Se entrega distintas funciones objetivos según la concentración de cobre en PLS o alimentación de la primera etapa d

extracción.
Las alimentaciones contienen 2, 6 y 10 g/L de cobre.
La concentración de cobre en el electrólito pobre es de 30 g/L.
Y se espera que en el electrólito rico la concentración de cobre sean de entre 31 y 45 aproximadamente, según el cas

Se evalúan entre pH 1,3 y 2 cada concentración de PLS.

Además se evaluó respecto al tipo de reactivo utilizado, fuerte y debil, con PLS de 3 g/L de Cu y un electrólito pobre c
g/L y electrólito rico con aproximadamente 45 g/L.

Extracción
[Cu] en PLS a1 b0 b1 Función Obj.
�=(2,20192∗𝑋)/(0,17113+0,39196∗𝑋)
2 g/L 2.20192 0.17113 0.39196
�=(2,48685∗𝑋)/(0,22965+0,14997∗𝑋)
6 g/L 2.48685 0.22965 0.14997
�=(2,05437∗𝑋)/(0,41578+0,06758∗𝑋)
10 g/L 2.05437 0.41578 0.06758

Reactivo fuerte y debil Extracción Re-extracción

a1 2.24901683 2.38010469
b0 0.0780712 0.06876277
b1 0.38725844 0.00974344
�=(2,2490168∗𝑋)/(0,0780712+0,3872584∗𝑋)
�=(2,3801047∗𝑋)/(0,0687628+0,0097434∗𝑋)
limentación de la primera etapa de

5 aproximadamente, según el caso.

g/L de Cu y un electrólito pobre con 30

Re-extracción Y=(a1*x)/(b0+b1*x)
a1 b0 b1 Función Obj.
�=(2,93019∗𝑋)/(0,02316+0,06703∗𝑋)
2.93019 0.02316 0.06703
�=(2,25823∗𝑋)/(0,06912+0,03298∗𝑋)
2.25823 0.06912 0.03298
�=(2,25460∗𝑋)/(0,10424+0,02678∗𝑋)
2.25460 0.10424 0.02678
Extracción PLS: 2 g/L

LIX 84 IC LIX 984 N

a1 1.965015594 a1
bo 0.287225195 bo
b1 0.34696509 b1
b2
x y Ycal E^2 x y
0.21 0.864 1.145979402 0.0795123832 0.0747 0.969
0.244 1.13 1.289280884 0.0253704001 0.114 1.25
0.332 1.62 1.621164605 1.356305422E-06 0.197 1.77
0.601 2.68 2.382191589 0.0886898494 0.466 3.02
1.09 3.36 3.21883351 0.0199279778 0.927 4.07
1.94 3.81 3.969573587 0.0254637298 1.98 4.63
Suma 0.2389656967

0 0 0
0.05 0.322584847
0.1 0.610401713
0.15 0.868784081
0.2 1.102027616
0.25 1.313630877
0.3 1.506472017
0.35 1.682940462
0.4 1.845036424
0.45 1.99444705
0.5 2.132605364
0.55 2.260736378
0.6 2.37989351
0.65 2.490987617
0.7 2.594810318
0.75 2.69205289
0.8 2.783321676
0.85 2.869150743
0.9 2.950012338
0.95 3.026325579
1 3.098463729
1.05 3.166760291
1.15 3.292994054
1.25 3.40707723
1.35 3.51068359
1.45 3.605192982
1.55 3.691753132
1.65 3.771326487
1.75 3.844726153
 1.85 3.912643775
1.95 3.975671406
2.05 4.034318805
2.15 4.089027258
2.25 4.140180699

PLS: 6g/L

LIX 84 LIX 984 Líquido iónico media

a1 2.391387358 3.337549004 2.7489156308 2.8259507
b0 0.45233107 0.134917757 0.2183960099 0.2685483
b1 0.098082117 0.156919122 0.1416597567 0.1322203

x y ycal E^2 x y
0.872 2.56 3.877021733 1.7345462443 0.143 3.03
0.973 3.47 4.24784356 0.6050406033 0.244 3.98
1.32 4.63 5.425634615 0.6330344403 0.345 5.71
1.92 8.09 7.166897367 0.8521184708 0.893 10.3
3.1 11.7 9.800954032 3.6063755889 1.89 16.7
6.02 12.9 13.80547879 0.8198918346 6.03 17.6
suma 8.2510071822

x
0 0
0.2 1.013412462
0.4 1.945942145
0.6 2.806900621
0.8 3.604222967
1 4.344713053
1.2 5.034238183
1.4 5.677884884
1.6 6.280084599
1.8 6.844715857
2 7.375187899
2.2 7.874509569
2.4 8.345346423
2.6 8.790068323
2.8 9.210789341
3 9.609401354
3.2 9.987602496
3.4 10.34692134
3.6 10.68873752
3.8 11.01429951
4 11.32473975
4.2 11.6210879
4.4 11.90428221
4.6 12.17517944
4.8 12.43456352
5 12.68315317
5.2 12.92160845
5.4 13.15053673
5.6 13.37049776
5.8 13.58200831
6 13.78554618
6.2 13.9815538
 Líquido iónico
2.401715587 a1 2.202226405 a1
0.169658685 bo 0.194939573 b0
0.425710575 b1 0.403218235 b1

Ycal E^2 x y Ycal E^2 Y=(a1*x)/(b0+b1*x)

