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International Journal of Pavement Research and Technology 11 (2018) 655–665
www.elsevier.com/locate/IJPRT

Effect of blending time on viscosity of rubberized binders with


wax additives
Hyun Hwan Kim a, Mithil Mazumder a, Moon-Sup Lee b, Soon-Jae Lee a,⇑
a
Texas State University, San Marcos, TX 78666, United States
b
Korea Institute of Civil Engineering and Building Technology, Gyeonggi 10223, South Korea

Received 12 April 2017; received in revised form 3 August 2017; accepted 19 March 2018
Available online 24 March 2018

Abstract

The effect of blending time on the viscosity of rubberized binder with wax additives was evaluated through the rotational viscometer at
135 °C and 120 °C. The 10% crumb rubber modified (CRM) binders were produced with four blending periods (1, 30, 60, and 90 min),
and then mixed with two commercial wax additives. Three different testing periods of 30, 120, and 240 min were applied to the rotational
viscosity test to evaluate the viscous properties depending on the blending time. From the results, it is concluded that (1) the addition of
wax additives can significantly decreases the binder viscosity, (2) all the viscosity values of CRM binders are observed to increase after
certain time, regardless of the addition of wax additives, (3) CRM mixes with wax additives are expected to have a better haul manage-
ment, based on the less viscosity change, (4) in general, the effect of blending time at 177 °C on the viscous property of CRM binder is
found to be insignificant.
Ó 2018 Chinese Society of Pavement Engineering. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND
license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Keywords: CRM; Wax additive; Blending time; Rotational viscosity

1. Introduction The blending time required to interact the crumb rubber


with an asphalt binder is dependent on many factors
The use of crumb rubber to modify asphalt binder in including the chemistry of asphalt binder and crumb
pavement engineering began more than four decades ago rubber as well as the particle size and texture of the crumb
in the United States. The most important motivation rubber [8]. The binder interaction with crumb rubber is a
behind this application was the improvement of pave- complex chemical action which is not clearly identified
ment’s quality, including decreased traffic noise, reduced yet. Therefore, the blending time for CRM binder is one
maintenance costs and resistance to rutting and cracking of the important variables that can directly affect the binder
[5,9,10,13,18,20,24]. Furthermore, the disposal of scrap property.
tires has been a serious issue due to many reasons (e.g., lack Warm mix asphalt (WMA) technologies have potential
of landfill space, environmental issues, etc.). to reduce the mixing and compaction temperatures of hot
mix asphalt (HMA) and improve workability without com-
promising the performance of asphalt pavement. This
⇑ Corresponding author. promises various benefits including less fuel consumption,
E-mail addresses: k_h82@txstate.edu (H.H. Kim), m_m624@txstate. longer paving seasons, longer hauling distances, earlier
edu (M. Mazumder), truepath@kict.re.kr (M.-S. Lee), SL31@txstate.edu traffic opening, reduced binder aging, and reduced cracking
(S.-J. Lee). [1–4,6,7,9]. In general, two methods have been used to add
Peer review under responsibility of Chinese Society of Pavement
Engineering.
crumb rubber into the asphalt, the dry method and the wet

https://doi.org/10.1016/j.ijprt.2018.03.003
1996-6814/Ó 2018 Chinese Society of Pavement Engineering. Production and hosting by Elsevier B.V.
This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
656 H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665

PG 64-22

CRM binder production


- 10% by binder wt
-177

Blending time Blending time Blending time Blending time


1 minute 30 minutes 60 minutes 90 minutes
(1) (2) (3) (4)

Same Testing Procedures Same Testing Procedures Same Testing Procedures


as (3) as (3) as (3)

CRM binder : CRM binder with CRM binder with


No Wax additive LEADCAP Sasobit

Rotational Viscosity (RV) test


- Testing Temperatures: 135 and 120
- Testing Periods: 30, 120, and 240 minutes

Fig. 1. Flow chart of experimental design procedures.

Table 1
Properties of base asphalt binder (PG 64-22).
Aging states Test properties Test result
Unaged binder Viscosity @ 135 °C (cP) 531
G*/sin d @ 64 °C (kPa) 1.42
RTFO aged residual G*/sin d @ 64 °C (kPa) 2.53
RTFO + PAV G sin d @ 25 °C (kPa)
*
2558
aged residual Stiffness @ 12 °C (MPa) 287
m-value @ 12 °C 0.31

Table 2 efficient in improving properties of an asphalt mixture [22].


