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Normalidad de Disolucion Patron Primario Molaridad de disolucion Patron Prim

Sustancia Hidroxido de Sodio Hidroxido de sodio


PM 40 g de soluto 0.4 PM 40
Volumen(L) 0.1 Volumen(L) 0.1
Normalidad 0.1 Normalidad 0.1
#Cargas 1

Normalidad de Disolucion Patron Secundario Molaridad de disolucion Patron Secu


Sustancia CH3COOH Glacial Sustancia CH3COOH Glacia
PM 60.1 g de soluto Teorico 0.601 PM 60
Volumen(L) 0.1 Densidad 1.055 Volumen(L) 0.1
Normalidad 0.1 Pureza 99.7 Normalidad 0.1
#Cargas 1 mL de soluto REAL 0.57138239
olaridad de disolucion Patron Primario
Hidroxido de sodio
g de soluto 0.4

laridad de disolucion Patron Secundario


CH3COOH Glacial
g de soluto Teorico 0.6
Densidad 1.055
Pureza 99.7
mL de soluto REAL 0.57043167
Acidos
pKa 4.75 Concentracion 0.1
Ka 1.77827941E-05 a 1
b 1.77827941E-04 c -1.77827941E-04
Los acidos y bases de fuerza media
Grado de Tipo de Acido distaran de resultados exactos por el
Disociacion(α) 0.0131576828 Acido Debil redondeo de decimales al momento de
hacer operaciones en exel y el pKa de
%α 1.3157682799 a 1 acidos fuertes es igual a 2 y el pKb de
b 1.77827941E-05 c -1.77827941E-06 bases fuertes es igual a 2
pH 2.875 Acido Acetico
Bases
pKb 0 Concentracio 0.1
Kb 1.00000000E+00 a 1
b 1.00000000E+01 c -1.00000000E+01
ases de fuerza media
sultados exactos por el Grado de Tipo de
cimales al momento de Hidrolisis(α) -4.0839202169 Acido Base Fuerte
nes en exel y el pKa de
es igual a 2 y el pKb de %α -408.39202169 a 1
ertes es igual a 2 b 1.00000000E+00 c 1.00000000E-01
Hidroxido de
pH 13 Base Sodio
Acido debil-Base Fuerte
Molaridad de Acido 0.1 Volumen Inicial (ml) 15
Molaridad de Base 0.1 Volumen Agregado (mL) 0.2
Particiones 75 #Cargas o Equivalencia 1
ka (Acido) 0.000018 pka (Acido) 4.7447274949
Moles B 0.0015 Concentracion Rx 0.1
pKa (Base) 1E-14 pka(Base) 14
Volumen agregado
Acido Moles de A pH Constante de
equilibrio de
0 0 2.8723637474 Reaccion
0.2 0.00002 2.8754957752 1800000000
0.4 0.00004 3.1824346304
0.6
0.8
0.00006
0.00008
3.3645162532
3.4955291375 ε
1 0.0001 3.5985994592 7.453559924999E-05
1.2 0.00012 3.6840296545
1.4 0.00014 3.7573166222 %P(Cuantitividad)
1.6 0.00016 3.8217426792
1.8 0.00018 3.8794260688 99.9925464401
2 0.0002 3.9318141383
2.2 0.00022 3.9799402061
2.4 0.00024 4.0245681915
2.6 0.00026 4.0662791577
2.8 0.00028 4.1055256956
3 0.0003 4.1426675036
3.2 0.00032 4.1779954659
3.4 0.00034 4.2117484227
3.6 0.00036 4.2441251443
3.8 0.00038 4.2752930688
4 0.0004 4.3053948011
4.2 0.00042 4.3345530298
4.4 0.00044 4.3628743061
4.6 0.00046 4.3904519873
4.8 0.00048 4.4173685605
5 0.0005 4.4436974992
5.2 0.00052 4.4695047628
5.4 0.00054 4.4948500217
5.6 0.00056 4.5197876683
5.8 0.00058 4.5443676611
6 0.0006 4.5686362358
6.2 0.00062 4.5926365122
6.4 0.00064 4.6164090176
6.6 0.00066 4.6399921444
6.8 0.00068 4.6634225552
