The sodium phospathe buffer 0.1 M, pH = 7,00.

NaH2 PO4 /Na2 HPO4 → pKa = 7.20

119.98 g NaH2 PO4 /mol; 141.96 g Na2 HPO4 / mol

The Henderson-Hasselbalch equations is:

 
Na2 HPO4
pH = pKa + log
NaH2 PO4
 
Na2 HPO4
7.00 = 7.20 + log
NaH2 PO4
The system of equations is obtained
(
−0.63NaH2 PO4 + Na2 HPO4 = 0
NaH2 PO4 + Na2 HPO4 = 0.1M

And solving the system:

NaH2 PO4 = 6.13×10−2 M

Na2 HPO4 = 3.86×10−2 M

This result implies 7.36 g NaH2 PO4 , 5.48 g Na2 HPO4