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NOVATEUR PUBLICATIONS

JournalNX- A Multidisciplinary Peer Reviewed Journal


ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
PERFORMANCE STUDY OF COAGULATION & BALLAST FLOCCULATION
FOR RECYCLE BASED KRAFT PAPER MILL
MRS. SUSHMA SANGRAM KUMBHAR
Research Scholar, Environmental Science and Technology, Faculty of Engineering and Technology, Shivaji University,
Kolhapur, Maharashtra India

MR. S. M. BHOSALE
Coordinator, Environmental Science and Technology, Faculty of Engineering and Technology, Shivaji University, Kolhapur,
Maharashtra India

ABSTRACT: gaining importance day to day. Bagasse and wheat straw


The pulp and paper industry is one of India's is used in Northern India. Wheat straw is not available in
oldest and core industrial sector. The socio- plenty because it is a regular cattle feed and rice straw is
economic importance of paper has its own value to not a suitable raw material for large and medium paper
the countries development as it is directly related to mills especially for the production of good quality
the industrial and economic growth of the country. papers. Bagasse is a suitable raw material for most grade
Although paper has many uses, its most important of paper and its availability is increasing day by day as
contribution to modern civilization is its use as a more and more sugar mills improving their boiler
medium to record knowledge. efficiency to spare more and more bagasse for paper
Paper manufacturing is a highly capital, industry.
energy and water intensive industry. It is also a
highly polluting process and requires substantial LITERATURE REVIEW:
investments in pollution control equipment. Present Hanif et al.,(2006) adopted Cassia fistula for physoco-
research work describes a study of Coagulation & chemical treatment of textile wastewater as coagulation
Ballast Flocculation for Recycle based Kraft paper and TDS removal. The methodology was to find optimum
mill. pH and optimum dose by using the Jar test apparatus.
They observed that, the optimum pH for both units viz.
INTRODUCTION: Dyeing unit and finishing unit, was 6. By addition of
Today there are more than 600 pulp and paper sulfuric acid the alkaline wastewater was brought to the
mills in the country, nearly 6.2 million tons of paper, optimum pH. Dosing was varied from 250 mg/l to 1500
paper boards and news print is produced against an mg/L and TDS removal achieved was from 15% to 88%
operating installed capacity of nearly 8.5 million tons and turbidity removal from 10% to 60%.
(Shukla et al., 2008). According to recent studies, the Aziz et al.,(2007) studied the effect of Alum, Ferric
Indian paper industry is poised to grow from 7.2 million chloride, Ferrous sulfate, Ferric sulfate for removal of
tones in 2005-06 to 13.95 million tones in 2015- 2016. color from landfill leachate. The study shows that ferric
The demand for paper in India is witnessing a healthy chloride is the most efficient coagulant as compared to
growth of 7 % to 8% compared to 5% in the past, and the others. They studied the effect of coagulant at
there is huge potential for more (Prinen et al., 2008). The different pH like 4, 6 and 12. At lower pH 4 optimum
paper is manufactured from three major kinds of raw doses of all coagulants was observed to be more efficient
materials, viz. wood, agricultural residues and recycled than at other pH. For Alum the optimum dose was 2200
fibers. The total wood used in paper manufacturing is 5.8 mg/L with color removal efficiency of 82%. In case of
million ton per year in India (Panwar et al., 2008). Fast Ferric chloride it 800 mg/L with color removal of 94%.
depletion of natural forest in the country has resulted in Zonoozi et al., (2008) studied the efficiency of PAC and
acute shortage of forest-based raw material for the Alum for removal of Acid red 398 dye from an aqueous
paper industry. Efforts were made for the plantation of solution using the Jar test apparatus. The study was
fast growing trees like eucalyptus. But the supply of carried using the Jar test apparatus. In case of PAC the
wood is not sufficient to meet the growing demand of best removal efficiency was nearly about 80% at the
paper industry. Because of this short supply of dose of 100 mg/L to 120 mg/L, whereas for Alum it was
eucalyptus and bamboo, the agricultural residues have 60% at the dose of 140 mg/L to 160 mg/L. They also
gained importance. Wheat straw, rice straw and other studied the effect of coagulation aid Bentonite, which
grasses are being used since long but the bagasse, which resulted in an enhanced performance in color removal,
is a waste, obtained after extraction of sugar juice is

