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BURSTEN MURPHY WOODWARD LEMAY een aN = «I 5 fal w < a] = 5 o ir Q fey 4 So wo a “Ss: ae rN (=, amore | ie; A SOLUTIONS TO EXERCISES ROXY WILSON University of llinois, Urbana-Champaign TWELFTH EDITION CHEMISTRY THE CENTRAL SCIENCE BROWN LeMAY BURSTEN MURPHY WOODWARD ath Mowe Cy S8e Pade Sy Tole ‘Aone i Try Hang “Mami Eie,Conty wal once Ge M,C rt Mager Sen Shas Tose pean Speci Maun Ze ‘Sipe Cove ese Pa Cutan (over Cn Gps by Drei Mee fe Une Um Geran Pun Pe a rp ae RNASE it 0 pt i ak my py a by yma in ese te etme seh, and Hsing oe Oro ah pone to eer aceon Te Sr pins ayy fei ih Saat nny ett fae seul Sama in cmon Wi of ge ‘ang prom, te po “Tr wo pron by Unig Sa copra iws mds vlan reacting canes and Seeing so eri Ds leo ny pur of or wok Cig 0 be Waid ‘We wed wl sty te egy fe wrk nd i peed The wok at maa om ‘had ner be dete vey yrs ng epg it cn All ‘eet is woke ego aie by tae acm sd hae he eno ett papi eer of eric wh yo hn mae IseN-15: 978-0-21-70500-6 Isen-10:0-321-70500-9, PY son Chapter Chapter? Chapter’ Chapters ‘chapter? Chapters Chapter Chapter10 Chapter tt Chapter 2 Contents Introduction. Invroduction: Matter and Measurement. ‘Atom Molecules and Tons. Stoichiometry: Calculations with (Chemical Formula and Equation... Reactions in Aqueous Solution. ‘Themmochemisy. _ conic Struct of Atom Periodic Properties of he Ben cnet 166 Basic Concepts f Chemical Bo enn a Molecular Geometry and Bonding Theor. m0 aes, s ‘guid and Intermolecular Forces... Solids and Modern Materia. Chapter 13 Chapter 18 Chapter 15 Chapter 16 Chapter 17 Chapter Chapter39 Chapter20 Chapter 21 Chapter Chapter23 Chapter 24 Properties of Solutions. (Chemica Kinetics. (Chemical Equlbem A Base Eg rrr Additional Aspeets of Aqueous Equilibria... (Chemistry of the Environment... (Chemical Thermodynamies letra [Noclear Chemisty (Chemistry ofthe Nonmetals ‘Transition Metals and Coordination Chemistry ‘The Chemisty of Lite ‘Organic and Biological Chemistry. 576 667 Introduction ‘Chom Tee Cental Scene 12 ta, cons more hn 20 end per nerc Consistent the ern caus oe fh at tes tomer chemi iby sling plane Gopi the ceca bet mare int to ald th tude in elecing a2 png pale typeof probe. Within ‘echt ter grup snr problem oe anager ee ih, ‘opportunity 1 rior a parr bind of role, Ther rea x aba amber of [perl exeib in each caper to rppenen ose grouped by tpl. Ina exec, ‘nH ue tent tine cna om seer chaps ae scant fe he Taihecion Azewerto tho numbed pial exer pl slced pean iene ‘erry about 100 inal ae povided he txt‘ spendin ane ap 9 athe {exaust whi or amin "Ths manvat Soteton o Eater In Chemisty: The Cental Scns 12h editon, war veten enhance he eno cape eee by proving dona ions The manual ‘set th irc by sving Sine PO energie probes td ‘ss the ery fering cone independent source och the ndetanding of he ‘tera Mot lua hve ea wc! nth se etl tener mpl re (oe gud stents in hi stales ‘Torsone he ‘An, i,t, Che prblemasring meta wd exeiely nthe tt "hr ogy hala ben incor i he Slaton