0.89054308 0.006155488 0.127 0.96 1.136236839 0.031059424
1.254851117 2.35333E-05 0.156 1.25 1.332396696 0.006789216
1.866247731 0.009263626 0.232 1.78 1.771025859 8.05352E-05
3.040973896 0.000439904 0.525 2.94 2.843300519 0.00935079
3.945455224 0.015511401 1.03 3.92 3.716963555 0.041223798
4.696383874 0.004406819 2.02 4.24 4.406894456 0.027853759
Suma 0.035800772 Suma 0.116357521

0 0
0.628905045 0.511906426
1.131658343 0.936076399
1.54275708 1.293285474
1.885171151 1.59822968
2.174786776 1.861597721
2.422941708 2.091349713
2.637944363 2.293535629
2.826022231 2.472835836
2.991934974 2.632927897
3.139382821 2.776741493
3.271285797 2.90663934
3.389979066 3.024548009
3.497352372 3.132054128
3.594951411 3.230476189
3.68405272 3.320918897
3.765719816 3.404314813
3.840845855 3.481456625
3.910186429 3.553022429
3.974385068 3.619595708
4.033993271 3.681681281
4.089486393 3.739718128
4.189721842 3.845132814
4.27779671 3.93838515
4.355797419 4.021465203
4.425358917 4.095951327
4.487780521 4.1631114
4.544107845 4.223975588
4.595191834 4.27938956
4.641732057 4.330054018
4.684308931 4.37655449
4.723408057 4.419384054
4.759438816 4.458960895
4.792748764 4.495642004

20

18

16

14

12
Li x 84
Cu acuoso

l i x 984
10
LI
l i x 84 Aju
8
l i x 984 Ajus
LI ajus
6
medi a
4

0
0 1 2 3 4 5 6 7

Cu organico
ycal E^2 x y ycal E^2
3.033032702 9.19728E-06 0.316 2.73 3.300865298 0.325887189
4.701695381 0.520844222 0.453 3.59 4.406936776 0.667385695
6.090583668 0.144843929 0.612 5.28 5.514197598 0.054848515
10.83609828 0.287401366 1.32 9.35 8.950878119 0.159298276
14.61886956 4.331103908 2.6 13.5 12.18176588 1.737741188
18.61499838 1.030221719 5.99 14.6 15.43295427 0.69381281
suma 6.314424342 suma 3.638973672

0 0
4.013851193 2.228296798
6.753253214 3.997551813
8.742027036 5.436366543
10.25151811 6.629407969
11.43635108 7.634694082
12.39109613 8.49331378
13.17684418 9.235181745
13.8348175 9.882595198
14.39383972 10.45251341
14.87467131 10.95806489
15.29264482 11.40957117
15.65932997 11.81525896
15.98362121 12.18176588
16.27246877 12.51450655
16.53138232 12.8179418
16.76478585 13.09577984
16.97627247 13.35112859
17.1687908 13.58661238
17.34478321 13.80446254
17.50629003 14.00658825
17.65502899 14.1946327
17.79245655 14.37001784
17.91981578 14.53398039
18.03817402 14.68760105
18.14845291 14.8318284
18.25145242 14.96749841
18.34787027 15.09535072
18.43831778 15.21604215
18.52333284 15.3301579
18.6033906 15.43822112
18.67891238 15.54070091
 6
medias
2.1896525
0.2172745
0.3919646 5

Y=(a1*x)/(b0+b1*x)

Cu en orgánico
3

0 2
0.462200241
0.853762405
1.189730343
1
1.4811592
1.736355182
1.961679982
2.162088337 0
2.341496608 0 0.5 1 1.5 2

2.503041252 Cu en acuoso
2.649263756
2.782245326
2.903706573
3.015082372
3.117578805
3.212217021
3.299867369
3.381276244
3.457087398
3.527858994
3.594077376
3.656168258
3.769420591
3.870119471
3.960242525
4.041372705
4.11479207
4.181550032
4.242513842
4.298406465
4.349835395
4.397314818
4.441282868
4.482115182

0
1.91594847
3.516652825
4.874002726
6.039573319
7.051327345
7.937828109
8.720978993
9.417857604
10.04197542
10.60416245
11.11320098
11.57628772
11.99937619
12.38743401
12.7446389
13.07452967
13.38012387
13.66401034
13.92842274
14.17529845
14.4063261
14.62298428
14.82657317
15.01824071
15.19900421
15.36976845
15.53134077
15.6844439
15.82972674
15.96777353
16.09911176
 LIX 84 IC
LIX 984 N
Líqui do i óni co
LIX 84 Mod
LIX 984 Mod
LI
Medi a

1.5 2 2.5

o
 a1 1.99162512 2.26982447 2.38140236
b0 0.20891215 0.11595037 0.05011169
pH 2 2gpl b1 0.46051395 0.55812861 0.5631728
LIX 84 LIX 984
x y ycal error x y ycal
0.159 0.92 1.12240473 0.04096767 0.0678 0.96 1.00066717
0.195 1.21 1.30013662 0.00812461 0.0943 1.27 1.26967631
0.297 1.73 1.71113298 0.00035596 0.163 1.8 1.78799461
0.641 2.79 2.53248889 0.06631197 0.544 2.95 2.94295976
1.23 3.24 3.1594981 0.00648056 1.12 3.49 3.43052189
2.04 3.37 3.53801338 0.0282285 2.01 3.63 3.68588477
0.15046927

