Fiitjee Phase Test Paper

FIITJEE - JEE (Mains)
PHYSICS, CHEMISTRY & MATHEMATICS

JEE – MAINS- 2020
CODE:
SET-A
Time Allotted: 3 Hours Maximum Marks: 360
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4. The Test Booklet consists of 90 questions. The maximum marks are 360.
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having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct
response.
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TWO YEAR CRP C-LOT (1820) MAINS (PCM) SET-A
Useful Data Chemistry:

Gas Constant = 8.314 J K1 mol1
R
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56, Mn=55,
Pb=207,
Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
PART –A (PHYSICS)
dN
1. For a sample of gas with N0 number of molecules,  av 2 for, O  v  v 0 and zero for
dVv
v  v 0 a is a constant R.M.S speed of the molecules is
(A) v 0 2 / 5 (B) v 0 3 / 5 (C) v 0 4 / 5 (D) v 0
2. A tube shaped ring, is separated into two parts by a fixed P

partition at P and movable partition at Q. It carries equal
masses of O2 and N2 in the two parts. Consider the gases
to be ideal and tube to the frictionless. The angle θ in
equilibrium is – θ N2
(A) 7  / 8 (B) 15  / 16
(C) 16  / 15 (D) 8  / 7
O2
Q
3. An ideal gas is following a process where P  P0  aV 2 .Pressure of the gas when

temperature is maximum is
(A) P0 / 3 (B) 2P0 / 3 (C) P0 (D) None of these
4. A heater is supplying heat at constant rate q J/S to n moles of an P2

ideal monoatomic gas confined in a cylindrical container with
m A
movable piston of mass m, such that the piston moves with
2q
constant speed, v  ; P is:
P  mg  P0 A 
(A) 1 (B) 3
(C) 5 (D) 7
5. One mole of a diatomic gas undergoes through a process P  aT 2 where a is a constant.

Molar specific heat of the gas is
3R 5R 7R
(A) (B) (C) (D) None of these
2 2 2
Space for rough work
6. An ideal gas is taken through a cyclic process ABCDA. P

The amount of work done by the gas in this process is 3 atm B
about 

(A)  10 5 J (B)   10 5 J A C
2
(C) 2   10 5 J (D)   10 3 J
1atm 
D
V
1m3 5m3
7. A spring is stretched by 2 cm under a tension of 540 N. Work done by the force is

(A) 2.7 J (B) 5.4 J
(C)27 J (D) 54 J
8. Two wires of same material has lengths in the ratio 1 : 2 and radius in the ratio 2:1. If equal
load is hanged from them, then the ratio of their elongation is –
(A) 1 : 2 (B) 1 : 4
(C) 1 : 8 (D) 8 : 1
9. Two wires, separated by 90 cm, holds a platform horizontally.

The radius and Young’s modulus of left and right wires are r
and 2r and Y and 2Y respectively. An external force F is
applied on the platform at a distance x from the left wire such
that the platform still remains horizontal. The value of x is.
(A) 40 cm (B) 50 cm x
(C) 60 cm (D) 80 cm F
10. Two rods of lengths, Young’s modulus and coefficient of

linear expansion, l1 , Y1 , 1 and l 2 ,Y2 , 2 ; having same cross
sectional area A are connected at one end and placed
between two rigid supports. If temperature is now
increased by  , then force exerted by the rods on one l1 Y1 1 l 2 Y2  2
another is -
 l   l  Y Y A
(A) 1 1 2 2 1 2
 l   l  Y Y A
(B) 1 1 2 2 1 2
l1Y1  l1Y2 l1Y2  l 2Y1
(C)
 l12  l2 1 Y1Y2 A (D)
 l12  l2 1 Y1Y2 A
l1Y2  l 2Y1 l1Y1  l 2Y2
11. A wire of length 2l, cross-sectional area A and Young’s

modulus Y is light fixed horizontally between two rigid
supports. When a block of mass M is hanged from middle,
the mid-point gets slightly depressed. The depression is –
1
 Mg   Mg  2 M
A) l   (B) l  
 YA   YA 
1 1
 Mg  3  Mg  4
(C) l   (D) l  
 YA   YA 
12. A stationary wave, s = αsinkx cosωt is produced on a rod of density ρ and cross-sectional
area A. The total mechanical energy confined between two adjacent nodes is
2  2 A 2  2 A 2  2 A 2  2 A
(A) (B) (C) (D)
k 2k 4k 8k
13. A composite tube has a straight and a circular

portion of radius 0.5 m. A source ‘S’ emits all
possible audible frequencies which the detector ‘D’
detects at the other end. If speed of sound in the  r
tube is 314 m/s, then which of the following
frequency will not be detectable by D S D
(A) 50 Hz (B) 100 Hz
(C) 200 Hz (D) 400 Hz
14. Two coherent loud speakers, A and B are placed at a separation of

2m. A detector ‘D’ moves perpendicular to the line joining the sources
starting at P. Speed of sound is 340 m/s. The detector is unable to D
detect any destructive interference along its path for frequencies
below a certain frequency. That frequency is A B
  P
(A) 65 Hz (B) 75 Hz 2m
(C) 85 Hz (D) 95 Hz
15. Two coherent sources s1 , and s2 , placed at a separation 2λ, are

P
emitting waves of wavelength λ. A detector is moving along a line 
perpendicular to the line joining the sources. It detects a maxima at
‘O’ and another at ‘P’. The distance between O and P is (d<<λ).
A B
(A) d (B) 2d   o
s1 s2
(C) 3d (D) 2d
d D
16. Two coherent sources, emitting waves of wavelength λ, are placed at a separation of 3λ. A
detector is moving around them on a large circle. The number of minima detected by it in one
complete rotation is –
(A) 2 (B) 4
(C) 8 (D) 12
17. A string of linear mass density 0.25 kg/m is taut under a tension of
100 N inside a cart. A short pulse is generated at the left end which
then propagates in (+)ve x direction. An observer on ground
observes the pulse to be at rest. Velocity of the cart is
(A) 20iˆ m / s (B) 20iˆ m / s
 