Manoa. Stone moe aed ‘er and ulate Adland negate ences fete Ns fouatepappeach. We srg enoragernn asters pomet an aly pera ed, Wa ing hs rl ee eld tht mer el fy leon ined 1 te prcon o the umes Wel in he acon. In hs nul fo example some ues and physical eu re pL ped fo our wt Beso eta ‘cay a the tien I he pen. dens wai ier vale lve Probe hi aamers wl er gy fone Hd in he appends of hw eo he ‘al Tha es normal a «common dsece when comparing ae fom rent ‘elton or experimen: Rounding methods ae mcr suf dite tw ee vale. this man, wh slo ten In epa intedte rll Be ended fo he come nero ‘lenis gues however vended mbor wil yaad in bagueteakltone By flowing ie sce calor ne ear torent ended interedit en the mld of» alaon que, The fl rae wl appr with he comet mambo of Sic gues This mays na wall arepcy i th at glean ge oven ‘tides noes and he gents mal. Varins dae runding Or ‘nay tyr manera te “hein tp in hckng your in and evn lens betwen our newer an he Tv ok frre an irene in poems etd Uirately, ving te small umes ifr esrb’ above eee important an sndetndig the perl met fr sling probe. The gulf he man! 89 prove a eer Ge sound and conan probe svingmebads nan acl anerso eat s, crnertnary fers ae ben made hep tis marl serie pose. Al execs wr wr nd prose by at et hse chemists ensure cn mets na) ‘Rmathmat. The work and vic Me Rane Mast Ma Ko Vir, Chtopber Mit td riety Kochut have Ken nae t peck any watenok a8 ‘scaly calenging asthe ma yp a rs vay rep dep ou combined ‘lors Pawel and iin am. We hope at both ern nd dens il fr hs maa acu Rf and esctie ony Wibon PRD. Introduction: Matter and Measurement ‘Visualizing Concepts 13 ew con ond of sm. Aa ane pst gy oy ound pup calla males Coup Srna Kido sos bond Seite melecaee Meno sin more hn te Hb! om nd/or alas ‘bund i dice parle (6) paloma (0) mart denen (©) patesengouc iv (@)mureofanciener ed compound 12 Aer py cage, he nies ofthe shane neve are he sae ae Sets blr the change That cece ogi epson Dare {eal et oe new satan e pode range of tara The laa represents alan, ene te molec afer he change (ent han he mace bdret age 13, Tote acapof cafes, bg wth round fobs hterogemous mitra tle 4 pu sultce, Hot war nt the cole ground and dior ‘Sport he oe en ta ee weer Tice sew hopes ‘ure of unde! ce ban sie elude salto he mate ‘Spanted by liton. Uniaaeed grouse eon he Rr pape a gd ‘os ttf bomopernus itr Arps mo te onan low ‘sal two spain os, Chamilia among th compen of he ‘fos ban slim etn compounds to dnl In wat, whe or components ‘emain relbe Tha nd of span tse aly ence lat ‘ncn, The ncale grate se then apne fn te et tony fon 1) te) mae (© sempre) wen () gt © we tempeture 0) dersiy 0) vane 15 Demy the ato of mit 10 vue. Fora sper, sa is ke volume bith are (Serle ada oe pare (2) For aphee of te ste ae or volume, te donor of he deraty 1 Matter and Measurement Solutions to Exercises atone same Te dre he spree Reve A at | Tighe avo nnd clic erty anes The shina spor (Sty = 270 g/cm gh hen ce (erly = 680 g/cm) ten Re riy 70808 g/om) (®)Forspers fea mas th nanrar of he