Reacción 6 Conv m-X 0.

23076923

DTBB 2 1
m-X 1.3 0.3
TMBX 0 0.3
TBB 0 0.3

Reacción 7 Conv TBB 0.7

TBB 1 0.3
m-X 1.3 0.6
TMBX 0 0.5
B 0 0.5

0.61538462

0.53846154 0.23076923
0.57692308
0.46153846
0.23076923
0.15384615
 134.22 106.16 162.27 78.11
1 0.5
1.3 0.8
0 0.5 272.228
0 0.5 272.228
BALANCE DE MATERIA
PM
mol/(g h atm^2) Producción kg/kmol
k1 0.3293552 100000000 kg pX/año
Conversión
k2 0.51326851 941974.378 kmol/año tolueno 1ª
reacción

k3 0.00992986 118.936159 kmol/h

k4 0.01808235 0.80405 Pureza para-

xileno
Reacciones
T R1 0.83 Sel p-X R1 0.977 4y5
Porcentaje
Conv met R1 0.6 T R3 0.17 metanol
consumido
S met R1 0.6
S R4 R5 0.05 benceno R3 0.3
% met cons 0.84
0.6 149.897052

kmol/h Corriente 1 Corriente 2 Corriente 3 Corriente 4 Corriente 5

Tolueno C7H8 180.0 180.0 0.0 0.0 605.0
Metanol CH3OH 0.0 0.0 209.6 209.6 302.5
p-X p-C8H10 0.0 0.0 0.0 0.0 9.1
Agua H2O 0.0 0.0 0.0 0.0 7.4
Benceno C6H6 0.0 0.0 0.0 0.0 0.8
Etileno C2H4 0.0 0.0 0.0 0.0 0.3
m-X m-C8H10 0.0 0.0 0.0 0.0 0.0
o-X o-C8H10 0.0 0.0 0.0 0.0 0.0
TBB C18H30 0.0 0.0 0.0 0.0 0.0
DTBB C14H22 0.0 0.0 0.0 0.0 0.0
TMBX C12H18 0.0 0.0 0.0 0.0 0.0
TOTAL 180.0 180.0 209.6 209.6 925.1

kg/h Corriente 1 Corriente 2 Corriente 3 Corriente 4 Corriente 5

Tolueno C7H8 16585.13 16585.13 0.00 0.00 55744.70
Metanol CH3OH 0.00 0.00 6715.41 6715.41 9692.10
p-X p-C8H10 0.00 0.00 0.00 0.00 966.06
Agua H2O 0.00 0.00 0.00 0.00 133.35
Benceno C6H6 0.00 0.00 0.00 0.00 62.49
Etileno C2H4 0.00 0.00 0.00 0.00 8.42
 m-X m-C8H10 0.00 0.00 0.00 0.00 0.00
o-X o-C8H10 0.00 0.00 0.00 0.00 0.00
TBB C18H30 0.00 0.00 0.00 0.00 0.00
DTBB C14H22 0.00 0.00 0.00 0.00 0.00
TMBX C12H18 0.00 0.00 0.00 0.00 0.00
TOTAL 16585.13 16585.13 6715.41 6715.41 66607.11

c5 60095.1
60095.1

23815.410
23793.3358 60095.1

126.833708
 Tolueno Metanol p-X Agua Benceno Etileno m-X
92.14 32.04 106.16 18.02 78.11 28.05 106.16

Selectividad Selectividad
0.3 tolueno 1 ª 0.83 tolueno 3ª 0.17
reacción reacción

Selectividad
metanol 1ª 0.6
reacción

0.977

0.1

0.84 c5

Tol 545.0 605.0 Agua 6.655

Met 272.5 302.5 Benceno 0.6888
pX 9.0550 9.1000 Etileno 0.210
14.9897052

Corriente 5' Corriente 6 Corriente 7 Corriente 8 Corriente 9 Corriente 10 Corriente 11 Corriente 12

545.0 371.3 371.3 2.6 368.7 1.8 366.9 1.8
272.5 98.5 98.5 3.9 94.6 66.2 28.4 66.2
9.055 133.9 133.9 0.7 133.2 1.1 132.0 1.1
6.6555 180.6 180.6 10.8 169.8 166.4 3.4 166.4
0.6888 47.0 47.0 0.9 46.1 0.2 45.8 0.2
0.21001 46.7 46.7 39.7 7.0 2.1 4.9 2.1
0.0327 1.3201 1.3 0.0 1.3 0.0 1.3 0.0066
0.0327 1.3201 1.3 0.0 1.3 0.0 1.3 0.0066
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
834.2 880.6 880.6 58.7 822.0 237.9 584.0 237.9

28.0507763
Corriente 5' Corriente 6 Corriente 7 Corriente 8 Corriente 9 Corriente 10 Corriente 11 Corriente 12
50216.30 34212.03 34212.03 239.48 33972.55 169.86 33802.69 169.86
8730.90 3157.09 3157.09 126.28 3030.81 2121.57 909.24 2121.57
961.28 14209.55 14209.55 71.05 14138.51 120.18 14018.33 120.18
119.93 3254.76 3254.76 195.29 3059.48 2998.29 61.19 2998.29
53.80 3672.25 3672.25 73.44 3598.80 17.99 3580.81 17.99
5.89 1309.08 1309.08 1112.72 196.36 58.91 137.45 58.91
 3.48 140.14 140.14 0.56 139.58 0.70 138.88 0.70
3.48 140.14 140.14 0.56 139.58 0.70 138.88 0.70
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
60095.05 60095.05 60095.05 1819.38 58275.67 5488.19 52787.48 5488.19