(C) 40iˆ m / s (D) 40iˆ m / s
18. If specific heat capacity of a substance in solid and liquid state is proportional to temperature
of the substance, then if heat is supplied to the solid initially at – 20°C(having melting point
0°C) at constant rate. Then the temperature dependence of solid with time will be best
represented by
(A) (B)
T T
t t
(C) (D)
T T
t t
19. All the rods have same conductance ‘K’ and same area B
of cross-section ‘A’. If ends A and C are maintained at
temperature 2T0 and T0 respectively, then which of the a a
following is/are correct? b
(A) Rate of heat flow through ABC, AOC and ADC is
same
A C
b b
(B) Rate of heat flow through BO and OD is not same b
3KAT0 a a
(C) Total rate of heat flow from A to C is
2a
D
(D) Temperature at junctions B, O and D are same
20. A hollow copper sphere and a hollow copper cube, of same surface area and negligible
thickness, are filled with warm water of same temperature and placed in an enclosure of
constant temperature, a few degrees below that of the bodies. Then in the beginning:
(A) The rate of energy lost by the sphere is greater than that by the cube
(B) The rate of fall of temperature for sphere is greater than that by the cube
(C) The rate of energy lost by the sphere is less than that by the cube
(D) The rate of fall of temperature for sphere is less than that for the cube
21. There are two thin spheres A and B of the same material and same thickness. They emit
like black bodies. Radius of A is double that of B. A and B have same temperature T. When A
and B are kept in a room of temperature T0(<T), the ratio of their rates of cooling (rate of fall
of temperature) is: [assume negligible heat exchange between A and B]
(A) 2 : 1 (B) 1 : 1
(C) 4 : 1 (D) 8 : 1
22. In a cyclic process, a gas is taken from state A to B via P B

path-I as shown in the indicator diagram and taken back to
state A from state B via path-II. In the complete cycle:
(A) work is done on the gas
(B) heat is given to the gas A
(C) no work is done by the gas
(D) nothing can be said about work as data is insufficient V
23. A rod of length l is in motion such that its ends A and B are y
moving along x-axis and y-axis respectively. It is given that B P
d 
 2 rad/s always. P is a fixed point on the rod. Let M be l
dt
the projection of P on x-axis. For the time interval in which  A
 x
changes from 0 to , choose the correct statement: M
2
(A) The acceleration of M is always directed towards right
(B) M executes SHM
(C) M moves with constant speed
(D) M moves with constant acceleration
24. A block of mass ‘m’ is attached to a spring in natural length of spring constant ‘k’. The other
end A of the spring is moved with a constant velocity v away from the block, find the
amplitude of oscillation of the block in the reference frame of point A of the spring.
1 m 2 1 m 2
(A) (B)
4 k 2 k
m 2 m 2
(C) (D) 2
k k
25. Two light strings, each of length l, are fixed at A B y

x
points A and B on a fixed horizontal rod xy. A small 45 45
bob is tied by both strings and in equilibrium, the
strings are making angle 45° with the rod. If the  
bob is slightly displaced normal to the plane of the
strings and released then time period of the
resulting small oscillation will be:
2 2l 2l
(A) 2 (B) 2
g g
l l
(C) 2 (D) 2
g 2g
26. A particle of mass m = 2 kg executes SHM in xy-plane y

between points A and B under action of force A2, 2 

F  Fxiˆ  Fy ˆj. Minimum time taken by particle to move
x
from A to B is 1 sec. At t = 0 the particle is at x = 2 and y
= 2. Then, Fx as function of time t is: B
(A) 4 2 sin  t (B) 4 2 cos  t   2,  2 
(C) 4 2 cos  t (D) none of these
27. An organ pipe of length L is open at one end and closed at other end. The wavelengths of the
three lowest resonating frequencies that can be produced by this pipe are:
(A) 4L, 2L, L (B) 2L, L, L/2
(C) 2L, L, 2L/3 (D) 4L, 4L/3, 4L/5
28. A, B and C are three tuning forks. Frequency of A is 350Hz. Beats produced by A and B are 5
per second and by B and C are 4 per second. When a wax is put on A, beat frequency
between A and B is 2Hz and between A and C is 6Hz. Then frequency of B and C
respectively are:
(A) 341 Hz, 359 Hz (B) 345 Hz, 341 Hz
(C) 359 Hz, 345 Hz (D) 355 Hz, 341 Hz
29. In resonance tube experiment, if 400 Hz tuning fork is used, the first resonance occurs when
length of air column is 19cm. If the 400 Hz tuning fork is replaced by 1600Hz tuning fork then
to get resonance, the water level in the tube should be further lowered by a minimum value of
(take end correction = 1 cm):
(A) 5 cm (B) 10 cm
(C) 15 cm (D) 20 cm
30. A car moves towards a hill with speed c . It blows a horn of frequency f which is heard by an
observer following the car with speed 0 . The speed of sound in air is  .
(A) The wavelength of sound reaching the hill is  /f.
  c
(B) The wavelength of sound reaching the hill is .
2f
  c
(C) The wavelength of sound of horn directly reaching the observer is
2f
2c   0  f
(D) The beat frequency observed by the observed is
 2  c2
PART –B (CHEMISTRY)
1. Rank in increasing order of acidity
OH OH
(II)
(I)
NO2
O 2N O 2N
OH OH
NO2
(III) (IV)
CH3 NO2
(A) III < II < I < IV (B) IV < II < I < III
(C) III < I < II < IV (D) I < II < IV < III
2. Rank in increasing order of pKa values.

O O
I II
OMe
O O O O
III IV
OMe
(A) I < II < IV < III (B) III < IV < I < II
(C) III < I < IV < II (D) IV < I < III < II
3. Identify the major species in solution for reaction:

OH
COOH
NaOH  one eqv . 
       
H 2O
CH 2 OH
ONa OH
COOH COOH
(A) (B)
CH2OH CH2ONa
OH OH
COOH COONa
(C) (D)
CH2OH CH2OH
4. Rank the following carbocations in order of increasing stability (least stable first)
II
I
IV
III
(A) II < IV < I < III < V (B) IV < I < V < II < III
(C) IV < II < III < V < I (D) I < II < III < V < IV
5. Which of the following is most stable carbocation?
+
(A) (B)
(C)
(D) +
+
6. The most stable diene is

(A) (B)
(C) (D)
7. Which of the following is the strongest base?
(A) (B)
N N
H
(C) (D)
N O
H
8. Arrange the following in the increasing order of their basic strength

O
O O
NH 2 NH NH 2
NH 2 N H 2N
H
(I) (II) (III) (IV)
(A) I < II < III < IV (B) IV < III < II < I
(C) IV < III < I < II (D) II < I < III < IV
9. Which of the following is the resonance form of the following enolate ion
OH O
(B)
(A)
O O
(C) (D)
10. Which of the following compound is most basic?
(A) (B)
N N
H H
(C) (D)
N N
H H
11. What is the major product of the reaction?

