TABLA DE DATOS EXPERIMENTALES

V1 (mL V2 (mL x1 x2 n(liq) T(°C) n (cond) y1

Metan) Isoprop)

0 35 0 1 1.3752 74 1.3742 1

2 33 0.1 0.9 1.3708 73 1.3688 2

4 31 0.2 0.8 1.3688 71 1.3656 3

6.5 28.5 0.3 0.7 1.3665 70 1.3604 4

9.135 25.864 0.4 0.6 1.3645 69 1.3539 5

12.12 22.8792 0.5 0.5 1.3639 68 1.3533 6

15.497 19.5023 0.6 0.4 1.3633 67 1.3465 7

19.35 15.63 0.7 0.3 1.3594 66 1.3394 8

23.778 11.2211 0.8 0.2 1.3533 65 1.3340 9

28.9 6.1 0.9 0.1 1.3428 63 1.3297 10

35 0 1 0 1.3272 57 1.3274 11

𝑃 𝑠𝑎𝑡
𝐵′
𝑙𝑛𝑃 𝑠𝑎𝑡 = 𝐴 −
𝑇+𝐶
Sustancia A B C
Isopropanol 18.6929 3640.2 -53.54
Metanol 18.5875 3626.55 -34.29

 Metanol
3626.55
𝑃 𝑠𝑎𝑡 = 𝑒 18.5875−𝑇−34.29

 Isopropanol
3640.20
𝑃 𝑠𝑎𝑡 = 𝑒 18.6929−𝑇−53.54
Conversión de Temperaturas

T(°C) T(K)
74 347.15
73 346.15
71 344.15
70 343.15
69 342.15
68 341.15
67 340.15
66 339.15
65 338.15
63 336.15
57 330.15

Presión Saturada de las diferentes sustancias

Metanol
𝑃 𝑠𝑎𝑡 = 1092.139102 𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 1052.290259𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 976.1985621𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 939.8989377𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 904.726355𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 870.6535337𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 837.6536323𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 805.7002454𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 774.767402𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 715.8616209𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 561.0692578𝑚𝑚𝐻𝑔
Isopropanol
𝑃 𝑠𝑎𝑡 = 541.7588171𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 519.2836443𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 476.6746289𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 456.4972346 𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 437.0429277𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 418.2909967𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 400.2211492𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 382.8135081𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 366.0486077𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 334.3712012𝑚𝑚𝐻𝑔
𝑃 𝑠𝑎𝑡 = 252.8648539𝑚𝑚𝐻𝑔

𝑃 − 𝑃2𝑠𝑎𝑡
𝑋1 𝑎𝑗𝑢𝑠𝑡𝑎𝑑𝑎 = 𝑃1𝑠𝑎𝑡 = 𝑀𝑒𝑡𝑎𝑛𝑜𝑙
𝑃1𝑠𝑎𝑡 −𝑃2𝑠𝑎𝑡
𝑃2𝑠𝑎𝑡 = 𝐼𝑠𝑜𝑝𝑟𝑜𝑝𝑎𝑛𝑜𝑙
𝑃 = 585 𝑚𝑚𝐻𝑔

𝑎𝑗𝑢𝑠𝑡𝑎𝑑𝑎
𝑋1 ∗ 𝑃1𝑠𝑎𝑡
𝑌1 𝑎𝑗𝑢𝑠𝑡𝑎𝑑𝑎 =
𝑃
𝑋1 𝑎𝑗𝑢𝑠𝑡𝑎𝑑𝑎 𝑌1 𝑎𝑗𝑢𝑠𝑡𝑎𝑑𝑎
0.07856601 0.14667523
0.1232937 0.22177907
0.21685722 0.361873
0.26583019 0.42710002
0.31636159 0.4892661
0.36852964 0.54848143
0.42241685 0.604853
0.47811027 0.65848472
0.5357018 0.70947742
0.65697272 0.80393428
1.07764569 1.03356216

Y1 Ajustada VsX1 Ajustada

1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2

T Vs X1 Ajustada
348
346
344
342
340
338
336
334
332
330
328
0 0.2 0.4 0.6 0.8 1 1.2