27.1383506 58275.7 5488.2

58275.7 5488.2
 o-X TBB DTBB TMBX
106.16 134.22 190.32 162.27

7.4
0.8 0.4 1.2820873
0.3

Corriente 13 Corriente 14 Corriente 15 Corriente 16 Corriente 17 Corriente 18 Corriente 19 Corriente 20

366.9 0.0 1.8 0.0 0.4 3.3 363.2 363.2
28.4 0.7 62.9 2.6 0.6 27.8 0.0 0.0
132.0 0.0 1.1 0.0 0.0 0.0 132.0 7.9
3.4 0.0 6.7 159.7 0.1 3.3 0.0 0.0
45.8 0.0 0.2 0.0 0.9 44.5 0.5 0.5
4.9 1.9 0.2 0.0 3.8 1.1 0.0 0.0
1.3 0.0 0.0 0.0 0.0 0.0 1.3 0.026
1.3 0.0 0.0 0.0 0.0 0.0 1.3 0.0
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
584.0 2.6 73.0 162.4 5.7 80.0 498.3 371.6

Corriente 13 Corriente 14 Corriente 15 Corriente 16 Corriente 17 Corriente 18 Corriente 19 Corriente 20

33802.69 0.00 169.86 0.00 33.80 304.22 33464.66 33461.31
909.24 21.22 2015.49 84.86 18.18 891.06 0.00 0.00
14018.33 0.00 120.18 0.00 0.00 0.00 14018.33 841.10
61.19 0.00 119.93 2878.36 1.22 59.97 0.00 0.00
3580.81 0.00 17.99 0.00 71.62 3473.38 35.81 35.81
137.45 53.02 5.89 0.00 107.21 30.24 0.00 0.00
 138.88 0.00 0.70 0.00 0.00 0.00 138.88 2.78
138.88 0.00 0.70 0.00 0.00 0.00 138.88 2.78
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
52787.48 74.23 2450.74 2963.22 232.04 4758.87 47796.56 34343.78

52787.5 36794.5 47796.6

52787.5 36794.5 47796.6
0.38461538 Pureza
0.99825585

Corriente 21 Corriente 22 Corriente 23 Corriente 23 Solvent Corriente 24 Corriente 25 Corriente 26

0.0363 365.0 365.0 365.0 0.0 0.0 0.0 0.015
0.0 62.9 62.9 62.9 0.0 0.0 0.0 0.0
124.1 9.1 9.054984 9.1 0.0 121.6 2.5 2.4
0.0 6.7 6.655 6.7 0.0 0.0 0.0 0.0
0.0 0.7 0.6888 0.7 0.0 0.7 0.0 0.6930693
0.0 0.2 0.210 0.2 0.0 0.0 0.0 0.0
1.3 0.0 0.0 0.0 0.0 0.0 0.0 0.0
1.3 0.0 0.0 0.0 0.0 0.2 1.1 0.0
0.0 0.0 0.0 0.0 1.0 0.0 0.6 0.0
0.0 0.0 0.0 0.0 2.0 0.0 2.0 0.0
0.0 0.0 0.0 0.0 0.0 0.0 0.7 0.0
126.7 444.6 444.6 444.6 3.0 122.6 6.9 3.1

Corriente 21 Corriente 22 Corriente 23 Corriente 23 Solvent Corriente 24 Corriente 25 Corriente 26

3.35 33631.17 33631.17 33631.17 0.00 3.35 0.00 1.34
0.00 2015.49 2015.49 2015.49 0.00 0.00 0.00 0.00
13177.23 961.28 961.28 961.28 0.00 12913.68 263.54 258.27
0.00 119.93 119.93 119.93 0.00 0.00 0.00 0.00
0.00 53.80 53.80 53.80 0.00 54.68 0.00 54.14
0.00 5.89 5.89 5.89 0.00 0.00 0.00 0.00
 136.11 3.48 3.48 3.48 0.00 0.00 0.00 0.00
136.11 3.48 3.48 3.48 0.00 19.05 117.05 0.00
0.00 0.00 0.00 0.00 134.23 0.00 79.98 0.00
0.00 0.00 0.00 0.00 380.64 0.00 380.64 0.00
0.00 0.00 0.00 0.00 0.00 0.00 113.60 0.00
13452.79 36794.52 36794.52 36794.52 514.87 12990.77 954.82 313.75

13967.7 13945.6 12990.8 12990.8

13967.66
13945.59
Corriente 27
0.022
0.0
119.2
0.0
0.0070007
0.0
0.0
0.2
0.0
0.0
0.0
119.4

Corriente 27
2.01
0.00
12655.41
0.00
0.55
0.00
 0.00
19.05
0.00
0.00
0.00
12677.02