7 0.0007 4.6867355479
7.2 0.00072 4.7099653886
7.4 0.00074 4.7331456223
7.6 0.00076 4.7563093674
7.8 0.00078 4.7794896012
8 0.0008 4.8027194419
8.2 0.00082 4.8260324346
8.4 0.00084 4.8494628454
8.6 0.00086 4.8730459722
8.8 0.00088 4.8968184775
9 0.0009 4.920818754
9.2 0.00092 4.9450873287
9.4 0.00094 4.9696673215
9.6 0.00096 4.9946049681
9.8 0.00098 5.019950227
10 0.001 5.0457574906
10.2 0.00102 5.0720864293
10.4 0.00104 5.0990030025
10.6 0.00106 5.1265806837
10.8 0.00108 5.15490196
11 0.0011 5.1840601887
11.2 0.00112 5.214161921
11.4 0.00114 5.2453298455
11.6 0.00116 5.2777065671
11.8 0.00118 5.3114595239
12 0.0012 5.3467874862
12.2 0.00122 5.3839292942
12.4 0.00124 5.4231758321
12.6 0.00126 5.4648867983
12.8 0.00128 5.5095147837
13 0.0013 5.5576408515
13.2 0.00132 5.610028921
13.4 0.00134 5.6677123106
13.6 0.00136 5.7321383676
13.8 0.00138 5.8054253353
14 0.0014 5.8908555306
14.2 0.00142 5.9939258523
14.4 0.00144 6.1249387366
14.6 0.00146 6.3070203594
14.8 0.00148 6.6139592146
15 0.0015 7.960409377
15.2 0.00152 11.1818435879
15.4 0.00154 11.1875207208
15.6 0.00156 11.1931245984
15.8 0.00158 11.198657087
16 0.0016 11.2041199827
16.2 0.00162 11.2095150145
16.4 0.00164 11.214843848
16.6 0.00166 11.220108088
16.8 0.00168 11.2253092817
17 0.0017 11.2304489214
17.2 0.00172 11.2355284469
17.4 0.00174 11.2405492483
17.6 0.00176 11.2455126678
17.8 0.00178 11.2504200023
18 0.0018 11.2552725051
18.2 0.00182 11.260071388
18.4 0.00184 11.264817823
18.6 0.00186 11.2695129442
18.8 0.00188 11.2741578493
19 0.0019 11.278753601
19.2 0.00192 11.2833012287
19.4 0.00194 11.2878017299
19.6 0.00196 11.2922560714
19.8 0.00198 11.2966651903
20 0.002 11.3010299957
20.2 0.00202 11.3053513694
20.4 0.00204 11.3096301674
20.6 0.00206 11.3138672204
20.8 0.00208 11.318063335
21 0.0021 11.3222192947
21.2 0.00212 11.3263358609
21.4 0.00214 11.3304137733
21.6 0.00216 11.3344537512
21.8 0.00218 11.3384564936
22 0.0022 11.3424226808
22.2 0.00222 11.3463529745
22.4 0.00224 11.3502480183
22.6 0.00226 11.3541084391
22.8 0.00228 11.357934847
23 0.0023 11.361727836
23.2 0.00232 11.3654879849
23.4 0.00234 11.3692158574
23.6 0.00236 11.372912003
23.8 0.00238 11.3765769571
24 0.0024 11.3802112417
24.2 0.00242 11.383815366
24.4 0.00244 11.3873898263
24.6 0.00246 11.3909351071
24.8 0.00248 11.3944516808
25 0.0025 11.3979400087
25.2 0.00252 11.4014005408
25.4 0.00254 11.4048337166
25.6 0.00256 11.4082399653
25.8 0.00258 11.411619706
26 0.0026 11.414973348
26.2 0.00262 11.4183012913
26.4 0.00264 11.4216039269
26.6 0.00266 11.4248816366
26.8 0.00268 11.428134794
27 0.0027 11.4313637642
27.2 0.00272 11.434568904
27.4 0.00274 11.4377505628
27.6 0.00276 11.4409090821
27.8 0.00278 11.4440447959
28 0.0028 11.4471580313
28.2 0.00282 11.4502491083
28.4 0.00284 11.45331834
28.6 0.00286 11.4563660331
28.8 0.00288 11.4593924878
29 0.0029 11.4623979979
Acido debil-Base Fuerte
14

