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Los sulfuros son compuestos de diversos minerales combinados con el azufre. En términos de química,
un sulfuro es la combinación del azufre con un elemento químico o con uno radical. Hay unos pocos
compuestos covalentes con el azufre, como el disulfuro de carbono, y el sulfuro de hidrógeno que son
también considerados como sulfuros.
Pertenecen a esta clase aquellos minerales en cuya composición se encuentra la combinación no
oxigenada de metales y no metales con azufre (S), selenio (Se), teluro (Te), arsénico (As) y antimonio
(Sb) (rara vez Bi).
Los minerales sulfurados, primarios y secundarios, generalmente en yacimientos de tipo “porfídico”.
Composición química de algunos minerales sulfurados, por ejemplo calcopirita (primario), covelina
(secundario), bornita (secundario), calcosina (secundario), enargita (secundario).
El tipo de enlace que presentan estos compuestos es en su mayoría covalente, aunque muchos de ellos
poseen un marcado carácter metálico, algunos son casi aleaciones. También existen sulfuros, los más
simples, con un cierto carácter iónico.
La mayor parte de los minerales de esta clase, se hallan en yacimientos de origen hidrotermal, tanto de
alta los hipotermales, como de media los mesotermales, e igualmente los de baja temperatura,
epitermales. Los elementos metálicos procedentes de focos magmáticos, se depositan cuando bajan las
presiones y las temperaturas. Estos compuestos son transportados en disolución, hasta que al bajar más
la temperatura y aumentar la disociación del SH2, se forman los aniones sulfuro. La presencia
simultánea del sulfuro y de los cationes metálicos en disolución provoca la precipitación de los sulfuros
metálicos en el momento que se alcanza el producto de solubilidad. También se forman sulfuros en
rocas sedimentarias y en formaciones carboníferas, piritas, marcasitas.
Los minerales oxidados son producto de la combinación del oxígeno con un elemento, entre ellos se
cuenta oligisto, corindón, casiterita, bauxita.
En un mineral oxidado, el material del mineral ha sido oxidado o erosionado, posiblemente en un área
que es atípica de los yacimientos sulfuros primarios, y para los cuales se requiere algún tipo de
procesamiento especial.
Incluso el uso de los óxidos es hoy muy limitado debido a la baja cantidad de mineral disponible. En el
caso de los óxidos es posible seguir a un procedimiento de producción similar a la de hierro.
Composición química de algunos minerales oxidados son azurita, malaquita, brocantita, calcantita,
atacamita, crisocola, cuprita. El procesamiento del mineral de óxido de cobre se realiza a través de un
proceso hidrometalúrgico llamado extracción por solvente/ electrodeposición.
Los óxidos son minerales en los que el oxígeno forma enlaces con los metales, sólo oxígeno en el caso de
los óxidos, y oxígeno con hidrógeno (OH-) en los hidróxidos. Comprenden unos 250 minerales
aproximadamente.
El primer paso, la lixiviación, se inicia rociando una solución de baja concentración de ácido sulfúrico y
agua sobre una pila de acopio de mineral de bajo grado. El líquido se percola a través de la pila
disolviendo los minerales de cobre y produciendo un líquido con contenido de cobre llamado “solución
de lixiviación cargada” (PLS). La PLS fluye a un depósito de recolección y luego a una planta de
extracción por solvente donde se mezcla con un diluyente para extraer el cobre. La solución menos el
cobre contenido, llamado refinado, es vuelta a cargar y enviada nuevamente a la pila de acopio para ser
reutilizada, completando así el ciclo. Las mediciones del flujo volumétrico son necesarias para mantener
el control y la eficiencia del proceso.
Composición química de algunos minerales oxidados
Azurita
Malaquita
Brocantita
Calcantita
Atacamita
Crisocola
Cuprita
The selection of the actual sample preparation procedures depends on the type and size of the
sample, the mineralogy, and the client’s analytical and budgetary requirements. Sample
preparation packages are available for commonly used procedures. Please contact our
Laboratory Managers to discuss the most suitable options for your requirements.
