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typical neighbor r
bond energy
Energy
• Dense, regular packing
typical neighbor
bond length
typical neighbor r
bond energy
Si Oxygen
Noncrystalline materials...
• atoms have no periodic packing
• occurs for: -complex structures
-rapid cooling
"Amorphous" = Noncrystalline noncrystalline SiO2
• Coordination # = 8
atoms volume
4
unit cell 2 π ( 3a/4)3
3 atom
APF =
volume
a3
unit cell
Materials Science Chapter 3 8
Face Centered Cubic Structure (FCC)
• Close packed directions are face diagonals.
--Note: All atoms are identical; the face-centered atoms are shaded
differently only for ease of viewing.
• Coordination # = 12
atoms volume
4 3
unit cell 4 π ( 2a/4)
3 atom
APF =
3 volume
a
unit cell
Materials Science Chapter 3 10
FCC Stacking Sequence
• ABCABC... Stacking Sequence
• 2D Projection
A
B B
C
A
A sites B B B
C C
B sites B B
C sites
A
B
• FCC Unit Cell C
• Coordination # = 12
• APF = 0.74
ρ= nA
Volume/unit cell VcNA Avogadro's number
(cm3/unit cell) (6.023 x 10 23 atoms/mol)
Example: Copper
Data from Table inside front cover of Callister (see next slide):
• crystal structure = FCC: 4 atoms/unit cell
• atomic weight = 63.55 g/mol (1 amu = 1 g/mol)
• atomic radius R = 0.128 nm (1 nm = 10-7 cm)
Vc = a3 ; For FCC, a = 4R/ 2 ; Vc = 4.75 x 10-23cm3
Result: theoretical ρCu = 8.89 g/cm3
Compare to actual: ρCu = 8.94 g/cm3
Materials Science Chapter 3 13
Materials Science Chapter 3 14
Materials Science Chapter 3 15
Materials Science Chapter 3 16
Materials Science Chapter 3 17
Linear and Planar Densities
• Linear Density
• Planar Density
•A series regularly
spaced obstacles
•Spacing ~ wavelength
•Constructive interference
Path length difference ~ n λ
•Destructive interference
Path length difference ~ n/2 λ
x-ray
intensity d=nλ/2sinθc
(from
detector)
θ
θc