12

10

0
0 5 10 15 20 25 30 35
Cu
mL Adicionados pH x ΔpH/Δv 14
0 3.36 0.5 0.8
1 4.16 1.5 0.1 12

2 4.26 2.5 0.14 10


3 4.4 3.5 0.11
4 4.51 4.5 0.13 8

5 4.64 5.5 0.1 6


6 4.74 6.5 0.09
7 4.83 7.5 0.09 4

8 4.92 8.5 0.09 2


9 5.01 9.5 0.11
10 5.12 10.5 0.1 0
0 5
11 5.22 11.5 0.1
12 5.32 12.5 0.08
13 5.4 13.5 0.12
14 5.52 14.5 0.13 12
15 5.65 15.5 0.18
16 5.83 16.5 0.23 10
17 6.06 17.5 0.32
18 6.38 18.1 0.55 8
18.2 6.49 18.3 0.65
18.4 6.62 18.5 2.15 6
18.6 6.82 18.7 7.2
18.8 7.05 18.9 10.35 4
19 8.49 19.1 2.6
19.2 10.56 19.3 0.85
2
19.4 11.08 19.5 0.6
19.6 11.25 19.7 0.65
0
19.8 11.37 19.9 0.4 0 5
20 11.5 20.1 0.55
20.2 11.58
20.4 11.69

mL Adicionados pH x ΔpH/Δv
0 3.96 0.5 0.14
1 4.1 1.5 0.14
2 4.24 2.5 0.15
3 4.39 3.5 0.13
4 4.52 4.5 0.11
5 4.63 5.5 0.11
6 4.74 6.5 0.08
7 4.82 7.5 0.11
8 4.93 8.5 0.08
9 5.01 9.5 0.1
10 5.11 10.5 0.09
11 5.2 11.5 0.11
12 5.31 12.5 0.11
13 5.42 13.5 0.12
14 5.54 14.5 0.14
15 5.68 15.5 0.18
16 5.86 16.5 0.21
17 6.07 17.5 0.33
18 6.4 18.1 0.75
18.2 6.55 18.3 0.7
18.4 6.69 18.5 1.75
18.6 6.82 18.7 6
18.8 7.04 18.9 8.6
19 8.24 19.1 1.85
19.2 9.96 19.3 3.05
19.4 10.33 19.5 0.85
19.6 10.94 19.7 0.85
19.8 11.11 19.9 0.7
20 11.28 20.1 0.6
20.2 11.42
20.4 11.54

mL Adicionados pH x ΔpH/Δv

0 3.96 0.5 0.15


1 4.11 1.5 0.13
2 4.24 2.5 0.1
3 4.34 3.5 0.19
4 4.53 4.5 0.1
5 4.63 5.5 0.1
6 4.73 6.5 0.12
7 4.85 7.5 0.09
8 4.94 8.5 0.08
9 5.02 9.5 0.11
10 5.13 10.5 0.1
11 5.23 11.5 0.09
12 5.32 12.5 0.11
13 5.43 13.5 0.11
14 5.54 14.5 0.15
15 5.69 15.5 0.15
16 5.84 16.5 0.19
17 6.03 17.5 0.37
18 6.4 18.1 0.55
18.2 6.51 18.3 0.85
18.4 6.68 18.5 1
18.6 6.88 18.7 0.9
18.8 7.06 18.9 4.15
19 7.89 19.1 11.25
19.2 10.14 19.3 2.75
19.4 10.69 19.5 1.7
19.6 11.03 19.7 1
19.8 11.23 19.9 0.85
20 11.4 20.1 0.55
20.2 11.51
20.4 11.6
Curva de titulacion
4

