing is
associated with inadequate or failed
lubrication.
‰ Occurs non-uniformly. Can start at one place on a surface and
spread to another after continued operation.
‰ Can lead to seizure (incipient galling) in tight-tolerance components.
‰ Scuffing damage is difficult to measure in a quantitative way.

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U. S. DEPARTMENT OF ENERGY
3
Historical Attempts to Define Critical
Scuffing Criteria
1/ 2
‰ ‘Plasticity Index’ (Greenwood and Williamson, ⎛ E ' ⎞⎛⎜ σ ⎞⎟
*
PRS, 1966). ψ = ⎜ ⎟⎜ ⎟
⎝ H ⎠⎝ R ⎠

‰ Modified Plasticity Index (Whitehouse and 1/ 2


⎛ E ' ⎞⎛⎜ σ ⎞⎟
*
Archard, PRS, 1970). ψ = 0.06⎜ ⎟⎜ * ⎟
⎝ H ⎠⎝ β ⎠

‰ ‘Film thickness ratio’ L (Beerbower, ASLE Λ=


h
Trans., 1971) σc

β∗ (autocorrelation function) is measure of surface randomness, β* = 0 when


surface heights are random; β* =1 for a flat, smooth surface)

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U. S. DEPARTMENT OF ENERGY
4
Some Problems with Critical Scuffing
Criteria based solely on Mechanics

‰ Surface roughness rarely remains constant once relative motion


begins (break-in, wear-in). Plasticity indices cannot easily
accommodate the consequences of time-dependent changes in
roughness and texture during continued contact.
‰ Plasticity models ignore the important effects of the lubricant
chemistry (Park and Ludema, Wear, 1994)
‰ Testing approaches to oil additive formulation are based on
lubricant properties. Tests keeps the material combination and
surface conditions constant.

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U. S. DEPARTMENT OF ENERGY
5
Current Scuffing Tests Popularly Use
Stepped Loading to Determine Critical Loads

‰ Stepped loading does not simulate actual


component conditions.
‰ Dwell times at each load allow subsurface
damage to accumulate and may not produce the
L
same result as if load were held constant for the
same time but at the level that induced scuffing.
μ
‰ Stepped loading tests do not address the issue of
t localized initiation and propagation of scuffing
damage.
‰ Stepped tests often use unidirectional sliding but
many key engine components reciprocate (e.g.,
pistons, fuel injectors, actuators, valve guides)
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6
Some ASTM Standards Used to Quantify
Scuffing-Related Performance of Oils

‰ ASTM D5182: “Standard test method for the scuffing load capacity of
oils (FZG visual method)” ( Example of step loading )
‰ Motor-driven gear set uses twelve 15-minute test stages with
examinations after each one.
‰ Document shows sample images of polishing, scuffing, and scoring
to estimate the extent of damage
‰ “Failure” occurs when total width of scuffing or scoring damage for
all 16 teeth on the test gear ≥ the width of one tooth (20 mm).
Metric: the ‘failure load’ stage.
‰ ASTM D6078 Ball-on-Cylinder Lubricant Evaluation (BOCLE)
‰ ASTM D6425 Optimal SRV Test – high-speed linear oscillation

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ORNL’s Approach to Scuffing Measurement
Case Study I: Fuel Injector Plungers

‰ Develop a convenient bench-scale laboratory test that


does not rely on stepped loading, but characterizes the time-
dependent progression of damage on a contact surface.
‰ Flexibility to use either experimental test coupons or
production parts.
‰ Minimize the time per test.
‰ Enable studies of the effect of surface finishes, coatings,
and other surface engineering approaches.
‰ Develop scuffing maps / models useful in material selection.

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U. S. DEPARTMENT OF ENERGY
8
Development of the ‘Pin-on-Twin’ Test

‰ Geometry allows testing


both simple cylinders and
actual fuel injector plungers.

Load

‰ High-speed data acquisition


captures friction for various locations
Top pin
Bottom pins on the stroke as a function of time or
numbers of cycles.
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First experiments evaluated 52100 steel in
#2 Diesel fuel and a low sulfur fuel (‘Jet A’)

0.20
Jet A fuel-lubrication, 10 N load,
5 Hz frequency, 10 mm stroke
Friction Coefficient

0.15

0.10

0.05 Annealed E52100 Steel


Hardened E52100 Steel
0.00
0 20 40 60
Sliding Distance (m)

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U. S. DEPARTMENT OF ENERGY
10
Friction Trace Comparison Method
Enables Initiation to be Detected

12 m
Hardened E52100 Steel (Jet A, 50 N, 5 Hz)
0.20
0.15
Friction Coefficient

0.10
0.05
0.00
-0.05
-0.10
-0.15
-0.20
Initial 12 18 30 60
Sliding Distance (m)