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NOVATEUR PUBLICATIONS
JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
and this was increased by 15% for alum and 9% when COAGULATION –FLOCCULATION AND BALLAST
used with PAC. FLOCCULATION:
Guendy (2010) the effect of coagulants for various In wastewater treatment, coagulation and
dosage and pH for color removal was examined using the flocculation are employed to separate suspended solids
Jar test apparatus. The effect of Ferric chloride was from water. Although the terms coagulation and
compared with the results of Alum. The effective dose for flocculation are often used the single term "flocculation"
both coagulants was 50 mg/L in the pH range of 4-6. The is used to describe both; they are, in fact, two distinct
efficiency observed at the above condition was 90%. processes. Finely dispersed solids (colloids) suspended
Aygun and Yilmaz,(2010) studied the effect of in wastewaters are stabilized by negative electric
coagulation with Ferric chloride by providing coagulant charges on their surfaces, causing them to repel each
aid as polyelectrolytes and clay minerals like other. Since this prevents these charged particles from
montmorillonite and bentonite for treatment of colliding to form larger masses, called flocks, they do not
Detergent wastewater. Optimum condition ferric settle. For removal of colloidal particles from
chloride was obtained at pH 11 with dosing of 2000 suspension, chemical coagulation and flocculation are
mg/L in which COD removal achieved was 71%. Using required. These processes, usually done in sequence, are
clay minerals at the dose of 500 mg/L with ferric a combination of physical and chemical procedures.
chloride provided 84% of COD removal and removal Chemicals are mixed with wastewater to promote the
efficiency using polyelectrolyte was 87%. aggregation of the suspended solids in to particles large
Parmar et al.,(2011) studied the use of Ferrous enough to settle or be removed. Coagulation is the
sulfate and Alum as a coagulant in treatment of Dairy destabilization of colloids by neutralizing the forces that
industry wastewater. They studied the use of coagulants keep them apart. Cationic coagulants provide positive
in the Jar test apparatus in the Jars of 1000 ml capacity. electric charges to reduce the negative charge (zeta
The study was conducted at the optimum pH of 4.5 with potential) of the colloids. As a result, the particles collide
the varying dosage from 25 mg/L to 500 mg/L to form larger particles (flocs).Rapid mixing is required
Appreciable COD removal was observed at optimum pH to disperse the coagulant throughout the liquid.
of 4.5 with dose 100 mg/L with 99% of turbidity Ballasted flocculation, also known as high rate
removal at the same dose and pH . clarification, is a physical-chemical treatment process
Islam et al.,(2011) studied the efficiency of coagulants that uses continuously recycled media and a variety of
combination for treatment of tannery wastewater. They additives to improve the settling properties of
studied the effect of Alum, Ferric chloride and Lime and suspended solids through improved floc bridging. The
their combination. The results for alum and ferric objective of this process is to form micro floc particles
chloride as an individual coagulants was obtained to be with a specific gravity of greater than two. Faster floc
satisfactory with color removal efficiency of 85% and formation and decreased particle settling time allow
82% respectively than their combination with other clarification to occur up to ten times faster than with
coagulants, at pH 6.83 and 5.73, the dosing was 70 mg/L. conventional clarification, allowing treatment of flows at
In case of COD removal, alum and ferric chloride a significantly higher rate than allowed by traditional
achieved the removal efficiency of 80% and 79% unit processes. Ballasted flocculation units function
respectively. through the addition of a coagulant, such as ferric
Literature review defines that Coagulation, sulphate, an anionic polymer, and a ballast material such
ballast Flocculation system has potential application in as micro sand, a micro carrier, or chemically enhanced
treating wastewater from recycle based Kraft paper mill. sludge. When coupled with chemical addition, this
Objectives were set to study the wastewater ballast material has been shown to be effective in
characteristics of Kraft paper industry. To carry out reducing coagulation sedimentation time.
experiments on bench scale with Jar test.To perform
coagulation and ballast flocculation for removal ADVANTAGES OF COAGULATION- FLOCCULATION
efficiency of suspended solids, color, chemical oxygen AND BALLAST FLOCCULATION:
demand. To determine optimal dose for coagulant, i. Coagulation–flocculation is one of the most
ballast flocculation for removal efficiency of suspended important physicochemical treatment steps in
solid, color, chemical oxygen demand. To verify the effect industrial wastewater treatment to reduce the
of reuse micro sand on removal efficiency of suspended suspended and colloidal materials.
solid, color, chemical oxygen demand. ii. It reduces the organic matters which
contributes to the BOD and COD content of the
wastewater