0 0 0
0.015 0.13842274 0.27386371
0.03 0.26825935 0.51317026
0.045 0.39028467 0.7240723
0.06 0.50518304 0.91134373
0.075 0.61356111 1.07874541
0.09 0.71595861 1.22928033
0.105 0.81285727 1.36537538
0.13 0.96328692 1.56533728
0.155 1.10135892 1.73773711
0.18 1.22853594 1.88790606
0.205 1.3460586 2.01988367
0.23 1.45498601 2.13678669
0.255 1.55622787 2.24105833
0.28 1.65056986 2.33464089
0.305 1.73869409 2.41909787
0.33 1.82119564 2.49570202
0.66 2.56306733 3.0932004
0.99 2.96577419 3.36145693
1.32 3.21862818 3.51382442
1.65 3.39215166 3.6120605
1.98 3.51861599 3.68066072
2.31 3.61487879 3.73127814
2.21428398
0.12499141
0.52727179
LI
error x y ycal error
0.00165382 0.0221 0.96 0.8412858 0.01409306
1.0478E-07 0.0274 1.27 0.9955419 0.07532725
0.00014413 0.084 1.87 2.05339246 0.03363279
4.9565E-05 0.396 3.25 3.45272157 0.04109603
0.00353765 1.04 3.92 3.89527217 0.00061147
0.00312311 2.02 4.2 4.05013786 0.02245866
0.00850837 0.18721926

0
0.60999789
1.06619025
1.42023552
1.70298742
1.93401042
2.12631038
2.28887032
2.51031374
2.68637587
2.82971039
2.94866672 4.5
3.04897675
3.13470602 4
3.20881827
3.27352495 3.5
3.33050972
3.72618347 3

3.87982824
2.5
3.96150216
4.01217817
2
4.04668865
4.07170472
1.5

0.5

0
0 0.5 1
 LIX 84
LIX 984
LI
84 a justa da
984 a justa da
LI ajustada

0.5 1 1.5 2 2.5

re ph 1,3 2gpl
LIX 84 LIX 984
x y ycal error x y ycal
0.557 30.1 29.7868568 0.09805867 0.664 30.6 29.9431548
0.715 30.6 30.7182841 0.01399113 0.826 31 31.2088985
0.975 31.3 31.6486335 0.12154535 1.04 31.8 32.3626872
1.2 31.9 32.1507145 0.06285775 1.22 32.4 33.0586923
1.91 33.4 32.9938529 0.16495544 1.79 35.2 34.4206696
0.46140835

0 0 0
0.15 21.7056405 17.5249136
0.3 26.6537761 23.9371584
0.45 28.8457182 27.2621718
0.6 30.0826817 29.2969307
0.75 30.8771264 30.670414
0.9 31.4304853 31.6599232
1.05 31.8380423 32.4067285
1.2 32.1507145 32.9903697
1.35 32.3981825 33.4590535
1.5 32.5989167 33.8436989
1.65 32.7650135 34.1650493
1.8 32.9047259 34.4375401
1.95 33.023878 34.6715273
2.1 33.1266974 34.8746333
2.25 33.2163269 35.0525932
2.4 33.2951514 35.2098047
2.55 33.3650139 35.3496964
2.7 33.4273604 35.4749811
2.85 33.4833419 35.5878331
3 33.5338859 35.6900155
3.15 33.5797478 35.7829733
3.3 33.6215495 35.8679015
3.45 33.6598072 35.9457975
3.6 33.6949533 36.0175
3.75 33.7273527 36.0837194
3.9 33.7573151 36.1450614
4.05 33.7851056 36.2020459
4.2 36.2551212
4.35 36.3046762
4.5 36.3510499
4.65 36.3945392
4.8
4.95
5.1
5.25
5.4
5.55
5.7
5.85
 LI
error x y ycal error
0.43144557 0.262 30.6 30.3012135 0.08927335
0.04363858 0.575 31.1 31.6720161 0.32720246
0.31661685 1.08 31.8 32.2429345 0.19619099
0.43387557 1.44 32.5 32.4092312 0.00823898
0.60735594 2.14 33.2 32.5740956 0.39175635
1.8329325 1.01266213

36

media
0 0
28.6031153 21.6107304
30.6094906 26.7168077
35
31.34233 29.0008687
31.7220682 30.2958898
31.9543603 31.1299463
32.1111209 31.7119742
32.2240378 32.1412137
32.309248 34 32.4708471
32.3758348 32.7319407
32.4293021 32.9438583
32.4731797 33.1192974
32.5098351 33.2669303
32.540916 33.3928824
32.567604 33 33.5016029
32.5907691 33.5964016
32.6110656 33.6797917
Cu acuoso

32.6289953 33.7537157
32.6449493 33.8196989
32.6592372 33.8789555
32.672107 32 33.9324643
32.6837599 33.9810229
32.6943606 34.0252878
32.7040456 34.0658044
32.7129285 34.1030296
32.721105 34.1373486
31
32.7286562 34.169089
32.7356511 34.198531
32.7421491 34.2259155

30
 31

32.7482013 34.2514508
32.753852 34.2753182
32.7591399 30 34.2976758
32.7640989 34.3186627
32.7687587 34.338401
32.7731456 34.356999
32.7772829 34.3745527
32.7811913 34.3911476
32.7848893 29 34.4068603
0 0.5
32.7883934
32.7917186
0
0
 lix 84 lix894 li media
a1 3.33082513 2.99407016 2.79586247 3.04025259
b0 0.0085464 0.01372982 0.00192212 0.00806611
b1 0.09647834 0.07931437 0.08493267 0.08690846
0.5 1 1.5 2 2.5