Intertek is committed to providing the best advice and modern state-of-the-art equipment to
guarantee the production of precise, accurate and meaningful analytical data.
Discusión
Conclusiones
En esta contribución se ha presentado un modelo descriptivo de vetas
mesotermales portadoras de Pb-Zn-Ag-Au que constituye un aporte inédito a la
metalogénesis de metales base y preciosos de la Faja de Cizalla Guacha
Corral en la Sierra de Comechingones. Las concentraciones de hasta 3,57 g/t
de Au y 216 g/t de Ag son comparables con las encontradas en diversos
distritos mineros de las Sierras Pampeanas, entre los que se destacan
Candelaria y El Guaico, ubicados en la Sierra Grande de Córdoba. Si bien no
se ha determinado aún la mineralogía primaria portadora de los metales
preciosos, ha podido constatarse que los mayores tenores de Au y Ag se
encuentran en las zonas de oxidación de los depósitos (gossans), lo que
evidencia la importancia de los procesos de alteración supergénica para la
reconcentración, especialmente del Au, en estas zonas. La asociación sericita-
hematita-cuarzo se considera diagnóstica de este evento hidrotermal
mineralizante. Las relaciones de campo, las evidencias estructurales,
microestructurales y los estudios petrográficos de las alteraciones
hidrotermales, indican que el emplazamiento de los depósitos ocurrió de
manera posterior a la última fase del evento deformacional (M3b-D3b) de la
FCGC. Los estudios actuales y a futuro se encuentran principalmente
orientados a determinar la potencialidad metalogenética de la FCGC como así
también la influencia del magmatismo devónico como un posible metalotecto de
las mineralizaciones. Para ello no solo se ampliarán las investigaciones sobre
los depósitos del área de estudio sino que se incluirán otros depósitos
emplazados en la misma faja de cizalla y próximos al BCA, por ejemplo, los
que integran el distrito Piedra Blanca ubicados más al sur, de los cuales
tampoco existen referencias sobre su metalogénesis.
Understanding Sampling Techniques
by Chris Ralph
There are a lot of differences between the operations of successful mining companies
and ones that become financial failures, but one of the consistent key differences
between them is their sampling programs. One is reminded of the old saying about the
three most important things to remember about investing in real estate—they are
location, location, and location. For mining it is similar, and perhaps the three most
important things in designing a successful mining project are sampling, sampling,
sampling.
No mineral deposit is uniformly rich; in fact, most are extremely variable. If the property is a good one,
some spots may be rich; some will be lower grade but still rich enough to be profitable; but many will be
too typical toolslow-grade to work profitably. When rock is too low-grade to make money, it is waste
and should not be processed. Large operators spend huge amounts of money on sampling. They have a
good idea before mining begins how much waste and how much ore they have. Successful mining
companies know that the investment necessary for a good sampling program is well worth the time and
dollars expended. Far too often small operators, in a mistaken attempt to reduce costs, conduct little or
no sampling before beginning to mine.
I cannot tell you how many times I have been told things like, “We can’t afford the costs and delays of
waiting to sample,” or, “Old Tom worked this place in the 30s and he told us it was rich,” or, “We know
it’s rich, so there is no need to sample.”
I knew one guy who told me exactly that—I know it’s rich, so there is no need to sample. He sold his
house in the Bay Area of California for around $300,000 in the mid-1980s and invested it all in some
quality used mining equipment. He bought a used dozer, front-end loader, a smaller dump truck and a
nice Gardener-Denver placer plant. Then he and his two sons spent 3 months working that really “rich”
property—the exact same one he told me was so rich he didn’t need to sample. Want to know his total
take for three months commercial-scale mining? He got only three ounces of gold—mostly fines. That
was not even enough to pay for the fuel he consumed, let alone any wages for him and his sons. He lost
his shirt in his placer mining venture. A similar fate happens to commercial mining operations that don’t
do their sampling “homework” beforehand.