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NOVATEUR PUBLICATIONS
JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
iii. Addition of coagulants involves destabilization BALLASTING AGENT (BA):
of the particulate matters present in the The micro sand of 90 to 150 micron diameter
wastewater, followed by particle collision and was used for the experiments. It was collected from Patil
floc formation which results in the Enviro Engineers, Hatkanangale, Kolhapur Specific
sedimentation. gravity of micro sand is more than 2.6 and having
iv. Coagulation and flocculation can be used density of 2700 kg/m3.
effectively for color removal.
v. Large sand particle surface area serves as a METHODOLOGY:
“seed” for floc formation i. The analysis of parameter namely suspended solids,
vi. Microsand and polymer produce a large, stable color, chemical oxygen demand and treated effluent
floc will be carried out as per Standard Methods for
vii. Microsand (specific gravity 2.65) serves as Examination of Water & wastewater prepared and
ballast for the formation of high-density floc published by American Public Health Association
viii. Enhance coagulation allows for variable process (APHA) for raw vegetable tannery wastewater.
chemistry. ii. Jar test apparatus will be used to determine optimal
ix. The reduced surface area of the clarifiers dose of coagulant and ballast flocculent for Color, SS,
minimizes short-circuiting and flow patterns and COD removal.
caused by wind and freezing iii. Experiment will be conducted using reuse micro
x. Systems using ballasted flocculation can treat a sand for ballast flocculation.
wider range of flows without reducing removal
efficiencies. JAR TEST EXPERIMENT:
xi. Enhanced primary clarification. Jar testing is a common laboratory procedure
used to determine the optimum operating conditions for
MATERIAL AND METHODOLOGY: water or wastewater treatment. Jar test simulates the
MATERIAL: coagulation and flocculation processes where optimum
WASTEWATER SAMPLE: conditions are determined empirically rather than
The sample was collected form Biltube theoretically. The values that are obtained through the
Industries Ltd., Warnanagar, Tal. Panhala, Dist. Kolhapur experiment are correlated and adjusted in order to
The nature of sampling done is grab sampling. Grab account for the actual treatment system. The main
Sampling means all of the test materials are collected at variables coagulant dosage and pH were investigated in
one time. this research.
The jar testing process can be summarized as
ALUM: 1. Six beakers are used for the experiment.
The aluminum sulphate, Al2 (SO4)3.18H2O was 2. Measure the equal volume of sample into each of
Chemicals in the form of white crystalline solid. The beakers.
molecular weight of the aluminum sulphate is 666.43 3. Place the beakers such that the paddles are in
g/mol. was purchase from Eagle Scientific Company center.
Gangavesh Kolhapur in the solid form. For the 4. Record the sample temperature, pH turbidity,
experiment it is used in powder form with dosed in COD and color at start of test.
grams. 5. Experiments will be conducted for determining
optimum pH and optimum dose of coagulant
FERRIC CHLORIDE (FECL3): and flocculent.
Ferric chloride, Fe2Cl3.6H2O was purchased 6. Experiment will be conducted using 90- 150
from Eagle Scientific Company Gangavesh Kolhapur. The micrometer size microsand for ballast
molecular weight of the ferric chloride is 270.30 g/mol. flocculation with maximum removal and
The powder form is used at the time of experiment. optimum dose of coagulant and flocculent.
7. Experiment will be conducted using reuse of 90-
FLOCCULENT IND-FLOC 441: 150 micrometer size microsand for ballast
Ind-Floc 441 is a high molecular weight flocculation with maximum removal and
polyacrylamide. It was appeared white granular powder, optimum dose of coagulant and flocculent.
with bulk density 0.6-0.8 gm/ml. This flocculent is 8. After the final settling withdraw adequate
anionic type .It was purchased from Ion Exchange India sample volume of supernatant from Jar .
Ltd. sales office: Pune Road, Kasarwadi, Pune-India.