CH3
2 D
 
Ni
D D
(A) CH3 (B) CH3

D D
H D
CH3 CH3
(C) D (D) H
D D
H H
12. Free radical chlorination of n-hexane produces this number of monochloroderivatives

(including stereoisomers)?
(A) 5 (B) 7
(C) 8 (D) 3
13. The major monobromination product in the photochemical bromination of 2,2-dimethyl

butane is
(A) (B)
Br
Br
(C) (D)
Br
Br
14. What is the most likely product of the following reaction?

2 Cl
 
hv
(A) (B)
Cl Cl
(C) (D) Cl
Cl
15. An unknown alkene was treated with ozone followed by zinc dust in dilute acetic acid.
The reaction products were determined to be acetone and propanol. What is the structure of
the unknown?
O O
 i  O ,CH Cl
+
3 2 2
?  
 ii  Zn,CH3CO2H H
(B)
(A)
(C) (D)
16. Which is the best combination of reagents to carry out the synthesis?
? OH

OH
(A) m-CPBA,CH2Cl2 (B) (i) O3 (ii) CH3SCH3

(C) Br2,H2O (D) OsO4,KHSO3, acetone
17. What is the product of the reaction?
H3C CH3 OsO4 ,CH3  COOH

3
C C 


H H CH3 3 COH ,O H
(A) CH3CHO
(B) Racemic (2R,3R) and (2S,3S)-2,3-butanediol
(C) Meso-2,3-butanediol
(D) Cis-2,3-epoxybutane
18. What would be the best method to bring about the following conversion?
CH3 CH3
CH 3 C CH CH2 CH 3 C CHCH 3
CH3 CH3 OH
(A) BH3, THF; then H2O2, OH- (B) HBr; then NaOH/H2O
(C) Conc. H2SO4, then H2O, heat (D) Hg(OAc)2 /THF-H2O, then NaBH4, OH-
19. Select the reaction(s) that would result in the formation of 2-bromopropane.
Peroxides
I  CH3CH  CH2  HBr  
CCl
II  CH3CH  CH2  NBS 
4

hv
III  CH3CH2CH3  Br2  
CCl
IV  CH3CH  CH2  Br2 
4

(A) I and III (B) III only
(C) I, II, III and IV (D) I, II and III
20. Give the major product of the following reaction
Catalytic H 
 Major product
Heat
(A) (B)
(C) (D)
21. What is the major organic product of the reaction
Hg , H 2 SO 4
C CH     
(A) (B)
H
CCH3 C C
OH
O H
(C) H (D)
H
C C CH2CHO
OH
22. The product that should be formed in the reaction are
i  H , Lindlar ' s catalyst

CH 3  C  C  CH 3   2       
 ii  Br2 ,CCl 4
Br Br
H H
(I) CH3 (II) CH3
H3C H3C
H Br
Br H
CH3 H
H H 3C
Br (IV) Br
(III) Br Br
H H
H3 C H3 C
(A) I and III in equal amounts (B) II and IV in equal amount

(C) All four in unequal amounts (D) II and III in equal amount
23. Choose the best reagent for the following transformation

2  heptyne  cis  2  heptene
(A) H2/Pt (B) Na/liq. NH3
(C) H+/H2O (D) H2/Lindlar’s catalyst
24. For the following series of reaction, what can be predicted about stereochemistry of final
product?
Na, liq. NH
H3C CH3 
3

Br / CCl
2 4
 
 Product(s)
(A) Meso compound (B) A chiral compound

(C) Racemic mixture (D) A pair of diastereomers
25. Which of the following compounds would not be considered aromatic in its behaviour?
(A) (B)
N
(C) (D)
N
H
26. Which of the following cations is aromatic?



(I) (II)



(IV)
(III)
(A) II, IV (B) IV

(C) I, II, IV (D) II, III, IV
27. How many of the compounds will give predominantly meta substituted product in electrophilic
aromatic substitution?
NH3 Cl CH3
CN
(I) OMe (III) (IV) (V)

(II)
(A) 1 (B) 2
(C) 3 (D) 4
28. What product(s) would you expect from the following reaction?
O
3HNO
O 
H2 SO4
O O
(A) O 2N
O O
(B)
NO 2
O O NO2
(C) (D)
O O
NO2
29. Predict the major product of the following reaction.

Br
3HNO

H2 SO4
CHO
(A) 4-bromo-2-nitrobenzaldehyde
(B) 4-bromo-3-nitrobenzaldehyde
(C) 4-bromo-2,6-dinitrobenzaldehyde
(D) 4-bromo-3,5- dinitrobenzaldehyde
30. What unusual characteristic does a halogen substituent exhibit in electrophilic aromatic
substitutions?
(A) It is activating but meta directing
(B) It is activating and directs to all positins equally
(C) It is deactivating but ortho/para directing
(D) It is activating but exclusively ortho directing
PART–C (MATHEMATICS)
sin x  cos x  3 2
1. The domain & range of the function f ( x )  log2 are given by
2
(A) Df   ,   , Rf  1, 2 
(B) Df   , 0    0,   , Rf   1,1
(C) Df   0,   , Rf  1, 2 
(D) None of these
2. If f(x) be a continuous function defined for 1  x  3 . If f ( x )  Qx  1, 3  , f (2 )  10 , then

f(1.8) is
(where Q is the set of all rational numbers)
(A) 1 (B) 5 (C) 10 (D) 20
3. Let the function f(x) be defined as follows:

f ( x )  x 3  x 2  10 x, 1  x  0
cos x, 0x /2
1  sin x, /2 x
Then f(x) has
(A) A local minimum at x = π/2
(B) A local maximum at x = π/2
(C) an absolute minimum at x = -1
(D) an absolute maximum at x = π
x dx
4. The slope of the tangent to the curve y   at the point where x = 1 is
0 1  x3
(A) 1/2 (B) 1 (C) 1/4 (D) None
sin x cos x cos x

5. The number of distinct real roots of cos x sin x cos x  0 in the interval
cos x cos x sin x
 / 4  x   / 4
(A) 0 (B) 2 (C) 1 (D) 3
6. If
ABCDEF is a regular
   hexagon
  inscribed in a circle with centre O, then
AB  AC  AD  AE  AF 
   