If you are running a commercial operation and your total operating costs are $10 per yard to process
gravel, how much $3 gravel should you process? None—because you are losing $7 per yard! How much
$50 gravel should you process? As much as possible! Unfortunately, without good sampling you have no
idea what it is you are putting in the hopper. Is it $50 material or $3 material? You might have some kind
of guess, but who really knows if you don’t have samples! You will find out eventually, but if you ran
money-losing rock the money will be already gone before you find out!
Concepts of Sampling
Designing a sampling program. Probably the first thing one needs to determine is what the goal of your
sampling program is. Mark Twain tells a funny story of miners seeking to sell their property who would
search for hours to find some small piece of ore that was high grade. That tiny fragment, perhaps the
size of a walnut, would be taken in for assaying. The results would show extremely rich ore, with
perhaps hundreds of ounces of silver and many ounces of gold per ton. In selling his claim, the miner
would use the assay as if that quartzreflected the average grade of all the rock the mine produced, even
though there might not be even half a pound of that type of rock in 100 tons of ore. That’s how Twain
got his saying that the definition of a mine was “a hole in the ground with a liar standing next to it.”
Using poorly planned sampling methods is a technique guaranteed to give poor results. When beginning
a sampling project, it’s important to plan what you are doing in advance. When designing a sampling
program the first thing that has to be considered is: What are you trying to determine? Are you
exploring for new deposits or trying to characterize the average grade of a known vein or other deposit?
The goals of a prospecting or exploration sampling program are not the same as the goals in ore
characterization sampling.
In sampling, one is taking a more or less known deposit and testing it to characterize the extent and
grade of deposit, determine its size, typical grade and other characteristics. This is usually done when
considering a commercial mining operation in order to make an economic analysis or feasibility study to
determine if it is economic to mine that deposit. It is important to recognize that most of the gravel in
many placer mines is waste (the same is true for vein rock in most hard rock mines). When you are
prospecting, you are searching for the valuable parts of those deposits, while in sampling, you are
deciding the typical grade and size—what is ore and what is not.
Nugget effect. Designing a good sampling program requires an understanding of the deposit itself.
The famous “nugget effect” occurs when a sample includes a nugget or other piece of high-grade
material, giving an overall value much higher than the true average. Some deposits are like chocolate
chip cookies with a few “chips” of high grade spread thinly through the “dough” of the whole deposit.
Many placers tend to be like this and as a result these types of deposits are very difficult to sample as
you will get a few samples with very high values where the good stuff was included, and many more that
are very low grade where the high grade was not included in the assay. Larger volume bulk samples and
a combination of both the high and the low results need to be considered to give a true average. There
are hard rock deposits with characteristics like this, and they are among the most difficult to sample
properly. Dealing with these kinds of deposits require a good understanding of the size and dispersion of
the mineralization.
Sampling Placers. Sampling of placers is difficult, as placer deposits are typically stratified with increased
concentration of values in layers, especially on bedrock. Often the paying layer of bedrock may extend
one or more feet into bedrock because of crevices. If the placer values are coarse in size, the nugget
effect can be especially bad, making the determination of a true average extremely difficult. Checking
placers by fire assay quartz outcropalmost always gives misleading (higher than expected) results as the
fire assay captures gold within fragments of quartz and other mineralization that normal placer
operations simply cannot recover. Good placer sampling requires larger-sized bulk samples and accurate
collection of materials from the bedrock or other paying strata such as false bedrock or flood layers. It is
also much better to test a placer using recovery methods similar to those that will likely be used when
the deposit is mined.
Sampling mine dumps. Sometimes old dumps contain enough mineralization that they can be
economically mined and processed using updated methods. Special techniques, which consider the
layered structure of mine dumps, must be used since mine dumps are created in a way far different
from natural hardrock deposits. Channels cut across the surface of the dump need to be arranged
perpendicular to the layers of the dump—a direction that is usually parallel to the haulage track on
which the dump was built.