Gradation of crumb rubber used in this study. In the wet process, the viscosity of CRM binder increases
Sieve number (lm) % Cumulative passing rapidly with mixing time for roughly the first 80–90 min
30 (600) 100.0 of the measurements. Subsequently, a gradual increase in
40 (425) 91.0 viscosity is observed to be linear with time [21,17]. The
50 (300) 59.1 gradual viscosity increase can be explained due to the
80 (180) 26.2 amount of aromatic oil absorption and rubber particle
100 (150) 18.3
200 (75) 0.0
swelling. It was reported that as the percentage of rubber
increased the effects the rubber had on the viscosity
increased significantly [14]. The viscosity increase of
CRM binder negatively effects on workability of asphalt
mixture.
method. In the dry method, the rubber is used as an aggre- Insufficient blending time may be considered as one of
gate replacement. The more common method, referred to the main reasons for the gradual viscosity increase of
as the wet process, consists of the addition of the rubber CRM binder. Moreover, the addition of wax additive into
to the asphalt binder. The wet process is known to be more CRM binder can be a potential solution to reduce the
H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665 657

Fig. 2. Wax additives; (a) LEADCAP and (b) Sasobit.

Fig. 3. Viscosity of CRM binders with wax additive at 135 °C as a function of blending time.

binder viscosity [1,9]. In general, wax shows a softening 2.1. Materials


effect on the binder and asphalt mix due to the lower melt-
ing point compared to asphalt binder. Therefore, wax can Performance grade (PG) 64-22 asphalt binder was used
be used as a flow improver, and the main purpose of such as a base binder for this study. The binder properties are
an addition is to reduce the production temperature of the represented in Table 1. The crumb rubber included in this
asphalt mixture in the plant. study was obtained from one source. This source used the
mechanical shredding method to process scrap passenger
2. Experimental design tires into crumb rubber. Table 2 shows a gradation of
crumb rubber. In general, the CRM binders were produced
This study was performed to evaluate the effect of with an open blade mixer (700 rpm) under the following
blending time on viscosity of CRM binder containing mixing conditions: temperature of 177 °C and a blending
wax additives. The base binder was blended with crumb time of 30 min [11,12,16]. Although a blending time of
rubber using four blending periods (1, 30, 60, and 90 30 min is used in the general method, the four blending
min). The viscosity changes of rubberized asphalt binders periods (1, 30, 60, and 90 min) were used in this study.
containing wax additive were evaluated through rota- The percentage of crumb rubber added for CRM binder
tional viscometer (RV) test using two testing tempera- was 10% by weight of the base binder. To ensure that the
tures (135 °C and 120 °C) and three periods (30, 120, consistency of the CRM was maintained throughout the
and 240 min). Fig. 1 shows a flow chart of the experi- study, only one batch of crumb rubber was used in this
mental design used in this study. study.
658 H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665

Fig. 4. Viscosity change during 120 min at 135 °C. 1 min, (b) 30 min, (c) 60 min, and (d) 90 min.

Two commercial wax additives of LEADCAP and Saso- 2.2. Rotational viscosity (RV) test
bit were selected to add into the CRM binder. The process
included the addition of additive at a specified concentra- The RV test was conducted to evaluate the effect of
tion (1.5% by the weight of the CRM binder) followed blending time on the viscosity of CRM binders containing
by hand mixing for a minute to achieve a consistent mixing. wax additives. A Brookfield rotational viscometer was used
The concentration of 1.5% was suggested by the to measure the viscosity at 135 °C (the standard test tem-
manufacturer. perature) and at 120 °C (the mixing temperature generally
The LEADCAP is classified as an organic WMA addi- used for warm mix asphalt). Three testing periods (i.e., 30,
tive, which is a wax-based composition including crystal 120, and 240 min) were applied to evaluate the viscosity
controller to adjust crystalline degree of wax material at change by different testing time considerations. The 30
the low temperature and adhesion promoter to enhance min is considered as standard testing time. To evaluate
adhesion between asphalt and aggregate [9]. Sasobit is a the effect of longer haul distance (and period) of CRM mix-
product of Sasol Wax. It is a long chain aliphatic hydrocar- ture, the viscosity change was measured for the 120 min
bon obtained from coal gasification using the Fischer– and the 240 min. A 10.5 g sample of CRM binders was
Tropsch process. After crystallization, it forms a lattice tested with a number 27 spindle in the viscometer. Three
structure in the binder which is the basis of the structure duplicate samples were tested and the results were reported
stability of the binder containing Sasobit [19]. These two as the average. For all binders, each specimen was poured
wax additives are shown in Fig. 2. just prior to testing.
H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665 659

Fig. 5. Viscosity change during 240 min at 135 °C. 1 min, (b) 30 min, (c) 60 min, and (d) 90 min.