(A) 4AO (B) 5 AO (C) 6 AO (D) 8 AO
7. The lines 2x  y  1  0,  m  4  x   2m  1 y  0 and 4mx   m  6  y  1  0 are

(A) concurrent for two values of m
(B) concurrent for one value of m
(C) concurrent for no value of m
(D) None of these
8. A plane meets the coordinate axes in A, B, C and  , ,   is the centroid of the triangle ABC,
then equation of plane is-
x y z x y z
(A)    3 (B)    1
     
3x 3y 3z
(C)   1 (D) ax  y  z  1
  
x y
9. A variable line   1 , moves in such a way that harmonic mean of a and b is 8. Then the
a b
least area of triangle made by line and coordinate axes is-
(A) 8 (B) 16 (C) 32 (D) 64
10. Total no. Of ways of selecting two numbers from set { 1, 2, 3, ...... 3n}, so that their sum is
divisible by 3, is equal to-
2n 2  n 3n 2  n
(A) (B) (C) 2n 2  n (D) None
2 2
11. If i z 3  z 2  z  i  0 , then
(A) z  1 (B) z  1 (C) z  1 (D) z  0
12. The value of

18 3
 7 3  3.18.7.25  is
3  6.243.2  15.81.4  20.27.8  15.9.16  6.3.32  64
6
(A) 0 (B) 1 (C) 2 (D) None
13. If a circle passes through the points (1, 0), (5, 0) and touches the y-axis at (0, h), then h =
(A) 5 (B) 2 5 (C) 3 5 (D) 4 5
x2 y 2 4
14. A tangent to the ellipse   1 , having slope  meets the major and minor axes at A
18 32 3
and B. If O be the origin, then the area of OAB is.
(A) 24 sq. units (B) 48 sq. units (C) 36 sq. units (D) Non of these
x 1 y 1 z 1 x 3 y k z
15. If the lines   and   intersect, then k is equal to:
2 3 4 1 2 1
(A) -1 (B) 2/9 (C) 9/2 (D) 0
16. The tangent to the graph of the function y = f(x) at the point with abscissa x = 1 from an angle
of π/6 and at the point x = 2 an angle of π/3, at the point x = 3 an angle of π/4. The value of
3 3
1
f '( x )f ''( x )dx   f ''( x )dx
1
( f ''( x ) is supposed to be continuous) os;

4 3 1 3 3 1 4 3
(A) (B) (C) (D) None of these
3 3 2 3
The area bounded by the curves y   x  1 , y   x  1 2 2 , the line y = 1/4 an x-axis is:
2
17.
(A) 1/6 (B) 2/3 (C) 1/4 (D) 1/3
18. Let a, b, c be any real numbers. Suppose the three are real numbers x, y, z not all zero such
taht x = cy + bz, y = az + cx and z = bx + ay then a2  b 2  c 2  2abc is equal to;
(A) 1 (B) 2 (C) -1 (D) 0
cox3  1
19. If  then θ =
2 cos 2   1 2
  
(A) n  (B) n  (C) 2n  (D) None of these
3 4 6
 2x 
20. Statement – I (s1 ) : Let   sin1  2 
,
1  x 
 1  x2  du
v  cos1  2 
. Then  1 for 0 < x < 1.
 1  x  dv
 2x 
Statement – I  s2  : sin1  2 
 2 tan 1 x
 1  x 
 1  x 2

For -1 < x < 1 and cos1  2 
 2 tan1 x
 1  x 
(A) If both Statement-I and Statement-II are true but Statement-II is not the correct
explanation of Statement-II.
(B) If both Statement-I and Statement-II are true, and Statement-II is correct explanation
of Statement-I.
(C) If Statement-I is true but Statement-II is false.
(D) if Statement-I is false but Statement-II is true
21. The locus of z which statisfies the inequality log0.3 z  1  log0.3 z  i is given by,
(A) x + y > 0 (B) x – y < 0 (C) x + y < 0 (D) x – y > 0
22. When 5 99 is divided by 13, the remainder is

(A) 8 (B) 9 (C) 10 (D) None
23. A circle C1 of radius 2 touches both x-axis and y-axis. Another circle C2 whose radius is
greater than 2 touches circle C1 and both the axes. Then the radius of circle C2 is
(A) 6  4 2 (B) 6  4 2 (C) 6  4 3 (D) 6  4 3
 3
24. The tangent to ellipse 3x 2  16y 2  12 . At the point 1,  , intersects the curve y 2  x  0 at
 4
(A) no point (B) Exactly one point
(C) two distinct points (D) more than two points
25. The volume of the tetrahedron included between the plane 3x + 4x – 5z – 60 = 0 and the
coordinate planes is
(A) 60 (B) 600 (C) 720 (D) None
26.  
The tangent to the curve y  e x drawn at A c, ec intersect the line joining the points
  
P c  1, e c 1 and Q c  1, e c 1 : 
(A) on the left of x = c (B) on the right of x = c
(C) at no point (D) at all points
 xl  x  l  x  ...l  x 
1
27. If l r means (log log log...)x, the log being repeated r times, then 2 r
dx is
equal to:
l r 1  x 
(A) l r 1  x   c (B) c
r 1
(C) l r  x   c (D) None of these
t 2 f ( x )  x 2 f (t )
28. Let f(x) be differentiable in the interval (0, π) such that f(1) = 1 and lim  1 for
t x tx
each x > 0. Then f(x) is:
1 2 x2 1 4x 2
(A)  (B)  
3x 3 3x 3
1 2 1
(C)   (D)
2 x x2 x
29. The angle of elevation of the top of a tower standing on a horizontal plane from a point A is α.
After walking a distance a towards the foot of the tower the angle of elevation is found to be
β. The height of the tower is –
a sin  sin  a sin  sin 
(A) (B)
sin      sin     
a sin      a sin     
(C) (D)
sin  sin  sin  sin 
30. Assertion (s1 ) : The equation x 6  5 x 5  3x 3  2 x 2  6  0 has at least two imaginary roots.
Reason (s2 ) : f(x) has two changes in sign and f(-x) also has two changes in sign.
You have to select the correct choice.
(A) Statement-1 is true, Statement-2 is true, Statement-2 is a correct explanation for
Statement-1
(B) Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation for
Statement-1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true
FIITJEE -- JEE (Mains)