Sampling hardrock. Effective hardrock orebody sampling requires some understanding of the structure
of the ore deposit. Sometimes this can be difficult when the geologist is considering a new deposit—
what direction does the deposit go? Some deposits have sharp contacts with the country rock, and some
just slowly grade from ore into waste. Different techniques are required for surface or sub-surface
deposits. In drilling, the angle and depth of the sample are designed to go (as much as possible) across
the structure of the deposit so that a true sample across the deposit can be obtained. In sampling
hardrock deposits, there are a number of types of samples a geologist might take.
Grab samples are samples of rock material from a small area, often just a few pieces or even a single
piece of rock “grabbed” from a face, dump or outcrop. These are the most common types of samples
collected when surveying an area or beginning exploration for hardrock deposits in the field. The sample
usually consists of material that is taken to be representative of a specific type of rock or mineralization.
It is more associated with exploration programs.
Composite chip samples consist of a series of small chips collected over a larger area. The sample source
may be a line or a grid laid out on the face of an exposed outcrop. Composite samples are normally
taken from similar sorts of material but are specifically intended as representative samples, so the
balance of the material they represent is taken into consideration. The procedure is to collect small
chips and pieces of rock over a large area to make the sample as representative of the material as a
whole as is possible. A composite sample is typically collected to determine the average grade of the
mineralization present. If the area covered is too large, the information as to what is present (i.e., small
high-grade portions) will be lost to the averaging effect of this sample method.
High-grade samples are more like the type of samples Mark Twain mentioned. A high-grade sample
consists of selected pieces of the most highly mineralized material, specifically excluding any less
mineralized rock. As a result, a high-grade sample is not representative of the overall mineralization
found at that location. A high-grade sample might be collected to get an idea of what the richest
possible values are, or to provide material for certain types of trace element analyses. If a very selective
sample like this does not return the expected high-grade results, then it is unlikely that a significant
amount of valuable mineralization is present, so it is sometimes used as a “worst case” type of test.
When a high-grade sample is collected it is important to label it as a high-grade sample, so its values will
not be misinterpreted as representing the “average” values of a deposit.
Channel samples consist of small chips of rock collected over a specified linear interval. Channel
sampling is used for veins and other structures exposed on the surface. The objective is to cut a linear
channel across the vein or orebody in order to obtain the most representative sample possible for the
designated interval. Most of the time, chip channel samples are collected in succession along a sample
line that is laid out in advance using a tape measure, and is designed to parallel the true width of the
deposit. Often the chip channel samples are collected along surface trenches or the floors or walls of
various underground workings.
When chip channel sampling is conducted along a rock face, often a piece of canvas or plastic is laid out
for the material to fall on so as to avoid contamination and make the collection of the sample easier.
Sample intervals are set at a specified width, usually ranging from 1 to 20 feet, commonly 5 feet.
Similarly, with rotary drilling, the geologist can capture a certain length of the chips collected along a
drill hole length, and produce a composited chip sample out of a drill hole.
A century ago, prospectors in the field sampled hardrock deposits by crushing any suspected ore and
carefully panning out the heavy materials, hopefully including gold.
Pan sampling was utilized by the old timers to test veins and other deposits by collecting a sample,
crushing it to fine sand, and carefully panning the results to see what heavy minerals, such as gold,
remain. With old mineexperience, the old timers learned to correlate the amount of color they saw in a
pan full of crushed vein material with the approximate ounces per ton reading one would get from a
normal fire assay. A very large percentage of the hardrock gold mines across the world were originally
discovered using some variation of this method, especially in combination with techniques for pocket
tracing (the method for following placer fragments up a drainage to its source). Many small mines were
run for years based mostly on “panned” assays of channel samples. The advantage of this method is that
it is cheap and quick, and it gives a good evaluation of coarse free gold, but also shows up any sulfides or
other heavy metallic minerals. Because sample results are there to see in only a few minutes, many
samples can be taken and many veins can be tested in a short period. The disadvantage to this type of
analysis is that it won’t capture extremely fine gold or any gold tied up in sulfides or tellurides.