Fig. 6. Viscosity of CRM binders with wax additive at 120 °C as a function of blending time.
660 H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665

Table 3
Increase rate of viscosity for the CRM binder with wax additive at 135 °C.
Temperature Blending time Minutes Increase rate (%)
CRM CRM + L CRM + S
135 °C 1 min 30 0.0* 0.0 0.0
60 10.9** 5.0 7.9
90 17.4*** 10.6 14.6
120 19.6 14.6 18.8
150 21.1 16.5 21.2
180 21.1 18.3 21.9
210 21.1 20.0 23.4
240 21.1 20.8 23.4
30 min 30 0.0 0.0 0.0
60 4.3 2.6 2.6
90 8.3 6.3 8.5
120 12.0 9.6 12.8
150 14.6 13.8 15.7
180 17.0 15.7 17.6
210 18.5 17.6 17.6
240 19.3 19.4 19.4
60 min 30 0.0 0.0 0.0
60 4.1 5.4 4.6
90 9.6 8.4 9.8
120 14.5 10.3 13.5
150 19.0 12.1 15.3
180 21.0 13.9 17.8
210 23.6 14.7 18.6
240 24.8 16.3 20.2
90 min 30 0.0 0.0 0.0
60 4.3 3.5 4.6
90 9.1 7.8 8.8
120 12.6 13.5 11.7
150 15.1 17.0 13.5
180 16.7 19.4 15.3
210 18.2 21.7 17.0
240 18.9 22.4 17.8
n o
Viscosity at30min
*
1 Viscosity at30min  100%.
n o
Viscosity at30min
**
1 Viscosity at60min  100%.
n o
Viscosity at30min
***
1 Viscosityat90min  100%.

2.3. Statistical analysis method pared. If the difference between two sample means was
greater than or equal to the LSD, the population means
A statistical analysis was performed using the Statistical were declared to be statistically different [15].
Analysis System (SAS) program to conduct an analysis of
variance (ANOVA) and Fisher’s Least Significant Differ- 3. Results and discussions
ence (LSD) comparison with an a = 0.05. The primary
variables included the blending periods (1, 30, 60, 90 min) 3.1. Rotational viscosity at 135 °C (standard test)
and the wax types (Control, LEADCAP, and Sasobit).
The ANOVA was performed first to determine whether The viscosity of asphalt binders at high temperature is
significant differences among sample means existed. In the considered to be one of the important properties since it
analyses of this study, the significance level was .95 represents binder’s ability to be pumped through an
(a = 0.05), indicating that each finding had a 95% chance asphalt plant, thoroughly coat aggregate in asphalt con-
of being true. Upon determining that there were differences crete mix, and be placed and compacted to form a new
among sample means using the ANOVA, the LSD was pavement surface [23]. Fig. 3 shows the high temperature
then calculated. The LSD is defined as the observed differ- viscosity of the 10% CRM binder, the CRM binder with
ences between two sample means necessary to declare the LEADCAP, and the CRM binder with Sasobit as a blend-
corresponding population means difference. Once the ing time, at 177 °C, increases from 1 to 90 min. Although
LSD was calculated, all pairs of sample means were com- the viscosity of 10% CRM binder increases with blending
H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665 661

Fig. 7. Viscosity change during 120 min at 120 °C. 1 min, (b) 30 min, (c) 60 min, and (d) 90 min.

time (except for 90 min), the increasing rate is not signifi- values than the maximum requirement (3000 cP) at
cant. The increasing rate (0%, 4% and 8% increase for 1, 135 °C suggested by Superpave.
30 and 60 min blending time, respectively) seemed to have
linear relationship with blending time. In general, the CRM
binders with LEADCAP were found to have similar 3.2. Rotational viscosity as a function of time at 135 °C
decreasing rate at all blending times. The similar trend
has been observed for the CRM binder containing Sasobit. While the addition of warm additives can significantly
At 135 °C, with 90 min blending time, the average decreas- decrease the viscosity, the gradual increase of viscosity of
ing rate of viscosity due to the addition of wax additives is CRM binder over time is mentioned in previous study
higher compared to the other blending time. The addition [14]. The viscosity of all the binders was measured and
of wax additives into the CRM binder was efficient to recorded during 120 and 240 min to evaluate the change
reduce the viscosity of the binder regardless of blending of viscosity over a long period. Fig. 4 shows the change
time. The viscosity of the binders with 1 min blending time of the viscosity as a blending time increases from 1 to 90
showed relatively low values whereas the binders with 60 min. The viscosities of all the binders were found to have
min blending time have the highest viscosity value among gradually increased after 15–30 min regardless of blending
all the binders. In addition, both wax additives exhibited time, as expected. Although the addition of wax additives
similar viscous performance, indicating that the specific reduced the viscosity of the binder, the warm CRM binder
difference depending on the additives was not observed in also showed gradual increase of viscosity over time. The
the viscosity result. All viscosity results showed much less viscosity curves over 120 min of CRM binder without
662 H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665