0
0 5 10 15 20 25

Derivada de titulacion
12

10

0
0 5 10 15 20 25
Normalidad por peadas
Patron Primario Biftalato de Sodio PM del Patron Primario 204.23
#cargas 1 #Datos 3
Normalidad Teorica 0.1
Muestra Peso de Patron Primario(g) Volumen Ocupado(L) Concentracion
1 0.4083 1.89E-02 1.05779E-01
2 0.4081 1.89E-02 1.05727E-01
3 0.4084 1.91E-02 1.04697E-01
4
5
Promedio %E S CV
1.05401E-01 5.4007183872 0.0008630694 0.8188458673

Normalidad por alicuota CH3COOH


Patron Primario NaOH PM del Patron Primario 204.23
#cargas 1 #Datos 3
Normalidad Patron Primario 0.1054 Normalidad Teorica 0.1
Muestra Volumen de Patron Priario(g) Volumen Ocupado(L) Concentracion
1 1.46E-01 1.50E-02 1.02589E+00
2 1.46E-01 1.50E-02 1.02589E+00
3 1.46E-01 1.50E-02 1.02589E+00
4
5
Promedio %E S CV
1.02589E+00 925.893333333 0 0

Normalidad por alicuota HCL


Patron Primario NaOH PM del Patron Primario 204.23
#cargas 1 #Datos 3
Normalidad Patron Primario 0.1054 Normalidad Teorica 0.1
Muestra Volumen de Patron Priario(g) Volumen Ocupado(L) Concentracion
1 9.00E-02 1.00E-02 9.48600E-01
2 9.10E-02 1.00E-02 9.59140E-01
3 9.00E-02 1.00E-02 9.48600E-01
4
5
Promedio %E S CV
0.952113 852.113333333 0.008605874 0.9038707538
Molaridad por alicuotas
Acido debil-Base Fuerte
Molaridad de Acido 0.1 Volumen Inicial (ml) 15
Molaridad de Base 0.1 Volumen Agregado (mL) 0.2
Particiones 75 #Cargas o Equivalencia 1
Kb (Base) 0.000060256 pkb (Base) 4.22
Moles B 0.0015 Concentracion Rx 0.1
Ka (Acido) 1 pka(Acido) 0
Volumen agregado
Acido Moles de A pH Constante de
equilibrio de
0 0 9.61 Reaccion
0.2 0.00002 9.5892317197 16595.8690743756
0.4 0.00004 9.2822928645
0.6
0.8
0.00006
0.00008
9.1002112417
8.9691983574 ε
1 0.0001 8.8661280357 0.0245470892
1.2 0.00012 8.7806978404
1.4 0.00014 8.7074108727 %P(Cuantitividad)
1.6 0.00016 8.6429848157
1.8 0.00018 8.5853014261 97.5452910843
2 0.0002 8.5329133566
2.2 0.00022 8.4847872888
2.4 0.00024 8.4401593034
2.6 0.00026 8.3984483372
2.8 0.00028 8.3592017993
3 0.0003 8.3220599913
3.2 0.00032 8.286732029
3.4 0.00034 8.2529790722
3.6 0.00036 8.2206023506
3.8 0.00038 8.1894344261
4 0.0004 8.1593326938
4.2 0.00042 8.1301744651
4.4 0.00044 8.1018531888
4.6 0.00046 8.0742755076
4.8 0.00048 8.0473589344
5 0.0005 8.0210299957
5.2 0.00052 7.9952227321
5.4 0.00054 7.9698774732
5.6 0.00056 7.9449398266
5.8 0.00058 7.9203598338
6 0.0006 7.8960912591
6.2 0.00062 7.8720909827
6.4 0.00064 7.8483184773
6.6 0.00066 7.8247353505
6.8 0.00068 7.8013049397
7 0.0007 7.777991947
7.2 0.00072 7.7547621063
7.4 0.00074 7.7315818725
7.6 0.00076 7.7084181275
7.8 0.00078 7.6852378937
8 0.0008 7.662008053
8.2 0.00082 7.6386950603
8.4 0.00084 7.6152646495