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
JEE - MAINS 2020
CODE: SET-A
ANSWER KEYS
PHYSICS CHEMISTRY MATHEMATICS
Q. No. Ans. Concept Code Q. No. Ans. Concept Code Q. No. Ans. Concept Code
1. B 1. C 1. A
2. C 2. B 2. C
3. B 3. D 3. B
4. C 4. A 4. A
5. A 5. D 5. C
6. C 6. A 6. C
7. B 7. C 7. C
8. C 8. A 8. A
9. D 9. D 9. C
10. B 10. D 10. B
11. C 11. A 11. C
12. C 12. A 12. B
13. A 13. C 13. A
14. C 14. D 14. A
15. C 15. C 15. C
16. D 16. D 16. D
17. B 17. C 17. D
18. C 18. D 18. A
19. D 19. B 19. C
20. D 20. B 20. B
21. B 21. A 21. D
22. A 22. A 22. A
23. B 23. D 23. B
24. C 24. A 24. B
25. D 25. B 25. B
26. B 26. C 26. A
27. D 27. B 27. A
28. B 28. D 28. A
29. A 29. B 29. A
30. D 30. C 30. A
HINT AND SOLUTIONS

Physics
v0 v0
1. v rms 
0
v 2 dN

0
av 4 dv
v0 v0
0
dN 0
av 2 dN
v 05 / 5 3
 3
 v0
v0 / 3 5
m
P  r A   RT and
MO 2
2.
m
P  2     rA  RT
MO 2
2    MN 2 28
 
 MO 2 32
2   7
 
 8
 7
 2   1   
 8
16 
 
15
2
 nRT 
3. Ans. P  P0  aV 2  P0  a  
 P 
P P0  P dT
 T ; for T  max, 0
nR a dP

d
dP

P P0  P  0 
P
 P0  P  0
2 P0  P
P
 P0  P 
2
3 2
 P0  P  P  P0
2 P
4. Ans. dQ  nc p dT
5 PdV 5  mg 
 qdt  n R.   P0   Adx
2 nR 2 A 
5 dx 2q
Or qdt   P0 A  mg  dx  v  
2 dt 5  P0 A  mg 
5. From first law of thermodynamics, dQ  nCv dT  PdV

dQ P dV
  Cv 
ndT n dT
P dV nRT
Or, C  Cv  . ; now , P  aT 2 
n dT V
nR dV nR
 V  
aT dT aT 2
2
5 aT  nR  5 3
 C R . 2 
 R R  R
2 n  aT  2 2
6.
W   A   . a . b
 5 1 3   3 1 
  m   atm
 2   2 
 2  atm.m3  2   10 5 J
1 2 1 1
7. Ans. W  kx  kx.x  .F .x
2 2 2
1
  540  2  10 2  5.4J
2
F
8. Ans. Y A
l
l
Fl Fl
 l   2
YA r Y
1
l1 4r 2 1
  
l 2 2l 8
r2
F1l F2 l F
9. Ans. l1    F1  2
r Y 4 r .2Y
2 2
8
Now F1  F1  F and F1 x  F2  l  x 
 F1 x  8F1  l  x 
 9x  8l
8l 8
 x   90cm  80cm
9 9
10. Ans. Thermal expansion = Elastic compression

Fl Fl
 l11   l 2 2   1  2
Y1 A Y2 A
F 
 l11  l2 2  
 l1 l2  1
  
 Y1 Y2  A
F 
 l11  l 2 2 Y1Y2 A
l1Y2  l 2Y1
11. Ans. Elongation, l  l sec   l  l  sec   1

At equilibrium, 2T sinθ = Mg
 2YA  sec   1 sin   Mg
Mg
Or,  tan   sin   
2YA
Mg x x
  tan   sin   
2YA 1 l  x2
2
  
1
x  x2  2  x3
 1  1  2  
1  l   2l 3
 
1
 Mg  3
 x l 
 YA 
12. Ans.
dx
Kinetic energy of the elemental mass

2
1  ds  1
dK  Adx    Adx [ sin kx cos t ]
2  dt  2
1 2 2
   Adx sin2 kx cos2 t
2
1
dK max   2 2 Adx sin2 kx dx
2

1  sin 2kx  2
 2  2 A  x 
4  2k  0
1 2 2 2  2 A
   A 
8 4k

13. Ans. Here x  2 r   2n  1  for destructive interference
2
4 r
 
2n  1
v  2n  1 v
 v    2n  1 50Hz
 4 r
14. Ans. For destructive interference

 v
x   2n  1   2n  1 
2 2v
 2n  1 v v
 v min  
2 xmax 2 xmax
340m / s
  85Hz
2  2m
15. Ans. x0  d   d  2    2 , So, for maxima at P, x p  

P


x
 θ  
s1 2λ s2 O
 xP  S1P  S2 P  2  cos   
1
 cos  
2

 
3
Now, x  d tan  d tan60 o  3d
16. Along the axis, path difference is 3λ and along the bisector, O
path difference is zero. In between, there are path differences  
of 2λ and λ which all satify the condition of maxima. In this
way, there are 12 maxima on whole circle. Between every two 2λ 2λ
maxima, there is a minima. So, the number of minima is also B
o
12 3λ   3λ
3λ
2λ 2λ
 λ
O
F
17. Ans. Speed of the pulse, v 

100

 20ms
0.25
  
For the pulse to remain stationary, v PG  v PC  v CG  0
 
v CG  v PC  20iˆ m / s
18. As dQ = msdT
dQ dT dT
 ms  ms  K2
dt dt dt
dT
From question : S  T  m  K1T   K2
dt
 K T2
Or S  K1T  m 1  t
 K2  2
(K1 being proportionality constant)
dQ
Also,  constant  Given   K 2  say   T  t
dt
Hence, the graph will be:
T
19. By summetyry,
I AB  I BC and I AD  I DC
 No current in BO and OD
 TB  TO  TD
dQ
20.   KA 1   2 
dt
[Newton’s law of cooling]
 Rate of loss of heat is same.
dQ d
From  ms
dt dt
d KA
     S 
dt ms
Since, ‘m’ is larger for sphere, rate of cooling will be less for sphere.
21. The rate of heat loss by a thin hollow sphere of thickness ‘  x,, mean radius ‘r’ and made of
density '  ' is given by:
dT
ms     A T 4  T04 
dt
  4 r 2 x  s dT
dt
    4 r 2 T 4  T04 
dT   T 4  T04 
 
dt s x
is independent of radius.
Hence rate of cooling is same for both spheres.
22. As work done in state (II) is more than in state(I).

