SOLUTIONS TO THE CLASS 1 AND CLASS 2 PROBLEMS IN TRANSPORT PHENOMENA WARREN E. STEWART EDWIN N. LIGHTFOOT Department of Chemical Engineering University of Wisconsin Madison, Wisconsin New York ~ London, John Wiley & Sons, Inc.CHaerer 4 — Checked by | T. J. Sadowski L.A Computation | Rn of Goses at Low Den Two methods of solution are given in the texts the kinetic theory method based on Eq. |.4-18, and the corresponding states method baxd on Fig. 1.3-1, The kineivc Huory method is mor acurale, Coluulahons by both methods are summarized here. _ Me a Dap y dan [Mei] gmc | =e] nites | 0, 32.00| 3433) 113, 200 | 108 0.02029 | Ne | 202 3681 | as 320 | 1oan 0. 01747 ees 16.04 | | S822] Bt 24 | Lis 0. 01044 | _ Corresponding Stans Merned: oe [ Constants from lable 5-I Pr Me Brvalcted | | Gas | T. (K) | peat) | pe Cop) | = = BE | (fg. bao preny | O. | ies [487 [o0250 tao | 6.020 O82 | Na 126.2 335 0.0180 2.32, 0.030 0.97 0.075 | CHy | 191-0 458 0.0159 1.64 0.022 0.64 0.0110 ‘The observed valus are: 0, (0.0203cp), Na (0.017Sep) , CHy (0.0109 cp), as given wn Table 11-2, L.B Calculation of Viscosities of Gas Mixhares ak Low Density For the binary »yiem bang considered re seo “be He cs CchF, — 2h0 According to Eq, 4-20, & é i. =1, and “Le (HIM (ERIM = 008 an els Bs1 120.4 124, zoie \"4 == 2.) I. 1 f= flies (BR) MCREYAT® = coro Application of Eq. 14-19 than gives: Ze i 2.2 A= Be AtB= | xy | 2xjhy | Lx yhy xi / Ey xpi/ Sa Paine” Hongx 108 er nin Ht i 6.00, 3.434 ie00 0.0 124.0 (124.0) ato | o2s | 3.200 0.13 o4 tau. 3 ant (aa. | OSO! 2.467 0.546 17-4 113.6 130s" 43-4 i o7s | 1734 0.314 32 91, Bos las | 1.00} [.000 0.04z a4 0.0 (88%) Bas (8) Fom lable 8-1 we find that 1,= 126.2°K , pe= 33Satm., and He= 180x 1O~ g crn} sec '. Hence: Pe = pipe = (1000 + 147 )/(33.59C147) = 1-40 b From fig. 13-1) Mr = Lo! = Wh = (400468 / (126.218) = 232 iil Hence the predic viscosity 1S = By He = (-0F)(18Ox 107%) = 1.93 x 107% cow sect (bo) Fem Table lt-2, at 20°C (68°F), po al (6 107 g cmt see. Tom Mig, 13-2 for the vabics 3 Pe Gnd Tp Calculated above, pi = 1, Hence the predicied viseasily 8 i b= pp? = (an yciasxio4) = 1.93 %107* g cmtsec A.D Estimation of Liquid Wiscosity (a) Equation 15-10 may be used with valugof N,h, R fom TableC.2, and nn oT (R) 273-2 373-2 e (gy cm=3) 0.9948 0.4584 V=Mip (cm? g-molcn") 18-02. isso} AG np (cag) at rormal boiling pt) 4989 aq DU np = MAD yup (eat g-mncie™") 3,982 | 8,988 | exp 0-408 AU yu, /RT B.6ox10% | 1.40 x0™ Nas P(g et eet) 2aixio*| aaiaxiot Redined Viscouiry (4 € 0-19 0.0297