Cu orgánico
Li x 84
Li x 984
LI
Li x 84 ajustada
Li x 984 a justada
LI ajustada
2.5 3
 a1 2.79103327 3.03897721
b0 0.03761798 0.06349855
b1 0.04440148 0.03295077
Ree ph 2 2gpl

LIX 84 LIX 984

x y ycal error x y ycal
0.786 30.4 30.2513324 0.02210205 0.934 30.5 30.1078519
0.824 30.9 30.9927605 0.00860451 0.976 31.1 31.0065678
0.883 31.9 32.0793884 0.03218021 1.04 31.9 32.3271147
0.918 32.8 32.6896721 0.01217225 1.08 32.9 33.123912
1.26 37.6 37.5861229 0.00019257 1.34 38 37.8275142
0.07525159

0.5 23.3290973 18.9997981

0.53 24.1901758 19.8938863
0.56 25.0145404 20.7664048
0.59 25.8044901 21.618125
0.62 26.562136 22.4497817
0.65 27.2894198 23.2620755
0.68 27.9881309 24.055675
0.71 28.6599205 24.8312181
0.74 29.3063152 25.5893141
0.77 29.9287283 26.3305453
0.8 30.52847 27.0554682
0.83 31.106757 27.7646151
0.86 31.6647201 28.4584956
0.89 32.2034124 29.1375974
0.92 32.7238153 29.8023875
0.95 33.2268446 30.4533138
0.98 33.713356 31.0908054
1.01 34.1841501 31.7152741
1.04 34.6399764 32.3271147
1.07 35.0815375 32.9267066
1.1 35.5094926 33.5144139
1.13 35.9244613 34.0905865
1.16 36.3270257 34.6555607
1.19 36.7177338 35.2096597
1.22 37.0971018 35.7531947
1.25 37.4656164 36.2864649
1.28 37.8237368 36.8097583
1.31 38.1718966 37.3233524
1.34 38.5105056 37.8275142
1.37 38.8399516 38.3225014
1.4 39.1606015 38.808562
1.43 39.4728029 39.2859353
1.46 39.7768855 39.7548523
1.49 40.0731618 40.2155357
1.52 40.3619287 40.6682003
1.55 40.643468 41.1130538
1.58 40.9180478 41.5502967
1.61 41.1859229 41.9801225
1.64 41.447336 42.4027184
2.63035942 2.8201233
0.01366156 0.03825936
0.06409785 0.04715003
media

LI
error x y ycal error
0.15378014 0.573 30.6 29.9108378 0.47494447
0.00872957 0.682 31.2 31.2656164 0.00430551
0.18242697 0.84 32.2 32.7315427 0.28253762
0.05013657 0.998 33.1 33.8149911 0.5112123
0.02975135 1.62 36.9 36.2653592 0.40276894
0.4248246 1.67576885

28.771949
29.2670675
29.7237618
30.1463377
30.538481
39
30.9033649
37 31.2437362
31.5619848
35 31.8601996
32.1402146 LIX 84
33 32.4036465 LIX 984
0.573
32.6519262
31 84 a justa da
32.8863243 984 ajusta ada
33.1079734 LI ajustada
29
33.3178861
27
33.5169705
33.7060434
25 33.8858415
0.5 0.7 0.9 1.1 1.3 1.5 1.7
34.0570309
34.2202154
34.3759436
34.5247152
34.6669862
34.8031735
34.9336591
35.0587937
35.1789
35.294275
35.4051929
35.5119071
35.6146521
35.7136453
35.8090885
35.9011693
35.9900624
36.0759304
36.1589251
36.2391885
36.3168532
 LIX 84
LIX 984
0.573
84 a justa da
984 ajusta ada
LI ajustada

1.7
ree ph 1.3 6 gpl

LIX 84 LIX 984

x y ycal error x y ycal
1.36 31.6 30.9946234 0.36648081 0.701 31.9 29.6864779
1.53 33.1 32.638232 0.21322965 0.899 33.8 33.0922097
2.06 35.7 36.6370453 0.87805389 1.48 37.3 39.369615
2.42 38 38.6717482 0.4512456 2.12 39.7 43.1973241
4.3 45.5 44.9119157 0.34584312 4.38 51.8 48.8662804
0 2.25485306
0
0
0 55
0.5 17.4171347 24.9918277
0.7 21.7151546 29.6666741
0.9 25.165152 33.1071508
1.1 27.9955696 35.7451342
1.3 30.3595592 50 37.8320721
1.5 32.3636391 39.5242974
1.7 34.0841877 40.9241161
1.9 35.5773997 42.1012902
2.1 36.8855399 43.1050249
2.3 38.0410077 45 43.9710208
2.5 39.069057 44.7258095
2.7 39.9896628 45.3895198
2.9 40.8188325 45.9776989
3.1 41.5695438 46.5025459
3.3 42.2524297 40 46.9737673
3.5 42.8762847 47.3991823
3.7 43.448446 47.7851604
3.9 43.9750831 48.1369425
4.1 44.4614213 48.4588802
4.3 44.9119157 35 48.754617
4.5 45.3303882 49.0272263
4.7 45.7201357 49.2793189

30

25
0 0.5 1 1.5 2 2.5
25
0 0.5 1 1.5 2 2.5
 lix 84 lix 984 LI
a1 2.17407975 2.67260776 2.25973449
b0 0.04323568 0.02948993 0.05899038
b1 0.03835283 0.04795941 0.03195641