Sometimes crushed sulfides are hard to recognize and rich tellurides are hard to distinguish from things
like pyrite. Some very rich deposits (including those at the Carlin Trend in Nevada) have only very fine
gold, which cannot be panned by this method. The other part of this method is that you still need to
take multiple samples to really characterize the vein. You can’t determine the whole story from one pan
because even if you get a pennyweight of gold in one pan, you won’t know what is typical until you have
taken a few pans.
Geochemical sampling involves collecting and analyzing things like soils, stream sediments and rocks,
and testing for certain chemical elements that are associated with valuable mineral deposits. These
methods are extremely efficient exploration tools and a few well-located sediment samples can be used
to test vast areas for potential mineral deposits. The presence of these trace elements can be nearly
impossible to recognize in a hand specimen, but lab analysis by methods such as Atomic Absorption (AA)
can reveal elevated levels that are only in the parts per million range. Many well-known ore deposits
were discovered using these methods.
Geochemical sampling works because it is fairly normal that large hardrock gold and silver deposits have
a surrounding envelope of weak mineralization, also known as a dispersion halo. They are formed by
“leakage” of mineralizing fluids into the surrounding rocks, and are best developed around large bulk-
type deposits and those deposits that form in rocks that are porous enough to allow for fluid flow. These
halo areas have elevated concentrations of metals commonly found in association with gold deposits.
The concentrations are low, but significantly higher than the normal background levels found in
unmineralized rock. A variety of elements can be analyzed, typically focusing on expected elements that
commonly associate with known deposits. As an example, typical elevated elements that may be found
around epithermal gold or silver deposits include mercury, antimony and arsenic. Knowledge of these
pathfinder elements and which elements are associated with certain types of deposits is critical for
interpreting geochemical test results.
Even after the discovery of a possible new deposit, geochemical sampling is important in delineating the
areas of mineralization. For example, geochemical sampling of soils is often employed to outline the
general area of mineralization at shallow depths where outcrops of bedrock are minimal or nonexistent.
This can then be used in designing drilling programs. Sample results for certain elements are often
plotted on a map to locate regions of elevated concentration.
What does all this mean to the small operator or weekend prospector? The miner needs to know the
difference between exploring and mining, and that exploring always comes first. Explore and prospect
around to find the reverse circulationbest part of your claim. Few small operators spend enough time
prospecting and sampling—they want to move too quickly to mining. The best paystreaks are not always
exactly where you expect to find them. For example, if you are dredging, punch a few holes around to
see where bedrock is, what flood layers are present, how deep the bedrock is, etc. If you don’t find good
gold, move on and prospect further—keep exploring.
Far too many simply find a likely spot and start working down to bedrock. Once they hit bedrock, if
there’s not much there, they just spread the hole in an attempt to find something. It would be much
better to move up or down stream a ways, and then punch another hole.
The message to the individual is to explore and prospect to find a valuable deposit first, then sample to
determine its extent and value second, then mine it third! The most successful individual prospectors
think like snipers, prospecting to find a paying deposit first. Depending on your situation, it might even
be best to evaluate a property with a pan and crevice tools first to determine the best place to bring in a
dredge. When you do bring the dredge, punch a few holes to see how far the paystreak extends. Start
dredging seriously for production at the lower end of that paystreak and mine upstream so you don’t
dump your tailings on top of the unmined part of the paystreak. Don’t start out mining; start out
prospecting, then go to sampling, and finally on to mining.
Exploration sampling and prospecting can be the most difficult part of an operation for small operators
and individuals, but when done correctly, it will have the most rewarding results.