18 m
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U. S. DEPARTMENT OF ENERGY
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Scuffing Map Portrays Initiation and Spread

of Surface Damage on Cylindrical Plungers

Initial surface roughness affects


0.065
the time to initiate scuffing and
0.052-0.065
0.052 0.039-0.052 the time to transition to a fully
0.026-0.039
0.039 0.013-0.026
scuffed surface
Δμ 0.000-0.013

0.026

600

0.013 540

600 480

Scuffed
0.000 480

Sliding Time (sec)


420

0
1

3
240

360

360
Jet Fuel

4
Transition
5

120

Time (s) 300

240

(low S)

Stroke Location (mm) 9


0
10
180

120
No scuffing
Global Scuffing

Sequence of friction traces on a simulated 60

Local Scuffing

fuel injector plunger 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45
Composite Roughness R q ' (μm)

Zirconia on Steel
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New Multi-Stage Scuffing Model Includes


both Lubricant and Materials Effects

Material
Lubricant properties
flow and
viscosity

Boundary film properties


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13
Case Study II: High-Temperature Scuffing of
Wastegate Bushing Materials for EGR Systems

‰ Developed a “bow-tie test” for cylinder


on flat geometry up to 650o C
‰ Measures changes in torque due to
surface damage and debris
accumulation

OSCILLATION
θ ~ 50o

25.4 mm 32 mm

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U. S. DEPARTMENT OF ENERGY
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Multiple Criteria were used to create
Scuffing Severity Maps

Worse than the others Better than the others 1) Torque as a function of time
Tile roughness vs. specific load
1800
2) Changes in surface roughness
440C/PL33
1600

WORST RESULTS
3) Examination of test specimens
1400 T-400C/T-400C
316 (Nit) / IDM5399
SPECIFIC LOAD

1200

1000
440C/IDM5399

800
Stellite 3 ctg/Stellite 3 ctg
600
T-400C ctg/Stellite 3
Stellite 6B/Stellite 6B
400
316 (Nit) / T-400C
200
0 0.5 1 1.5 2

ROUGHNESS, Ra (μm)
(After testing)

(Corrected for the measured scuffed area)


J. Wu and M. Yao, Deloro-Stellite
OAK RIDGE NATIONAL LABORATORY
U. S. DEPARTMENT OF ENERGY
15
Biodiesel Additive Issues: How much BD can
improve lubricity? Fundamentally, what effect does
BD have on scuffing initiation and propagation?

‰ The National Biodiesel Board – www.biodiesel.org – reports


lubricity benefits when adding > 1% to #2 Diesel fuel (BOCLE).
Soybean oil-based additives claimed to meet or exceed
lubricity of current diesel fuels.
‰ Degree to which BD additives improve lubricity of low-S fuels
depends on which test method is used (e.g., BOCLE, SRV,
etc. -- report by L. Schumacher, U Idaho)
‰ Materials-based research is needed to understand these
discrepancies and to identify BD effects on the initiation and
propagation of scuffing damage in different materials.

OAK RIDGE NATIONAL LABORATORY


U. S. DEPARTMENT OF ENERGY
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DOE’s HTML User Program (Tribology Research User
Center) Provides Access to Specialized Test Methods

High-temperature
valve tests

High Temperature
Sliding Friction / Wear
Ring and Liner
Repeated
Impact

Advanced materials

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U. S. DEPARTMENT OF ENERGY Hot scuff testing
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Summary

‰ Scuffing is context-dependent. Tribosystems should be


individually analyzed in order to define ‘failure of function’.
‰ Scuffing damage can occur quickly or over time: depends
on operating conditions, materials, and lubrication.
‰ Approaches: redesign, alter operating conditions, alternative
materials or surface treatments, surface finish optimization, or
change lubricant type and means of supply.
‰ Simulative experiments and analytical models should be
applied to investigate effects of biodiesel fuels on the scuffing
mechanisms in materials/coatings.
‰ Methods described here are available to U.S. industry and
universities in the HTML Tribology Research User Center.

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U. S. DEPARTMENT OF ENERGY
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Special thanks to …

‰ Jun Qu, ORNL


‰ John J. Truhan, Jr. (UT, Caterpillar)
‰ Brian C. Jolly (ETSU, ORNL)
‰ Ray Johnson, ORNL
‰ Yuri Kalish, George Hansen (DDC)
‰ James Wu and Matthew Yao (Deloro-Stellite)
‰ Sid Diamond (DOE, dec.)
‰ Jerry Gibbs (DOE)
‰ OFCVT (HVPM program and the HTML User Program)

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U. S. DEPARTMENT OF ENERGY
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