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NOVATEUR PUBLICATIONS
JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
9. Record the Supernatant liquid temperature, pH chemical and recycling practices of wastewater. The
turbidity, COD and color recycling practices and addition of lime in primary
treatment increases concentration which contributes to
ANALYTICAL METHODS: the high alkalinity of the waste. Color is an important
All of the quality parameters that applied in the character of Kraft paper waste water; it is due to
study such as total suspended solids (TSS), chemical presence of lignins in it. TSS is due to the fine fiber of
oxygen demand (COD), color and pH were analyzed pulp. Coagulation-flocculation process was conducted for
according to the procedures described in Standard the treatment of the Kraft paper wastewater. Jar tests
Method for the Examination of Water and Wastewater were carried out in order to establish a practical
(APHA, 2002). understanding of coagulation performance and to find
Table 1: Parameters of analysis and their method. optimum pH, coagulant dosage and color removal
Sr. Parameter of analysis Method efficiency.
No.
1 pH Electronic pH meter
2 Colour Spectrophotometer
JAR TEST RESULT BY USING CHEMICAL COAGULANT
3 Total suspended solids Oven Drying Method ALUM:
4 COD COD Reflux Method Alum is both a specific chemical compound and a class of
chemical compounds. The specific compound is the
RESULTS AND DISCUSSIONS: hydrated potassium aluminium sulfate (potassium alum)
INTRODUCTION: with the formula KAl(SO4)2·12H2O. The wider class of
To Study the Efficacy of Coagulation and Ballast compounds known as alums have the related empirical
Flocculation for recycle based Kraft paper mill formula, Al2(SO4)2·14H2O.
Wastewater. Aluminum Sulphate, Ferric chloride , as a
Coagulant along with IND-FLOC 441 as a Flocculent were
used to find removal efficiency of TSS, Color and COD.
The Ballast Flocculation was done by using micro sand,
Aluminum Sulphate along with IND-FLOC 441 and also
the effect of reused micro sand on removal efficiency for
TSS, Color and COD was studied.

CHARACTERIZATION OF WASTEWATER:
In order to know the variation in pollution
strength of combined wastewater, the wastewater Fig 1: Chemical Coagulant - Alum
sample from collection tank & final treated water tank
were collected and analyzed. The industrial wastewater CHEMISTRY OF ALUM COAGULATION:
characteristics of Biltube Industries Ltd. are given in When alum is added to water it undergoes the
Table 4.1. reaction below. The alum reacts with bicarbonate to
Table 2 : Wastewater Characteristics form aluminum hydroxide, a precipitate. The coagulation
Untreated Treated
Parameter Standards reactions are as follows:
Effluent Effluent
pH 6.5 to 8.0 5.5 7.16
Al2(SO4 )3 + 3Ca(HCO3 )2 2Al(OH)3 + 3CaSO4 +
Colour Clear Brown Slight Brown 6CO2
Temperature oC - 32 33 Precipitate salt gas
COD (mg/L) 250 10500 800 Al2(SO4) 3 + 3Na2CO3+ 3H2O  2AI(OH)3 +
BOD5 (mg/L) 100 6500 450
3Na2SO4 + 3CO2
TSS (mg/L) 100 2200 750
Al2(SO4 )3 + 6NaOH  2AI(OH)3 + 3Na2 SO4
TDS (mg/L) 2100 6800 5000
Al2(SO4 )3 + 6H2O  2AI(OH)3 + 3H2SO4
Chlorides (mg/L) 600 700 300 (A. Koohestanian et al., 2008)
Sulphates (mg/L) 1000 1810 500
EFFECT OF PH : The pH is a key parameter in the
EC (μmhos /cm) - 7525 1050 coagulation process. The optimum value of pH depends
The characterized effluent is acidic in pH, on the properties of the wastewater treated, type of the
because processes like addition of alum and due to coagulant used and its concentration. (Farajnezhad et.al)
recycling practices of wastewater; the nature of the The pH affects not only the surface charge of coagulants,
waste is acidic. High COD value is due to the addition of but also the stabilization of the suspension; it is the most
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NOVATEUR PUBLICATIONS
JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
important variable in the coagulation process for water JAR TEST RESULT BY USING CHEMICAL COAGULANT
treatment. A suitable pH will help to neutralize the FERRIC CHLORIDE: Ferric chloride is the iron salt used
negative charge of colloidal particles and to form most commonly in precipitation application. The
linkages between colloid particles, thus effectively addition of ferric chloride to a wastewater produces the
helping with floc formation and reaching the expected hydrolysis of the ferric chloride with the consequent
settlement.( Nasir et.al) In this experiments were formation of insoluble ferric hydroxide. The insoluble
performed to assess COD, TSS and Colour removal as ferric hydroxide forms a floc responsible for colloid
well as coagulation-flocculation at various pH values. removal. If the wastewater is not buffered the PH is
The optimum pH obtained was 6 at a constant alum dose decrease which will prevent the reaction from
of 200mg/L. At a pH of 6 the optimum percent removal proceeding any further. In the presence of calcium or
for TSS, COD and Colour reduction were 64.5%, 58%, magnesium bicarbonate ferric chloride forms ferric
and 41.5 % respectively. In general, decreasing the pH hydroxide, which precipitates as before forming a
from the alkaline levels to near neutral levels has a sweeping floc responsible for colloid removal.
strong positive effect on removal of TSS, COD and Colour.
2FeCl3 + 3 Ca (HCO3)2 ------ 2 Fe (OH)3 + 3CaCl2 + 6CO2