LI
error x y ycal error
4.8996799 1.4 31.7 30.4988734 1.44270511
0.50096714 1.61 33.3 32.9424675 0.12782947
4.28330642 2 36.3 36.7725918 0.22334304
12.2312761 2.47 38.6 40.4686391 3.4918121
8.60671046 4.22 50.1 49.1939939 0.82084714
30.5219401 6.10653686

15.07121
19.4421927
23.1764615
26.4036952
29.2205956
31.700744
33.901121
35.8665383
37.6327223
39.2285061
40.6774148
41.9988339
43.2088809 LIX 84
44.3210666 LIX 984
45.3468011 LI
84 ajustado
46.2957874 984 ajustada
47.1763284 LI a justada
47.9955714
48.7597019
49.4741001
50.1434683
50.7719338

1.5 2 2.5 3 3.5 4 4.5 5

1.5 2 2.5 3 3.5 4 4.5 5
 a1 2.0470295 2.14557311 2.25067306
b0 0.3213206 0.1658598 0.08507703
ph 2 6gpl b1 0.17241278 0.16940793 0.16134667

LIX 84 LIX 984

x y ycal error x y ycal
0.483 2.66 2.44371008 0.04678133 0.243 2.81 2.51840083
0.7 3.36 3.24183194 0.01396369 0.349 3.72 3.32827129
1.22 4.66 4.69728083 0.00138986 0.757 5.29 5.52257737
2.6 6.75 6.91569575 0.02745508 1.98 8.13 8.4746474
3.97 8 8.07984946 0.00637594 3.62 9.75 9.96895167
5.98 9.23 9.0518323 0.03174373 6.05 11.3 10.9010412
0.12770963

0 0 0
0.1 0.60462493 1.17372328
0.12 0.71823469 1.38283742
0.14 0.82957642 1.5844769
0.16 0.93871735 1.77903545
0.18 1.04572212 141.96687961
0.22 1.25356917 2.32376874
0.26 1.45358649 12 2.6576152

0.3 1.64620833 2.97058087

10
0.34 1.83183741 3.26456533
0.38 2.01084772 3.54124458
8
0.42 2.18358706 3.80210291
0.55 2.70544912 64.55563549
0.68 3.1739693 5.19107771
0.81 3.59692843 45.73417234
0.94 3.9806642 6.20368673
1.07 4.33039094 2 6.6136255
1.2 4.65043793 6.97465131
0
1.33 4.94442957 7.29502557
0 1 2 3 4
1.46 5.21542319 7.58124836
1.9 5.99372297 8.35820698
2.34 6.6090928 8.92916616
2.78 7.1078468 9.36646304
3.22 7.52026486 9.7121152
3.66 7.86697879 9.9921993
4.1 8.16253158 10.2237559
4.54 8.41746915 10.4183913
4.98 8.63962532 10.5842841
5.42 8.83494098 10.7273632
5.86 9.00800327 10.852032
6.3 9.16241036 10.9616289
 LI
error x y ycal error
0.08503007 0.11 2.84 2.40771846 0.18686733
0.15345138 0.142 3.85 2.95954016 0.79291872
0.05409223 0.385 5.54 5.8867911 0.12026406
0.11878183 1.4 9.19 10.1328734 0.88901029
0.04793983 2.96 12.1 11.8401072 0.06754427
0.15916814 6 13.2 12.8224355 0.14255492
0.61846349 2.1991596

0
2.22372828
2.58602372
2.92660185
3.24735856
4 3.54997532
4.10661479
2 4.60669192
5.05841114
0
5.46846333
LIX 84
5.84235944
8 LIX 984
LI 6.1846796
6 847.12165801
ajus atda
984 ajustada
7.85685085
LI a justada
4 8.4491056
8.93641459
2 9.34440168
9.69097671
0
0 1 2 3 4 5 6 7 9.98903516
10.2480983
10.919022
11.3840327
11.725314
11.9864502
12.192706
12.359737
12.4977609
12.6137302
12.71254
12.7977363
12.8719514
 a1 2.18663733 2.1236245 2.13271117
b0 0.2004817 0.04538599 0.03716401
b1 0 0.03837938 0.04123814
ree ph 2 6gpl

LIX 84 LIX 984

x y ycal error x y ycal
2.91 31.1 31.7391295 0.40848654 1.4 31.7 29.9955684
3.03 32.5 33.0479596 0.30025972 1.78 33.1 33.2454619
3.24 34.5 35.3384122 0.70293509 2.38 35.5 36.9653091
3.38 36.9 36.8653807 0.0011985 2.87 37.9 39.1861002
4.26 47.9 46.463468 2.06362432 4.97 46 44.6971884
3.47650418