P B
A
V
d
 2;   2t
23. dt
Let BP  a ;  x  OM  a sin   a sin  2t 
Hence, M executes SHM within the given time
y
B a
P

l
A
o x M x
Period and its acceleration is opposite to ‘x’ that means towards left.
24. A = xmax
1
25. Resulting torque on the bob = mg sin 
2
ml 2
MI of bob about axix xy 
2

 2g
 .
l
 2
I l
l
T  2
2g mg
26. Let the line joining AB represents axis ‘r’. By the conditions given’r’ coordinate of the
particle at time t is
r  2 2 cos t
2 2
  
T 2
 r  2 2 cos  t
y r
r  0 A 2 , 2 
x
2
B
r
x  r cos 45   2 cos  t
2
 ax   2 x   2 2 cos  t
 Fx  max  4 2 cos  t
27. D
28. 359 Hz
4 C
355 Hz 
5 B
A  350 Hz  351Hz
4 C 349 Hz
wax 345 Hz 
2 341Hz
common
6 common
A '  347 * C 341Hz
A  350 / 347
A  B  5, A '  A, A ' B  2 
 B  345
B  C  4, A ' C  6  C  341
29. For first resonance with 400 Hz tuning fork

400Hz
v v
l eq.    19  1   20cm
4f0 4  400 
If we use 1600 Hz tuning fork

v v
 20 cm
4f0 4  1600 
20
  5cm
4
For Resonance
v 3v 5v 7v
l eq .  , , , ,.....
4f0 4f0 4f0 4f0
1cm  l  5cm,15cm, 25cm, 35cm, 45cm.....
l  4cm,14cm, 24cm, 34cm, 44cm.....
Water level should be further lowered by
24 – 19 = 5cm
Or 34 – 19 = 15 cm
30. Frequency of horn directly heard by observer

 v  v0 
 f
 v  vc 
v
Frequency of echo  f
v  vc
Frequency of echo of horn as heard by observer

v  v  v0 
f .
v  v c  v 
Frequency of beats:
 1 1  2v v  v 0 
 v  v 0  f    f  Beat f
v  vc v  vc  v 2  v 02  
Hint and Solutions

Chemistry
1. - NO2 group increases acid strength of phenol greatly when present at ortho/para position
due to resonance effect. Therefore, IV is the strongest acid. When – NO2 is present at
meta position, it increases acid strength by only inductive effect. Therefore,II is stronger
acid than I. III is weakest acid due to +I effect of – CH3.
2. III is a 1,3-diketo, most acidic followed by IV. I is more acidic than II.
3. The most acidic group (- COOH) will be neutralized.
4. V is most stable as it is 3° as well as benzylic. III is 2nd most stable and more stable than I as
both the resonance structures of III 2°. II is least stable as it is vinylic.
5. It has resonance stabilization
6. It is conjugated as well as trans at both double bonds
7. Lone pair of nitrogen is not involed in resonance as well as it has less s-character than the
nitrogen of pyridine; hence the former is better electron donor
8. IV is most basic as its conjugate acid has two equivalent resonance structures. Among the
amides I, II and III, III is most basic and I is least basic.
9.
O O
10. Lone pair is not delocalized
11. Syn addition of D2 will take place. In chair conformation of cyclohexane, axial-equatorial
position on adjacent ring carbons are cis.
12. (racemic),
Cl,
Cl Cl
(racemic): Total 5 isomers

13.
hv
+ Br2 
Br
2,2- dimethyl butane
Bromination occur selectively at carbon where more stable free radical is formed.
14. Free radical chlorination occur selectively at benzylic carbon
15.
Zn / H2O
H3C + O3  
O
CH3 C CH3 + CH3CH2CHO
16. OsO4/KHSO3 in acetone gives syn vicinal diol.
17. Syn hydroxylation of alkene. Here the alkene is symmetrical hence meso diol will be
produced.
18. Oxymercuration-demercuration reaction brings about Markownikoff’s hydration of

alkene without rearrangement.
19. hv
CH3CH2CH3  Br2 
 CH3  CH  CH3
Br
20.
+ + +
H -H
21. OH
|
C6H5  C  C  H  H   C6H5  C  CH2
Markownikoff's addition of H2O
O
||
tautomerisation

 C6H5  C  CH3
22. H3C C C CH3+ H2
CH3 CH3
Lindlar's

 C C
catalyst
H H
Br

2
 anti addition gives racemic mixture of dibromides.
23. Lindlar’s catalyst brings about cis hydrogenation of alkyne to alkene.
24. Na, liq. NH

CH3  C  C  CH3 
3

H3C H
C C Br

2
H CH3
Anti  addition of Br2 to

trans  2 butene gives meso dibromide
25. Lack of planarity prevent it to be aromatic.
26. I, II and IV have Huckel number of π electrons, delocalized in cyclic loop, hence aromatic
27. I and III
28. Nitration occur in phenoxy ring and at para position mainly, due to steric reason.
29. Nitration occur at ortho position to less deactivating bromin
30. Halogens are ortho/para directing but deactivating groups due to dominance of inductive
effect over resonance effect
Hint and Solutions

Mathematics
1. A
sin x  cos x sin  x   / 4 
u 3  3:2 
2 1  ....  1
u  4 : log2 u is defined for x   ,    Df
Rf : y  log2 u, 2  u  4 : log2 2  y  log2 4
1  y  2 : y  1, 2   Rf
2. C
y
10
x
0 1 2 3
A slight increase or decrease in the value of the function from the value at f(2) will result in
the inclusion of infinite irrational numbers and
 it is given that f(x) ϵ θ
 only possibility is that f(x) is constant in the given interval.
3. B
In 1  x  0, f '( x )  3 x 2  2 x  10  2 x 2   x  1   11  0
2
 f(x) is monotonically decreasing in the interval 1  x  0
+ +
-1 0 π/2 π
In 0  x   / 2, f '( x )   sin x  0,  f ( x ) is m.d.
In  / 2  x  , f '( x )  cos x  0,  f ( x ) is m.d.
Displaying the trend of values of the function in different intervals, we get the adjoining graph.
 f ( / 2  h)  2  f   / 2  , f   / 2  h   f   / 2 
 f  x  has a local maximum at x = π/2
4. A
dy 1 dy  1
  