Fig 2: Graph indicates percent removal of TSS, COD and


Colour reduction Vs pH.

EFFECT OF ALUM DOSAGE: Dosage was the most


important parameter that was considered to determine
the optimum condition for the performance of
coagulation and flocculation. Each type of coagulant has
its own characteristic optimum dosage range. Basically,
insufficient dosage or overdosing will result in poor
Fig 4: Chemical Coagulant, Ferric Chloride
performance in flocculation. Therefore, it was crucial to
determine the optimum dosage in order to minimize the
EFFECT OF PH: In this experiments were performed to
dosing cost and obtain the optimum performance in
assess COD, TSS and Colour removal as well as
treatment. (Nasir et.al) In this experiments were
coagulation-flocculation at various pH values. The
performed to assess COD, TSS and Colour removal as
optimum pH obtained was 4 at a constant Ferric
well as coagulation-flocculation at various alum dose(
Chloride dose (mg/L).At a pH 4, the optimum percent
mg/L). The optimum dose obtained was 200mg/L at a
removal for TSS, COD and Colour reduction were53%,
constant pH-6. At a Alum dose 200 mg/L, the optimum
45% and 35% respectively.
percent removal for TSS, COD and Colour reduction
were68%, 61% and 43%respectively.

Fig 3: Graph indicates percent removal of TSS, COD and


Fig 5: Graph indicates percent removal of TSS, COD and
Colour reduction Vs Alum Dose mg/L.
Colour reduction Vs pH.
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NOVATEUR PUBLICATIONS
JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
EFFECT OF FERRIC CHLORIDE DOSAGE: In this JAR TEST RESULT BY USING INDFLOC-441: Indfloc
experiments were performed to assess COD, TSS and 441 is high efficiency anionic polyelectrolyte specially
colour removal as well as coagulation-flocculation at design for solid- liquid separation process. One of the
various Ferric Chloride dose( mg/L). The optimum dose important features of Indfloc - 441 is that it is effective at
obtained was 400mg/L at a constant pH-4. At a dose 400 low dosages. In this experiments were performed to
mg/L, the optimum percent removal for TSS, COD and assess COD, TSS and Colour removal as well as
Colour reduction were 64%, 58% and 41% respectively. coagulation-flocculation at various dose ( mg/L).The
As the concentration of suspended solids in raw optimum dose obtained was 1 mg/lit for an constant pH-
wastewater was considerably high, the destabilizing of 6& Alum dose 200 mg/L. At a dose of 1mg/L, the
colloidal particles occurs due to the adsorption of optimum percent removal for TSS, COD and Colour
strongly charge partially hydrolysed metallic ions. reduction were 65%,62% and 66% respectively.
Continued adsorption will result in charge reversal and
restabilization of the suspension which does occur at
higher coagulant dosages. (Aziz et.al )