deny ren the ame ‘The dene the pete, he Salers value or sz A et om salt Inge ore of Soe devas. The patina oper eel = 2.18 ‘fen alt thn gold (ent = 1830 gem) hen id ety = 1135 | wen, Measeremens (rs) that ar doe 1 och sha prea, Merona ht ae lose tte" valo he bls ee) arate (0) Figure reps ats ht rth acca and ree The dara coe etal ejeand eachother (©) Figure represen dita tht ate pace ut car, Th dar ech her but ir center fie ea va) fr thule (©) Figure i epee dts hata ops rave ala i acute “Te dar ae fr ron ech ote, haere ao oe it prt inet teal ye (a) 75cm. Thee are wo sign grein henson he aber ‘nb ed pel bu ae sone eating rey mule ead Sethe ofa rine Lit te sige fuer cet wth he ‘oosenton ta masced ques ar npr a ha weeny ‘siya dig (0) The spend 72 m/e fees sii ius) o 315 ke over lets agian igre. Boy sclera rnd th cert te Sandan era” ple, ad sme ancy inte “one” pl The pe ox at pint ge eur mage (0) Volume egw ght. Bc petion mulipton te ‘inesoe wih owt lic gar ig fighter grin be rl The dimen". ha 2g fig oe vee pte wine (0) Dey = mat/vlue. Bs te option etn apn the dat with fewer son gare Seeman he amr of eho Whe ‘ta HK72 ga ig waa om a has gs dena abo ‘poral 25 8s When converting ui arage he overs acs th the gnu cn a the dented unto in thecometpston Fr eampl pp surly expe Inve of cenit bul Seed esl inp incest gv a ‘sc in th nate tha conversa ch mut ave ein ie devetn, Howeur he oat he 'ant i he deren, the ener tor st have Int mea Lely, #6 led othe edt the 2 1 Nate and Measurement Sotations o Exercises ——————— cocsnene 110 Gherea/sFinavei/. Doth the sven and deed wats have dane in de ‘nr ine te devant. Ls appropri cnweDion cr change ‘pnt ithe mame ands wt ne deena a= a= == SSE (Classification and Properties of Matter (sections 12and 13) am) Resrogeneans mitre (©) mops mise (there are undild pale sch at sand ot dein lin, emcure is eogees) fo pocracce (@ pursateance 12) Memogencns ise (Peeper (prtcsint) Gparesubstance (2 Peteogeous mite us 6) 8 MAL @K HA YG) unnun @ nicl) soda ()saminum (eon 1) CNT Em WF plosors cakéam Bem) dg) ser 15 Aw) = BCH ‘When std aon is armed in exes oxi the mers combine frm 2 ‘genus conpoud. carbon inde Castes Cs hs compound Sie C Prtced when Ais hn in he abso yp fom ay Eos caren and ‘Sgn in C mat have bem prea = A gal A efron ‘compos of woo more emer hema) cid Without mown ot ‘he chemcor py prope fs We canst Serine sel whee ea ‘Semen era compound Hower, oH ny ements eat awh i 0 8 ‘pobay abo scompound 136 Cold Anant fo gal" Pe compound bath ar sie nd pe ‘stn Take advtige of ferns i pyc anor chen popeee ‘oe theo astm, Dey sd cng pelt mcaurnens ern cd © ‘Sem sale ors to ates, meng pom ar ery ight rs ae (sy mea ald emach eet an fous gold” ald emacs rca 1 Matter and Measurement Solutions to Exercises rescte than Fes lave ec with ae and bey can eevee (Syermnnts deri meremest e tot Seite had ow nv doo te ‘Sipe te tt mtr setae i acd 4 mage nth os wl ot ea eid) 117 Phy propre avery white lar neous ming pint = ong pin =| PG dry 220" L728 g/cm: psd ino she cull) ew no in (rte gpd conduc, Chen popertin: bur na fo ive iene white Tp ects with produce bite wea 118 Psat pret sor gray (olny ming pone ~ APC: trdnse ~ 25 Mobs Ainay 2733 glam a °C Chl papers mec cs wth sac a rsce ygen gas ct sony wath onygen aleve erat pre 119) Gamal) physal © phys (6) chem (@) cami 120) chemical physica (6) ply! (he podacton of #0 6 a cee hag, Bu cms 2 Pia cnee) (phys (he produton of sot a chara change Bat dtr 2 Piel cans) 121) Tale abvamtage fe rn water Slits fhe ols. Ad water b ate he ge iter smite coecting th sand on he ies paper nd Chenega he la Ere water rm he ae cone sd ge (9) Tle dvannge ofthe cteret Sli and des oft wo gus ‘Alo te mit et ta de ar wo tit ayer Vinge er ‘Stn doer aon eBoy o oa) er ean ad ep. Cally por off moto he op layer the pes fom, a 8 ‘rope to move ny rmning 0. Vier in eile ano 122 Mtb the unc e610" vapor wae, Th ear wit ide contin pure nae —Th oer fo fakes have a, wh ese sere he ming pit of ach ls Soar hea mach ower mel pol ha ssh her wih th lower mein ee conan mga ter an ht ie ‘Dehipher ting reid conned al wate contmaton © regu, este ‘he dona te rie ede) Units and Measurement (section 14) 1B) PaO! | LIT | Lee Tat |) TH © 1 @ tO gy dO? roe nt 1) as Ee IM oat a e © a 0m EE = 1a 157 0 hg «GIB = 87h 16 IB «tm scosiser-se/92-s9s2re 9/500) 3039/5167 o22- a7 Ketcrs 29+ 755K scons K- raise 26-7 -9/5 UE) co5/9 08 8/9 (0 -s) TSHR CEA (rons 0 Ft scnok- mse 7199 ‘Sango hs) “cosner-seyeare Ke SCV MISA BRK EHO ATF so8/9 (ara) erate erce seme 08K syste) 22-4086 CHRIS 219815 « 106G F = 9/S MIND += devty = SA = B58 vogint o Lan? (hector willbe wd inert anal) Teanehorotyne, 162 g/ml, i ore dene an wae, 100 g/l: (starches wl kath tha ato ws, stent = ney wit7e cane gh y= ee) she (589m! 383? ety 24g ion 1 Matter and Measurement Solutions to Exercis © spat « 1 5 88. 75 -setgsanm amon + 18h MERZ rnagteme ‘Theater spray tae, densty #0986 /k. + AB -emtetyime set (sayy ow? SE oar wg ati BEE coogi Bont “Oe ‘The tad ave origin igus, wh th exes ae ae hve The tabula vale round the Spe 0%. The value gee ‘itn ae he niga gu of experi va he tw ese {pe The gu cule ese tm 8 * orig = 83mbaydehoane rege soe2=250 Veaisne 4/3082 25) co! 6488=Bem! Ferexample inthis exe the volume fh sphere 48cm’, rounded ‘Stam, ot 8405 ne In subset caution of mas. 74 10° J coe Sea? 11 g/m! ao yell 74 10" oer re, te ‘ony ound ef fro meds ny ot be eta 1 Matter and Measurement Solutions to Exercises ue, 20 Tims * "men 28 «10 thon one» i ‘Theme pf for 1 10 pt abe rane « hone (Theva he ae det te i 2 ution ne ew ‘Sayer waemcan cto ie 20 A Me gy 270 en (0) Clete te vote the water inc. V=a7h - Rive, ten Lem 75210 on 215em =075mm x TE Ve ath « xSon75« 10% cm) = S901 «Sem? Dany eV; m= dy V 238 5 suntan’ «12m -1200¢ ‘Uncertainty in Measurement (section 1.5) act (an (Al ths depend ot eee al snd ft ve mares ofemoe gst eng ola wees dened by he sean) ‘act (9 (Te nember ster 8 ext onan gien 3) ©) 32 OS M3 SO 1eeSumpletrcer4 4) 193 @t ws He OF (stot @ esrv.10" (@ BSex10* @ 290104 @ as (0) 7910") dante (0) 