0 0 0
0.2 2.18138347 8.00433392
0.4 4.36276694 13.9855347
0.6 6.54415042 18.6245773
0.8 8.72553389 22.3276506
1 10.9069174 25.3520585
1.2 13.0883008 27.8687091
1.4 15.2696843 29.9955684
1.6 17.4510678 31.8166865
1.8 19.6324512 33.3935693
2 21.8138347 34.7722617
2.2 23.9952182 35.9879188
2.4 26.1766017 37.0678454
2.6 28.3579851 38.0335715
2.8 30.5393686 38.9023021
3 32.7207521 39.6879515
3.2 34.9021356 40.401894
3.4 37.083519 41.0535184
3.6 39.2649025 41.6506427
3.8 41.446286 42.1998299
4 43.6276694 42.7066298
4.2 45.8090529 43.1757674
4.4 47.9904364 43.6112904
4.6 50.1718199 44.0166868
4.8 52.3532033 44.394978
5 54.5345868 44.7487944
5.2 56.7159703 45.0804369
5.4 58.8973537 45.3919267
5.6 61.0787372 45.6850464
5.8 63.2601207 45.9613745
 LI
error x y ycal error
2.90508711 1.36 31.9 31.1051281 0.6318214
0.02115915 1.63 33.5 33.303763 0.03850895
2.14713073 2.24 36.2 36.8794777 0.46168994
1.65405377 2.95 38.5 39.6148853 1.2429693
1.69731808 5.51 45.3 44.4472566 0.72717139
8.42474885 3.10216098

0
9.39279491
15.8981755
50 20.6701805
24.3201561
27.2022028
29.535603
45 31.4634071
33.082911
34.4625955
35.6520578
40 36.6881006
LIX 84
37.5986084 LIX 984
38.4050939 LI
39.1244202 84 ajusta
984 ajusta
35 39.7699923
LI ajustad
40.3526002
40.8810272
41.3624955
30 41.8029982
42.2075504
42.5803805
42.9250789
25 43.2447138
1 1.5 2 2.5 3 3.5
43.5419229 4 4.5 5 5.5 6

43.8189864
44.0778853
44.3203494
44.5478954
44.761859
 LIX 84
LIX 984
LI
84 ajusta
984 ajustada
LI ajustada

5.5 6
 a1
b0
pH 1,3 y 10gpl b1
LIX 84 LIX 984
x y ycal error x y ycal
2.48 3.85 4.89232685 1.08644527 0.799 4.52 4.68898046
2.85 4.77 5.53898107 0.59133188 1.03 5.86 5.69492866
3.5 6.66 6.62979903 0.0009121 1.79 8.07 8.31448645
5.04 10.1 9.00594694 1.19695209 3.78 12.5 12.3762366
7.73 13.5 12.5686755 0.8673654 6.85 15.8 15.4112744
10.1 14.4 15.2149073 0.66407384 10 2516.7 17.0311573
4.40708058

20

0 0 0
15
0.25 0.54230234 1.71782888
0.55 1.17728935 3.45648797
0.85 1.79570274 4.92155725
10
1.15 2.39818303 6.17290332
1.2 2.4970905 6.36392668
1.25 2.59557508 6.5504159
1.3 2.69363945 5 6.7325305
1.35 2.79128632 6.91042264
1.4 2.88851834 7.08423748
1.45 2.98533815 0 7.25411361
0 2 4 6
1.5 3.08174836 7.42018341
1.7 3.46334479 8.04884818
1.9 3.8385913 8.62580281
2.1 4.20764508 9.15717532
2.3 4.57065817 9.64816224
2.5 4.92777769 10.1031991
3.5 6.62979903 11.9559442
4.5 8.20403079 13.3121738
5.5 9.66434412 14.3478951
6.5 11.0226727 15.164717
7.5 12.2893396 15.8254035
8.5 13.4733201 16.370817
9.5 14.5824549 16.8287052
10.5 15.6236236 17.2185716
 1.85295231 2.09937789 2.17531175
0.84466758 0.28175495 0.16637838
0.03815486 0.0950914 0.09560239
LI
error x y ycal error
0.0285544 0.393 4.94 4.1916991 0.55995424
0.02724855 0.624 6.46 6.0052599 0.20678856
0.05977362 1.12 8.95 8.90957006 0.00163458
0.01531737 3.21 13.6 14.754512 1.33289801
0.15110763 5.93 17.3 17.5911478 0.08476706
0.10966513 9.99 20.2 19.3779807 0.67571579
0.3916667 2.86175824

LIX 84
0
2.85805586
LIX 984
5.4641174
LI
84 a justa da
7.46653177
984 a justa da
9.05326543
LI ajustada
9.28624161
9.51142677
9.72920529
9.93993669
10.1439576
10.3415834
2 4 6 8 10 12
10.5331103
11.2435467
11.8759198
12.4424262
12.9528472
13.4151189
15.1971905
16.4081143
17.2845433
17.948255
18.4683111
18.8867968
19.230821
19.5186336
 a1 2.17175224
b0 0.17823238
b1 0.0109457

re ph 1.3 10gpl

LIX 84 LIX 984

x y ycal error x y ycal
3.06 32.1 31.3875245 0.50762127 2.39 33 33.714453
3.4 34.2 34.2726133 0.00527269 2.62 35.7 35.8126939
3.89 37.8 38.2594641 0.21110722 3.13 40.8 40.030929
4.32 41.3 41.6019032 0.09114552 3.72 44.5 44.2805153
6.47 56.6 56.4191024 0.03272396 6.19 56.9 57.1158142
0.84787066