Fig. 8. Viscosity change during 240 min at 120 °C. 1 min, (b) 30 min, (c) 60 min, and (d) 90 min.

wax additives were formed at highest position and the gap regardless of blending time. In general, the gap between
between control CRM binder and warm CRM binders was control CRM binder and the warm CRM binder was
found to have little change over the whole testing period. observed to be gradually increased over 240 min Fig. 6.
This result indicates that the addition of wax additives into Table 3 exhibits the increase rate of viscosity of CRM
CRM binder is effective irrespective of blending time of binders over a long period at 135 °C. For each blending
CRM binder. In most cases the gap between the binders time, eight different time periods with a 30 min interval
containing wax additives was negligible, suggesting that period over the 240 min were selected. The increase rate
both the additives have similar performance in terms of of viscosity was measured. The viscosity of all the CRM
reducing the viscosity. No significant change has been binders is observed to have the increase rate between 16%
observed as a function of blending times over 120 min. and 24% at the end of 240 min. Even though there was
One of the benefits of wax additive is to increase the slight difference by the binder type at the same blending
hauling distance and period by reducing the viscosity of time, there was no significant difference due to the blending
the binder. The haul management of asphalt mixture usu- time. While the additives resulted in the lower viscosity
ally depends on the binder viscosity. The viscosity change values than the control CRM binder, the viscosity of warm
was observed for 240 min to evaluate the longer haul man- CRM binders steadily increased over the whole testing
agement of CRM binder. The results are shown in Fig. 5 period.
which presents the time versus viscosity curve over 240
min at 135 °C. It is clear that the viscosity of CRM binders 3.3. Rotational viscosity at 120 °C
at any blending time was increased over time. The viscosity
curves were gradually increased approximately after 20 The rotational viscosity test was performed at 120 °C
min. Also, the difference between the two viscosity curves that is typically a mixing temperature for WMA mixture.
of CRM binder containing wax additives was insignificant With the test temperature decreased, the viscosity of the
H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665 663

Table 4
Increase rate of viscosity for the CRM binder with wax additive at 120 °C.
Temperature Blending time min Increase rate (%)
CRM CRM + L CRM + S
120 °C 1 min 30 0.0* 0.0 0.0
60 2.6** 0.6 1.9
90 2.6*** 0.6 4.9
120 2.6 1.8 6.6
150 3.2 3.5 7.4
180 2.6 4.6 8.2
210 2.6 5.1 9.0
240 2.1 5.6 9.8
30 min 30 0.0 0.0 0.0
60 1.8 1.8 0.6
90 2.3 2.4 0.6
120 1.4 1.8 1.2
150 1.8 1.2 1.7
180 0.9 0.6 2.9
210 0.5 0.6 3.4
240 0.5 1.1 4.0
60 min 30 0.0 0.0 0.0
60 0.5 1.0 0.0
90 0.5 0.0 1.0
120 0.5 1.0 2.5
150 0.9 2.5 5.0
180 2.3 4.0 5.4
210 2.8 5.4 6.8
240 3.2 6.3 7.7
90 min 30 0.0 0.0 0.0
60 1.4 0.6 0.5
90 0.0 0.6 1.1
120 0.0 1.6 2.6
150 0.9 3.2 3.6
180 1.8 4.3 5.6
210 2.3 5.8 6.5
240 2.3 6.3 7.0
n o
Viscosity at 30 min
*
1 Viscosity at 30 min  100%.
n o
Viscosity at 30 min
**
1 Viscosity at 60 min  100%.
n o
Viscosity at 30 min
***
1 Viscosity at 90 min  100%.