14380 «248 = r7ans = 7 oe won and abc, emia ‘meri plas ie determi el ple ne) (0) 9s27-ran7s69-8120 (© 629 110240 = 823 «10 (For malian ad ro, he mit ‘amber flan as her thes eens ig gn the re) (@ 008/007 +8090107 1 Mater and Measurement Solutions to Exercises 140°) 20S ~ 6045/23] = 23 » 10° (The ntrmedae rr as two sigan: Figaro ethan nt hundred pain he nwer reign) (6) (ss 10 oon» 10] «2954 = 8260» 10” ne atcton depen co ‘lilacs oth uber at ave tse exponen dterie dca ‘ines/g Te medieval i fe 0 he Tower tases) © pmsxmomy + aNa~1y — =a4nr0 sgh /0 ep 2 iy At age Ce ee eee eo sete /0 dp Seige «de pSsig fl =2siets at Theme 21427 ghana gues 142 Theva inte panel fdr 9S. Lge volume ae reat he on of ena velit eran 0 Volume ht ‘tinker canbe mad wahceiy fo mand witsomeuneny © ml ses ‘Semen eg fn Dimensional Analysis (section 1.6) 149 neh onveron ac hold ut app i te decry, ocean he ‘un appa emer (mms: PI 10 at 0 mete ES tied 0 Mo Te Tote” son 2H sche Uk Ineach coven fn hl i pe in he deominie nlyan he sea epee bane (0) spams PIO 1 0° mem Se te 0 ame mom (mth 1688 1 Matter and Measurement a6 « » @ o » ° » See Se Be Re tate Sono? x = 13x10" gal wit US 1 45095 = 460m lla eee ad atom “ ane 7 NE . * Gono" Taoepiaw * Tin "thr 6707 10 mie vaste «DE ms ys ag = am ‘aes n0m? x PS IL 5.5665 10°. ewe? “aa Pompton , A, gat MB ase Tambo! TAT ig sondage » i, min, 8 aan state ar ay" he * Tain 8, Bin gg iin" The" Be inate 04 80/6061 31/8 ‘ete 1 10m 3? «7100027» 2m 27 20/004 70 cm? sna? = =m 9en4 ono Bhs le est 25m. 0m i Hi fe 4 a5 10h 1 Matter and Measurement Solutions to Exercises 1955? ABDI 2395 = 255790! 22s ° SE am = sans o o asiate (0 4)/1= 1201 im BE e8 Ibo Set ng, © Febei7 "za inte 6/2 3:9 1180S, fo Mim, Ami, 1 tat 898 PSL Tas Tg Teal” we (210 mie for sg) tite 0/508: 8/1645:5/1=5:5%4 «a Rape, st, Te "Soup "Tag (x10 mt/Lort 6) Ente 0/4 1210/50 «2128/1 = mg 257 i AA Sn ctrg wre areal Bsn Seta renter nee ta urges ae eed. The tp eps flere acral urges dsing the are ned Metin, ti, e+ nin » oa an © mee sition ees ioe Tae 14504165. 8002191419510 Gag) see Saal hd ALE stage aod oer tin 90/2 wt 0/1 9g wo 11 Matier and Measurement Solutions to Exercises AR Mogeiseeasaaaynas923900 8 penta, da? MIBCO, 1 1S. s5yyp ea a a? ° 153 Sdetacommon snitorcmyurtoin tice ea. “Theoret lngh om sare lang en he <7 ag 2m.1 Large Stoption cSt, Skemp Sg VpaedgtedLs tL H:O"1gH0:1 Leeog AL = EM ag ‘Thcnder enn mgt av WS pon = | |= [2 rewes | os | oe | 6 | os | w see | wo | we | w | ow | © FR Oi BFA Ot Sethe wo mcs ras fe ume la by friton they ves mer of protons, 54 Thy de im mass ramber fd nn) ese ey are (Dent manor of non, "Maha nets" ha ese @ te (2) Alam weigh ae ely steage soe masse vu he maf ach ‘ney curing wpe of en lent es cna banana B sto wil fave We mr foe ofthe satay ecuing bOOpe, whe he ‘k woght ran average vit The tural our cpa oF it stone masa eae abundances are wn, 1.012937, 18.9%: "8, 11.00830 1am (8) Theatoe elt of ttn port onthe ronnie cover of he tt shundane ugha urge fe stone mane fh 0 nly cg ‘stop of crt, PC. and, The