8.6 0.00086 7.5916815227
8.8 0.00088 7.5679090173
9 0.0009 7.5439087409
9.2 0.00092 7.5196401662
9.4 0.00094 7.4950601734
9.6 0.00096 7.4701225268
9.8 0.00098 7.4447772679
10 0.001 7.4189700043
10.2 0.00102 7.3926410656
10.4 0.00104 7.3657244924
10.6 0.00106 7.3381468112
10.8 0.00108 7.3098255349
11 0.0011 7.2806673062
11.2 0.00112 7.2505655739
11.4 0.00114 7.2193976494
11.6 0.00116 7.1870209278
11.8 0.00118 7.153267971
12 0.0012 7.1179400087
12.2 0.00122 7.0807982007
12.4 0.00124 7.0415516628
12.6 0.00126 6.9998406966
12.8 0.00128 6.9552127112
13 0.0013 6.9070866434
13.2 0.00132 6.8546985739
13.4 0.00134 6.7970151843
13.6 0.00136 6.7325891273
13.8 0.00138 6.6593021596
14 0.0014 6.5738719643
14.2 0.00142 6.4708016426
14.4 0.00144 6.3397887583
14.6 0.00146 6.1577071355
14.8 0.00148 5.8507682803
15 0.0015 3.5219543705
15.2 0.00152 2.8181564121
15.4 0.00154 2.8124792792
15.6 0.00156 2.8068754016
15.8 0.00158 2.801342913
16 0.0016 2.7958800173
16.2 0.00162 2.7904849855
16.4 0.00164 2.785156152
16.6 0.00166 2.779891912
16.8 0.00168 2.7746907183
17 0.0017 2.7695510786
17.2 0.00172 2.7644715531
17.4 0.00174 2.7594507517
17.6 0.00176 2.7544873322
17.8 0.00178 2.7495799977
18 0.0018 2.7447274949
18.2 0.00182 2.739928612
18.4 0.00184 2.735182177
18.6 0.00186 2.7304870558
18.8 0.00188 2.7258421507
19 0.0019 2.721246399
19.2 0.00192 2.7166987713
19.4 0.00194 2.7121982701
19.6 0.00196 2.7077439286
19.8 0.00198 2.7033348097
20 0.002 2.6989700043
20.2 0.00202 2.6946486306
20.4 0.00204 2.6903698326
20.6 0.00206 2.6861327796
20.8 0.00208 2.681936665
21 0.0021 2.6777807053
21.2 0.00212 2.6736641391
21.4 0.00214 2.6695862267
21.6 0.00216 2.6655462488
21.8 0.00218 2.6615435064
22 0.0022 2.6575773192
22.2 0.00222 2.6536470255
22.4 0.00224 2.6497519817
22.6 0.00226 2.6458915609
22.8 0.00228 2.642065153
23 0.0023 2.638272164
23.2 0.00232 2.6345120151
23.4 0.00234 2.6307841426
23.6 0.00236 2.627087997
23.8 0.00238 2.6234230429
24 0.0024 2.6197887583
24.2 0.00242 2.616184634
24.4 0.00244 2.6126101737
24.6 0.00246 2.6090648929
24.8 0.00248 2.6055483192
25 0.0025 2.6020599913
25.2 0.00252 2.5985994592
25.4 0.00254 2.5951662834
25.6 0.00256 2.5917600347
25.8 0.00258 2.588380294
26 0.0026 2.585026652
26.2 0.00262 2.5816987087
26.4 0.00264 2.5783960731
26.6 0.00266 2.5751183634
26.8 0.00268 2.571865206
27 0.0027 2.5686362358
27.2 0.00272 2.565431096
27.4 0.00274 2.5622494372
27.6 0.00276 2.5590909179
27.8 0.00278 2.5559552041
28 0.0028 2.5528419687
28.2 0.00282 2.5497508917
28.4 0.00284 2.54668166
28.6 0.00286 2.5436339669
28.8 0.00288 2.5406075122
29 0.0029 2.5376020021
Acido debil-Base Fuerte
12

10

0
0 5 10 15 20 25 30 35