binders was increased at all blending time. Also, it is clear cosity of the binders measured at 120 °C exhibited higher
that the wax additives can significantly reduce the viscosity values than the binders at 135 °C, all values satisfied the
in the CRM binder. This effect is consistent for the tests requirement (maximum 3000 cP) suggested by Superpave.
done with all CRM binders containing the additives. At
120 °C the viscosity of CRM binder increases with the
blending time like at 135 °C. The CRM binder with 3.4. Rotational viscosity as a function of time at 120 °C
LEADCAP was found to have 20.6% decrease in viscosity
value with 30 min blending time whereas for the other Fig. 7 illustrates the viscosity change of CRM binders
blending times the decreasing rate is in between 9.5% and over 120 min at 120 °C. The results showed a similar trend
15.1%. Similar trend has been observed for the binder with with the findings at 135 °C. The viscosity seemed to
Sasobit where the decreasing rate is 20.3% with 30 min increase approximately after 20 min. Unlike at 135 °C,
blending time. It suggests that the blending period of 30 the viscosity of the CRM binders increased steadily over
min is effective for decreasing the viscosity value of CRM 120 min at 120 °C. Also, the gap between the viscosity
binders by the addition of wax additives. In addition, the curves of control CRM binders and warm CRM binders
decreasing rate of viscosity at 120 °C was higher than at was higher than the results at 135 °C. It suggests that the
135 °C irrespective of the blending time, suggesting that addition of wax additives into the CRM binder is more
the addition of wax additive is more efficient to reduce influential at lower temperatures. In addition, among all
the viscosity of the binder at 120 °C. Even though the vis- the blending times the gap between the CRM binder and
664 H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665

Table 5
Statistical analysis results of the viscosity value as a function of binder type and blending time (a) 135 °C and (b) 120 °C.
(a)
Viscosity 1 min 30 min 60 min 90 min
1* 2 3 1 2 3 1 2 3 1 2 3
1 min 1 – S S N N N S S N S N N
2 – N S N N S S S S S S
3 – S N N S S N S S N
30 min 1 – S S N N S N N S
2 – N S S N S N N
3 – S S N S N N
60 min 1 – N S N S S
2 – S N S S
3 – S N N
90 min 1 – S S
2 – N
3 –
(b)
Viscosity 1 min 30 min 60 min 90 min
*
1 2 3 1 2 3 1 2 3 1 2 3
1 min 1 – S S S S S S N N S N S
2 – N S N N S S S S S S
3 – S N N S S S S S S
30 min 1 – S S N S S N S S
2 – N S S S S S N
3 – S S S S S S
60 min 1 – S S N S S
2 – N S N N
3 – S N N
90 min 1 – S S
2 – N
3 –
N: non-significant, S: significant.
*
CRM binder containing wax additive 1: CRM binder (Control). 2: CRM binder + 1.5% LEADCAP. 3: CRM binder + 1.5% Sasobit.

CRM binder containing wax additives is found to be bigger 3.5. Statistical analysis
with 30 min blending periods. There is no significant differ-
ence between the viscosity curves of two wax additives. It The statistical significance of the change in the viscosity
indicates that the wax additives have maintained similar as a function of binder type and blending time was exam-
viscous performance at lower temperature. ined and the results are shown in Table 5. In general, the
The viscosity change for 240 min is exhibited in Fig. 8. data indicated that the blending time has an insignificant
The similar trend of viscosity change during 120 min was effect on the viscosity of the warm CRM binders. It is evi-
noticed for 240 min. In general, there was no significant dent that the differences of viscosity between the control
change observed due to different blending periods. The CRM binders and two warm CRM binders at both testing
decreasing rate of viscosity by the addition of wax additives temperatures were statistically significant for all blending
is observed to be increased when compared to the results at times used in this study. The viscosity of control CRM bin-
135 °C. der with 1 min blending period seemed to have significant
For more detailed analysis, the increase rates at 120 °C differences with other blending periods at both testing tem-
were calculated and the results are shown in Table 4. There peratures. At 135 °C, with 1 min blending period, the bin-
was little change in the viscosity of CRM binders over the ders containing Sasobit has insignificant differences with
long period at 120 °C, compared to the results at 135 °C. other blending time whereas at 120 °C the opposite trend
In most cases, the maximum increase rate of viscosity of has been observed (except 30 min blending time). In gen-
CRM binder was over 20% at 135 °C whereas at 120 °C eral, the warm CRM binders with 30 min blending time
the increase rate was less than 10%. This result suggests that are found to have significant difference at 120 °C with the
the CRM mixes containing the warm additives can provide other blending periods. However, at 135 °C the difference
better haul management, based on the less increase rate of was non-significant. In most cases, the differences between
viscosity over a long period of time at lower temperatures. the CRM binder containing LEADCAP and the CRM
H.H. Kim et al. / International Journal of Pavement Research and Technology 11 (2018) 655–665 665

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