Fig 8: Graph indicates percent removal of TSS, COD and


Colour reduction Vs Indfloc-441Dose mg/L.
Fig 6: Graph indicates percent removal of TSS, COD and
Colour reduction Vs Ferric Chloride Dose mg/L. JAR TEST RESULT BY USING BALLAST SAND: In this
experiments were performed to assess COD, TSS and
JAR TEST RESULT BY USING CA-90: In this Colour removal as well as coagulation-flocculation at
experiments were performed to assess COD, TSS and various dose( mg/L). The optimum dose obtained was
Colour removal as well as coagulation-flocculation at 600mg/L at a constant pH-6, Alum dose 200 mg/L &
various dose( mg/L). The optimum dose obtained was Indfloc 441-1 mg/L. At a dose of 600mg/L, the optimum
2mg/L at a constant pH-6 & Alum dose 200 mg/L. At a percent removal for TSS, COD and Colour reduction were
dose2 mg/L, the optimum percent removal for TSS, COD 80%, 65% and 75%respectively.
and Colour reduction were 61%, 56% and 43%
respectively. Alum was coupled with CA-90. Flocculent
doses were increased from 0.5 to 3 mg/L with the fix
amount of alum (200 mg/L). The initial pH of
wastewater was adjusted to pH 6. The removal of TSS,
COD and Colour efficiencies were calculated from the
TSS, COD, and Colour initial concentration in raw waste
water and final concentration in the supernatant. It can
be seen that increasing flocculent doses does not always
improve the removal rates. The use of flocculent lowers
the coagulant doses needed to obtain a satisfactory Fig 9: Graph indicates percent removal of TSS, COD and
reduction in COD. Colour reduction Vs Ballast sand Dose mg/L.

JAR TEST RESULT BY USING RECYCLED BALLAST


SAND: In this experiments were performed to assess
COD, TSS and Colour removal as well as coagulation-
flocculation at various alum dose( mg/L). The optimum
dose obtained was 400 mg/L at a constant pH-6 , Alum
dose 200 mg/L & Indfloc 441-1 mg/L. At a
dose400mg/L, the optimum percent removal for TSS,
Fig 7: Graph indicates percent removal of TSS, COD and COD and Colour reduction were77%, 58% and 71%
Colour reduction Vs CA-90 Dose mg/L. respectively