oro PCa aly Hae at {te ori wig f 207 tae no acute perc foe MC a very senges nen Aas wept averages mas) Secon bande ms tops Now ght = 017429259 + C3TR9645279) = 5H56- 55 am ‘Nomicwpht eng ome mas) factor bandas mas ape ‘onic wlgh = 721549118) * 0278596907) = 845) = #547 ama (Th el 2 devia places a sg gn each We he Bs kg ‘grand ci pices) 2 Atoms, Molecules, and lons « » o ® Solations to Exercises Compare Figur 24 and 21, fering Sst 214 In Thomson's eatade ‘ay errs nd as spctenety are of ge pars ps oagh magi fe. Te cared parce re Ghd by the magete fd accord ther man and cage Fora cert gtd rg Apel ped fhe pure ihe prices xperosnedfecion ‘Thess nel (dpe! vale) stom weight and the ys ab (Gepnde arable) sg inet. charged pres ae ot del In age Bd. The fit of he sage Sidon moving cred prs te as of th separtion by ‘he perp fhe mgt in the mas econ change he patho ‘Roving a The mage othe Saronic ons ‘Ethers dcininaton ‘he atm wept of C355 an average ome mast ah verge of he pues of evo natal ecaring tye Weighed yt tanec ‘The singe peak at mas inte mas spectrum fpr iiaes at he mp conn ain tape of le ast sap a ae Avera som ase = 789235850) IOUS + O31025 57) som an “The atv nein of pen th mat space te he same athe ‘lates fh tp The bunds and pak igh an ‘gM Mg ae 782DS 1 ‘Tho pak 14185 HH eH 2.072.016 am 241-200 «2018030219 2 Atoms, Molecules, and Ions Solutions to Exercises 24281 2@040 = ez a (©) °H'Hitagt tena hr ett cha ta ame ne snd ote wlleonbine "=i teal ene he i he ls chan tht wo tame the less abun spe wl combi. “The Periodie Table; Molecules and Tons (sections 25.27) 257) G2 (oma) He rome) (© Zn.20¢oee) Me2iomia) @ Assent) 298) am 3 fret) ( sanaue.2t ee) (©) prem, ets) (yt, 70 et) (manganese 25 (met) (© sn 5 ett) ren st ream) 229 a) Keane) (©) Usage rons (© Matancera et) (Azle gas one) (©) Seager 240 Ceabon,nonne S leon met Grin eS, met Plo a 281 Anemos frie hows We Spl a oft df ome a mace. A ‘tet far shows at rad nde ef atoms lca, Asc! [sale thos ho ac tone a anand, 242 Compound wih ese empl bt df ma oral ier by Inspr nba of pal formu ri the especie teas, Th, ey ct Ive very erent molar Scr sb and ma sling Very eet yal rope. 28) Ay HO | FO, © cena NH, 2 Arete fractal tr in mola, AN emir omala hows he senplot sae som na olor deers in acento (0) moe oma CH, empl emule Ct (©) mae orm SC ental ome: (ste inlet a) (meas Bc emp BH, (moss H,Pasempieea CHO wo 6 M6 OR 25 it i ote Meee BGK HEN aon KH 1 emia Hosa @ NsaH Ho a hon ‘Syatar BEF SE ag Prone 7 Ey 7 a Neaone 2 « m6 ™ one * = ” 7m Nace o 2 » » Sater a Neto 6 s ° ™ Nacoaye + 2 * * Me A OK sh Cn ee 2 Atoms, Molecules, and tons Solutions 253) GR, pllm(tn ents) Ut tm nde (© Ayoluminam iodide (4) KS pouiam de 2k) St, O85 SN 238) Cathy ©) COs AICHICOOIs OHS. MasPOU 256 Cadre RO) (9 He:CO, ——( CGOY, HY .FO, Ton @ Nae e Ra) NRG | ge RG on ror | xtior | germ | rqors cor Keo. | tines | goo, | Refcomn ros" ee a Fatale NTU cS cy a a = a Nor nano, | canoe | Feworn | AWtony sor Naso, | caso. 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