dx 1  x 3 dx  x 1 2
5. C
Applying C  C1  C2  C3 , we get
sin x  2 cos x cos x cos x
sin x  2 cos x sin x cos x  0
sin x  2 cos x cos x sin x
1 cos x cos x
  sin x  2 cos x  1 sin x cos x  0
1 cos x sin x
1 cos x cos x
  sin x  2 cos x  0 sin x  cos x 0 0
0 0 sin x  cos x
  sin x  2 cos x  sin x  cos x   0
2
 sin x  2 cos x  0, sin x  cos x  0

 tan x  2. tan x  1 .
6. C
AB  AC  AD  AE  AF  ?
E D
 AC  AB  BC  AB  AO ...(1)
 AE  AF  FE  AF  AO ...(2)
By (1) + (2)
F C
 AC  AE  AB  AF  2 AO ...(3) O
Also, AD  2AO
AB  AF  AB  BO  AO A B
 AB  AC  AD  AE  AF
  
 AB  AF  AC  AE  AD 
 AO  3 AO  2AO  6 AO
7. C
2 1 1
m  4 2m  1 0  0
4m m 6 1
2  2m  1   1  m  4    m  4  m  6   4m  2m  1  0
 4m  2  m  4  m2  2m  24  2m 2  4m  0
 7m 2  7 m  22  0
D   7   4 7  22   49  616
2
D<0
8. A (0, q, 0) y
G  , ,   is the centroid of ABC Equation of the plane
which is passing through the points A, B, and C is B
x y z
  1 ....(1)
p q r
 p0 0 o x
(0, 0, r) A
  3
 p  3
(p, 0, 0)
 C
 0 q 0
G   q  3 z
 3
 00r
 3
 r  3

x y z
 By (1)    3
  
9. C
2ab
8
ab
 2ab  8  a  b   ab  4  a  b 
A.M .  G.M.
a  b  2 ab
ab
 2 ab  ab  8  ab  64
4
1
  ab
2
1
 min  64   32
2
10. B
Group A : 1, 4, 7 ..... : (n) nos. [3n+1] from
Group B : 2, 5, 8 ..... : (n) nos. [3n+2] from
Group C : 3, 6, 9 ..... : (n) nos. [3n] from
Select Select
C 2 C 2
B 1
 nC2  nC1 . nC1
n  n  1 n 2  n  2n 2 3n 2  n
  n.n  
2 2 2
11. C
Given, i z 3  z 2  z  i  0
 i z2  z  i    z  i   0
1
 
  z  i  i z2  1  0  z  i or z 2 
i
 i
Now, z  i  z  i  1
And z 2  i  z 2  i  z 2  1  z  1
Thus, in both cases z  1 .
12. B
The numerator is of the form
a3  b 3  3ab  a  b    a  b 
3
Where a = 18 and b = 7
Numerator  18  7   25 3
3
For denominator, 31  3, 3 2  9, 3 3  27, 3 4  81, 3 5  243

6
C1  6, 6C2  15, 6C3  20
6
C4  6C2  15, 6C5  6C1  6, 6C6  1
denominator 3 6  6C1 3 5.21  6C2 3 4.2 2  6C3 3 3.2 3  6C4 3 2.2 4  6C5 3.2 5  6C6 2 6
This is clearly the expansion of
3  2 
6
 5 6  25 3
 25   1
3
Numerator
 
Denominator  25 3
13. A
Let the equation of the given circle be
Y
x  y  2gx  2fy  c  0
2 2
Since it passes through (1, 0) and (5, 0) therefore 1 + 2g + c = 0

and 25 + 10g C = 0. On solving the two equations, we get g = -3
and C = 5.
So, the circle is x 2  y 2  6x  2fy  5  0 Since it touches y- (0,h)
axis at (0, h), therefore h  2fh  5  0 2
Discriminant of this quadratic must be zero, i.e. O X

4f 2  20  0  f   5 (1,0) (5,0)
 h 2  2 5h  5  0
 
2
 h 5 0
h 5
14. A
The coordinates of any point on the given ellipse are
x2

y2

 1 are 3 2 cos , 4 2 sin  
   
2 2
3 2 4 2
The slope of tangent

b2 x1 b . 3 2 cos 

2
 4
  cot 

a2 y1 a . 4 2 cos 
2
 3 
4
Given : Slope of the tangent  
3
4 4 
 cot    or tan q  1   
3 3 4
Thus, the equation of the tangent is
1 1
x. y.
x cos  y sin  2  2 1 x y
 1  Or  1
3 2 4 2 3 2 4 2 6 8
Therefore, the coordinates of A and B are (6, 0) and (0, 8) respectively.
1
Area of OAB   6  8  24sq. units
2
15. C
x 1 y 1 z 1
 
2 3 4
x 3 y k z
 
1 2 1
    
a 1, 1,1 ; b  2, 3, 4  r  a  b
    
c  3, k, 0  ; d 1, 2,1 r  c  d
These lilnes qwill intersect if the lines are coplanar
   
a  c , b and d are coplanar
   
 [a  c , b , d ]
2 k  1 1
 2 3 4 0
1 2 1
 2  5    k  1 2   1(1)  0
 2  k  1  11
 k 9/2
16. D
f '(1)  tan  / 6  1 / 3 , f '(2 )  tan  / 3  3 and f '(3 )  tan  / 4  1
3 3
Now 1 f '( x )f ''( x )dx  2 f ''( x )dx
3
1 1  1 
 f '  x   f 'x 2 
2 3
 . 1  1  3 
2 1
2  3  
1
3
1
 1  3  4  3 3
3
 
17. D
Required area y=(x+1)2 y=(x-1)2
1 1 
 2      x  1 dx 
1 2
 4 2 1/ 2
 y=1/4
1 1  1 O1/2 1
2  
 8 24  3
18. A
19. C
cos3   3 cos  1
4 
4 cos2   3 2
3 1
cos2   or cos  
4 2

  2n  
3
20. B
21. D
By the given condition, z  1  z  i
 x  1  iy  x  i  y  1
  x  1  y 2  x 2   y  1
2 2
 2 x  2y  x  y  x  y  0
22. A
We have
5 99  5 3.5 96  125 625 
24
 13  9  8  1  48  13 
24
24
 13  9  8  1  24C1  48  13   24C2  48  13   ...   48  13  
2 24
 