1 11.4799362 17.4894894
1.02 11.6960005 17.7779336
1.04 11.9115659 18.0644008
1.06 12.1266341 18.3489113
1.08 12.3412069 18.631485
1.1 12.5552859 18.9121416
1.12 12.7688729 19.1909006
1.5 16.7357456 24.1508275
1.88 20.5366341 28.5461127
2.26 24.1817428 32.4679825
2.64 27.6804564 35.9890154
3.02 31.0414206 39.1676753
3.4 34.2726133 42.0515838
3.78 37.3814082 44.6799219
4.16 40.3746307 47.0852208
4.54 43.258608 49.2947156
4.92 46.0392136 51.3313802
5.3 48.7219075 53.2147301
5.68 51.3117717 54.961449
6.06 53.8135427 56.5858846
6.44 56.2316399 58.1004438
6.82 58.5701921 59.5159099
7.2 60.8330608 60.8416998
7.58 63.0238616 62.0860741
 7.96 65.1459833 63.2563087
8.34 67.2026056 64.3588379
8.72 69.196715 65.3993723
9.1 71.1311189 66.3829977
9.48 73.0084592 67.3142586
9.86 74.8312242 68.1972281
10.24 76.6017597 69.0355676
0 0
2.17944999 2.4125922
0.10311468 0.03136184
0.02150017 0.04787974

LI
error x y ycal error
0.51044311 1.07 33.5 31.255295 5.03870072
0.0126999 1.91 36.1 37.5211343 2.01962275
0.59147016 3.59 40.5 42.6135347 4.46702874
0.04817352 5.24 43.1 44.7897505 2.8552567
0.04657576 9.86 50.4 47.2497169 9.92428347
1.20936246 24.3048924

60

55
30.4460384
30.6841565
30.9166553
31.1437315 50
31.3655724
31.5823573
31.7942568 45
35.0730505
37.3688576
39.0661036
40
40.371877
41.4076139
42.2492305
42.9466246 35
43.5339422
44.0353387
44.4683836 30
44.8461617
45.1786185
45.473448
25
45.7366962 0 2
45.9731794
46.186782
46.3806714
46.5574563
46.7193044
46.8680321
47.0051725
47.1320292
47.2497169
47.3591952
0
0
0
0
60

55

50

45 LIX 84
LIX 984
LI
84 ajusta do
40 984 ajustada
LI ajustada

35

30

25
0 2 4 6 8 10 12
LIX 84
LIX 984
LI
84 ajusta do
984 ajustada
LI ajustada
 a1 2.06502391 2.07084856 2.0627235
b0 0.42737626 0.40738982 0.36708923
b1 0.0599372 0.05862921 0.05803521

ph 2 10gpl

LIX 84 LIX 984

x y ycal error x y ycal
1.38 4.16 5.5867303 2.03555935 1.32 4.49 5.63867735
1.69 5.41 6.60126275 1.41910693 1.57 5.81 6.50978574
2.16 7.41 8.01028441 0.36034138 2.21 7.79 8.5231157
3.5 12.8 11.3434992 2.12139465 3.54 13.3 11.9212235
5.56 16.9 15.0948254 3.25865523 5.95 17.5 16.2933107
9.93 18.9 20.0534299 1.3304006 10.3 20.2 21.0920195
10.5254581

1 4.23756797 4.44369961
1.05 4.4222506 25
4.63671764
1.1 4.60468932 4.82733751
1.15 4.78492478 5.01560363
20
1.2 4.96299665 5.20155934
1.25 5.13894366 5.38524691
1.3 5.31280362 15
5.56670757
1.35 5.48461344 5.74598159
1.5 5.9880984 6.27107199
10
1.65 6.47438078 6.77784226
1.8 6.94432742 7.26723473
1.95 7.39874788 7.7401282
5
2.1 7.83839908 8.19734318
2.8 9.71448744 10.1449738
0
3.5 11.3434992 11.8316424
0 2 4
4.2 12.771228 13.306505
4.9 14.0328093 14.6071014
5.6 15.1556509 15.762595
6.3 16.1614461 16.7959855
7 17.0675901 17.7256561
7.7 17.8881934 18.5664759
8.4 18.6348228 19.3306014
9.1 19.3170495 20.0280683
9.8 19.9428619 20.6672346
10.5 20.5189796 21.2551168
 LI
error x y ycal error
1.31945966 1.2 4.21 5.66771183 2.12492379
0.48970008 1.45 5.33 6.62828466 1.68554307
0.53745863 2.02 7.93 8.60319291 0.45318869
1.90102469 3.23 13.3 12.014573 1.65232269
1.45609918 5.41 18.5 16.3852504 4.47216605
0.79569875 10.1 20.6 21.8553574 1.57592217
6.49944099 11.9640665

4.85204636
25 5.06011002
5.26537158
20
5.46788728
5.66771183
5.86489854
LIX 84
15 6.05949929
LIX 984
6.25156462
LI
84 ajustada
6.81303408
10 984 ajustada
7.35338319
LI a justada
7.87378165
5 8.37531435
8.85898892
10.9058886
0
0 2 4 6 8 10 12 12.6611265
14.1828949
15.5148708
16.6904758
17.7357197
18.6711466
19.5131995
20.2751946
20.968031
21.6007151
22.1807549
 a1 1
b0 1
b1 1
ree ph 2 10gpl

LIX 84 LIX 984

x y ycal error x y ycal
2.5 32.6 0.71428571 1016.69878 3.6 32.3 0.7826087
2.89 34.5 0.74293059 1139.53974 3.83 34.5 0.79296066
3.41 39.2 0.77324263 1476.61568 4.22 39.4 0.80842912
4 43 0.8 1780.84 4.47 43.1 0.81718464
5.91 62.7 0.8552822 3824.76912 6.97 61.5 0.87452949
9238.46331
 1 1
1 1
1 1