= 8 + terms containing power of 13.
Hence remainder = 8
23. B
First circle touches both axes and radius is 2 unit. Hence, centre of circle is (2, 2). Let radius of
other circle be a and this circle also touches both the axes.
Hence, centre of circle is (a, a). This circle touches first cirle.
a  2   a  2   a  2
2 2
Hence,
On squaring both the sides, we get a2  12a  4  0
12  12 2  4  4  1 12  128
a 
2 2
6 4 2
But a > 2, therefore a = 6 4 2 is neglected.
Hence, a = 6 + 4 2
24. B
 3
Tangent to 3 x 2  16y 2  12 at 1,  is
 4
3
3x (1)  16    12  x  4y  4
4
Solving with y 2  x  0 , we get y 2  4  4y  0
 y  2  0  y  2
2
 tangent touches y 2  x  0 at (-4, 2)
25. B Z
The plane intersects the axes at (20, 0, 0), (0, 15, 0) and (0, 0, -
12) C
So the volume of tetrahedron OABC
0 0 0 1
20 0 0
1 20 0 0 1 1 B
   0 15 0  600 O Y
6 0 15 0 1 6
0 0 12
0 0 12 1 A
X
26. A
dy
y  ex   ex
dx
Tangent at A c, e c is]  
y e e
c c
x  c C
i.e., y  xe  e c  cec
c
....(1)
Line PQ is
e c 1  ec 1 C-1 C C+1
y  ec 1 
 c  1 c  1
 x   c  1 
e

c e  e 1  ec
y  .  x  c  1 
....(2)
2 e
Solving (1) and (2)
e2  2e  1
x c 2 c
e  2e  1
Tangent meets the line PQ on the left of x = c.
Aliter: From the graph
27. A
1
 l r  loglog...log( x ) l   dx
 xl ( x ) l 2 ( x )....l r ( x )
r times
Putting t  l r ( x )  loglog...log( x ) . Then


r times
1 1 1 dx
dt  . .. .
loglog...log( x ) loglog...log( x ) log x x
 
r -1 r -2
1 1
 . dx.
l ( x ) l 2 ( x )....l   ( x ) x
r 1
dt
 I    log t  c
t
 log  loglog...log ( x )  c  l r 1 ( x )  c


r times
28. A
t 2 f ( x )  x 2 f ( x )  x 2 f ( x )  x 2 f (t )
lim 1
t x tx
  f ( x )  f (t )  
lim  t  x  f ( x )  x 2    1
t x
  t  x 
2x f ( x )  x 2  f '( x )  1
dy
x2  2xy
dx 1 d  y  1
4
 4   2 4
x x dx  y  x
1 1 2
 x 2 y   c  x 2 y  
3x 3 3 x3 3
1 2 x2
y  .
3x 3
29. A P
Let OP be the tower of height h(say) and
A and B be the two positions on the
horizontal line through O, such that h
OAP  , OBP  
And OB = x. α β
In OBP, OB  x  h cot , and O
A α B x
In OAP, OA  a  x  h cot 
 a  h  cot   cot  
 h  a sin  sin  / sin     
30. A
f ( x )  x 6  5 x 5  3 x 3  2x 2  6
f (  x )  x 6  5 x 5  3x 3  2x 2  6
Both f(x) and f(-x) have 2 changes in sign, therefore there can be maximum two positive and
two negative roots and hence, there are minimum two imaginary roots.

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FIITJEE - JEE (Mains)

PHYSICS, CHEMISTRY & MATHEMATICS

3. The test is of 3 hours duration.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

Useful Data Chemistry:

Acceleration due to gravity g = 10 m / s2

2. A tube shaped ring, is separated into two parts by a fixed P

3. An ideal gas is following a process where P  P0  aV 2 .Pressure of the gas when

4. A heater is supplying heat at constant rate q J/S to n moles of an P2

5. One mole of a diatomic gas undergoes through a process P  aT 2 where a is a constant.

Space for rough work

6. An ideal gas is taken through a cyclic process ABCDA. P

7. A spring is stretched by 2 cm under a tension of 540 N. Work done by the force is

9. Two wires, separated by 90 cm, holds a platform horizontally.

10. Two rods of lengths, Young’s modulus and coefficient of

Space for rough work

11. A wire of length 2l, cross-sectional area A and Young’s

13. A composite tube has a straight and a circular

14. Two coherent loud speakers, A and B are placed at a separation of

15. Two coherent sources s1 , and s2 , placed at a separation 2λ, are

Space for rough work

22. In a cyclic process, a gas is taken from state A to B via P B

25. Two light strings, each of length l, are fixed at A B y

26. A particle of mass m = 2 kg executes SHM in xy-plane y

(C) 4 2 cos  t (D) none of these

2. Rank in increasing order of pKa values.

Space for rough work

3. Identify the major species in solution for reaction:

Space for rough work

5. Which of the following is most stable carbocation?

6. The most stable diene is

7. Which of the following is the strongest base?

8. Arrange the following in the increasing order of their basic strength

10. Which of the following compound is most basic?

11. What is the major product of the reaction?

(A) CH3 (B) CH3

12. Free radical chlorination of n-hexane produces this number of monochloroderivatives

13. The major monobromination product in the photochemical bromination of 2,2-dimethyl

14. What is the most likely product of the following reaction?

(A) m-CPBA,CH2Cl2 (B) (i) O3 (ii) CH3SCH3

17. What is the product of the reaction?

H3C CH3 OsO4 ,CH3  COOH

Space for rough work

20. Give the major product of the following reaction

21. What is the major organic product of the reaction

Space for rough work

22. The product that should be formed in the reaction are

i  H , Lindlar ' s catalyst

(A) I and III in equal amounts (B) II and IV in equal amount

23. Choose the best reagent for the following transformation

(A) Meso compound (B) A chiral compound

Space for rough work

26. Which of the following cations is aromatic?

(A) II, IV (B) IV

(I) OMe (III) (IV) (V)

Space for rough work

29. Predict the major product of the following reaction.

2. If f(x) be a continuous function defined for 1  x  3 . If f ( x )  Qx  1, 3  , f (2 )  10 , then

3. Let the function f(x) be defined as follows:

sin x cos x cos x

Space for rough work

Batch : Date of Examination :