LI
error x y ycal error
993.345955 3.31 32.6 0.76798144 1013.27741
1136.1645 3.72 34.8 0.78813559 1156.80692
1489.30934 4.55 38.5 0.81981982 1419.79598
1787.83647 5.14 42.2 0.83713355 1710.88672
3675.44768 7.04 61.1 0.87562189 3626.97572
9082.10395 8927.74274
Reactivo débil Reactivo fuerte
a1 2.1338426 a1 2.3641910
b0 0.1241334 b0 0.0320090
b1 0.3422559 b1 0.4322610

x y ycal E^2 x y ycal

0.00689 0.0264 0.116230463 0.008069512 0.00541 0.0264 0.372378766
0.029 0.234 0.461598983 0.051801297 0.0301 1.57 1.580678366
0.0393 0.404 0.609518208 0.042237734 0.0299 2.02 1.573196538
0.0584 0.683 0.864664032 0.03300182 0.0652 2.69 2.560877169
0.145 1.68 1.780652593 0.010130945 0.156 3.58 3.70884597
0.285 2.79 2.743391682 0.002172335 0.279 4.04 4.322196096
0.515 3.86 3.658276749 0.04069227 0.512 4.52 4.778282274
1.05 4.78 4.633970413 0.02132464 1.05 4.99 5.109050593
1.32 4.97 4.890809399 0.006271151 1.32 5.11 5.178835538
1.79 5.21 5.184209741 0.000665137 1.78 5.27 5.250916406
2.4 5.38 5.416143912 0.001306382 2.4 5.4 5.305658795
2.61 5.4 5.473964989 0.00547082 2.61 5.44 5.318466821
2.89 5.46 5.539445858 0.006311644 2.89 5.49 5.332721056
2.99 5.48 5.56018127 0.006429036 2.99 5.51 5.337180499
0.235884725 0
0
0 0 0 0
0.0025 0.04268058 0.0025 0.178620378
0.005 0.084780775 0.005 0.345942828
0.0075 0.126312343 0.0075 0.5030064
0.01 0.167286727 0.01 0.650726518
0.02 0.325830821 0.02 1.163074287
0.03 0.476300182 0.03 1.576941047
0.06 0.884990806 0.06 2.4480528
0.09 1.239513376 0.09 3.000562393
0.12 1.549967761 0.12 3.382236817
0.15 1.82408987 0.15 3.661699865
0.5 3.613480391 0.4 4.615006746
0.65 4.001726807 0.65 4.909998044
0.9 4.443820709 0.9 5.053564221
1.15 4.739786405 1.15 5.138486482
1.4 4.95179934 1.4 5.194602985
1.65 5.111143276 1.65 5.234444873
1.9 5.235276068 1.9 5.264195352
2.15 5.334707703 2.15 5.287257476
2.4 5.416143912 2.4 5.305658795
2.65 5.484064599 2.65 5.320682549
2.9 5.541576597 2.9 5.333180495
3.15 5.590902281 3.15 5.343740204
0
0
 2.2490168 2.249016831
0.078071198
0.387258442

E^2
0.119701306 3.379019236 8
0.000114027
0.199633333
0.016672705
0.016601284 7
0.079634637
0.066709733
0.014173044
0.004738331 6
0.000364184
0.008900263
0.014770313
0.024736666 5
0.02986658
Cu en Orgánico

0.596616407

0 4
0.071135991
0.140550393
0.208304955
0.274458509
3
0.524146364
0.752272203
1.332004733
1.792450624
2.166992359
2
2.477619074
3.861394459
4.432713397
4.744719028 1
4.94130379
5.076517175
5.175217976
5.250436473 0
5.309661923
0 0.5 1 1
5.357504866
5.396959019
5.430052881
5.458209718
 Reac
Reac
debi
fuer
med

1 1.5 2 2.5 3 3.5 4

Cu en acuoso
 Reactivo débil
Reactivo fuerte
debil calculada
fuerte calculada
media

4
Reactivo débil Reactivo fuerte

x y ycal error x y ycal

0.232 30 30.25630821 0.065693898 1.43 30 29.98785426
0.283 34.9 34.78366797 0.013533141 1.67 34.9 35.02078085
0.345 39.9 39.63165797 0.072007443 1.91 39.9 40.05370744
0.426 45 45.08536915 0.007287892 2.14 45 44.87692875
0.513 50 50.06147358 0.003779002 2.38 50 49.90985534
suma 0.162301375 suma

0
0 0 1.4 29.35873844
0.05 8.337414006 1.43 29.98785426
0.1 15.48931574 1.6 33.55284393
0.15 21.69177675 1.77 37.11783359
0.2 27.12209132 1.94 40.68282326
0.21 28.12802912 2.11 44.24781293
0.22 29.10952945 2.28 47.8128026
0.23 30.06747213 2.45 51.37779226
0.24 31.00269524 2.62 54.94278193
0.3 36.17917894
0.36 40.71080223
0.42 44.71099978
0.48 48.26807475
0.54 51.45179344
0.6 54.31800683
error 50
0.000147519 48
0.014588013
46
0.023625976
0.015146532 44
0.00812606
42

Cu en acuoso
0.0616341
40
38
36
34
32
30
0 0.5 1 1.5 2 2.5 3 3.5
Cu en organico

debil fuerte
a1 2.122754847 2.637454524
b0 0.011755951 0.125769584
b1 0.019486879 0
 Reactivo débil
Reactivo fuerte
debilajustada
fuerte ajustada

.5 3 3.5 4