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JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
REFERENCES:
1) American Public Health Association (APHA), (1995),
“Standard Methods for the Examination of Water and
Wastewater”, Nineteenth Edition Washington D. C.
2) Arceivala, S. J., and Asolekar, S.R. (2007),
“Wastewater Treatment for Pollution Control and
Reuse”, Third Edition, Tata Mcgraw-Hill publishing
company Ltd.
3) Brown, J. (2003), “Wastewater Treatment: The
Fig 10: Graph indicates percent removal of TSS, COD and
Experiences of the Scientific Research Council in
Colour reduction Vs Recycled Ballast sand Dose mg/L.
Jamaica”.
4) Buzzini, A. P., Nolascob, M. A., Springer, A. M., and
CONCLUSION:
Piresa, E. C. (2006), “Evaluation of Aerobic and
1. The experimental study clearly demonstrated that
Anaerobic Treatment of Kraft Pulp Mill Effluent for
the colour, TSS, and COD was removed successfully
Organochlorines Removal”, Water Practice and
by chemical treatment. An attempt has been made in
Technology, 1(3).
the present investigation to treat the recycle based
5) Chuphal, Y., Shah, S., and Takur, I. S. (2007),
paper mill wastewater by Coagulation, Flocculation
“Optimization of Upflow Anaerobic Sludge Blanket
and Ballast Flocculation.
Reactor for Treatment of Pulp and Paper Mill
2. It was observed that alum resulted in percentage
Effluent”, Pollution research, 26(1).
removal of 68% TSS , 61% COD , & 43% Colour
6) CPCB in “Water Quality In India (Status and trends)
reduction at pH-6 for a dosage of 200 mg/L.
1990 – 2001”
3. Ferric chloride resulted in percentage removal of
7) Dangcong, P., and Qiting, J. (2007),“Anaerobic
64% TSS , 58% COD , & 41% Colour reduction at
Digestion of Alkaline Black Liquor Using an Up-Flow
pH-4 for a dosage of 400 mg/L
Anaerobic Sludge Blanket Reactor” Journal of
4. Results obtained for Combination of alum with CA-
Chemical Technology and Biotechnology, 58(1).
90 were 61% TSS , 56% COD , & 43 % Colour
8) Dangcong, P., Xingwen, Z., Qiting, J., Zhang, D., and
reduction for a dosage of 2 mg/L
Liangkui X. (2004), “Effects of the Seed Sludge on the
5. Results obtained for Combination of alum with
Performance of UASB Reactors for Treatment of Toxic
Indfloc-441 were 65% TSS , 62% COD , & 66 %
Wastewater”, Journal of Chemical Technology and
Colour reduction for a dosage of 1 mg/L
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6. Results obtained for Combination of alum +Indfloc-
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441 + Ballast sand were 80 % TSS, 65 % COD , & 75
Wasenius, C.O Paques (1999), “Anaerobic Treatment
% Colour reduction at for a dosage of 600 mg/L
of Recycled Paper Mill Effluent with the Internal
7. Results obtained for Combination of alum +Indfloc-
Circulation Reactor” 6th IAWQ Symposium on Forest
441 + Recycled Ballast sand were 77 % TSS , 58 %
Industry Wastewaters, Tampere, Finland.
COD , & 71 % Colour reduction at a dosage of 400
10) Duggirala, Y. P. (2007), “Biogas Generation from
mg/L.
Bagasse-Based Paper Mills by Anaerobic Digestion”,
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Journal of Chemical Technology and Biotechnology,
dramatically increase the sedimentation rate by
51 (4).
weighing down the floc. Ballast also strengthens the
11) Ilamurugu, K., Dhevagi, P., and Ramasamy, K. (2006),
floc against shearing, allowing faster stirring rates.
“Anaerobic Treatment of Pharmaceutical Wastewater
Typically the ballast can be recover and recycled
by Upflow Anaerobic Sludge Blanket Reactor”, Journal
back in to the waste stream reducing the need to the
of Ecobiology 19 (4).
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12) Kanat, G., and Saral, A. (2008), “Estimation of Biogas
expenses. Further, recycled ballast can reduce the
Production Rate in a Thermophilic UASB Reactor
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13) Manivasakam, N. (1997), “Industrial Effluents: Origin,
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Characteristics, Effects Analysis and Treatment”,
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Shakati Publication.
footprints, reducing capital and operation cost over
14) Mathur, B. V., and Kulkarni, R. M. (1998), “Anaerobic
a conventional unit.
Treatment of Inhibitory Compounds of Agro Based

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JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
Pulp and Paper Mill Effluents - Various Preteatment 27) Trivedy, R.K. (1998), “Advances in Wastewater
Options”, Journal of the Indian Pulp and Paper Treatment Technology”, 1, Global Science
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NOVATEUR PUBLICATIONS
JournalNX- A Multidisciplinary Peer Reviewed Journal
ISSN No: 2581-4230
VOLUME 3, ISSUE 11, Nov. -2017
5) http://agriculture.indiabizclub.com/profile/874180
~miraj+products+pvt.+ltd.~udaipur_india
6) http://water.epa.go/scitech/wastetech/upload/200
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7) http://en.wikipedia.org/wiki/Leather_production_p
rocesses
8) www.gate-
international.org/documents/techbriefs/.../w019e_
2002.pd
9)
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bAid.pdf
10) http :// www. docstoc.com/docs/20666186/AP42-
915-Leather-Tanning
11) http://www.nanotech.wisc.edu/CNT_LABS/MSDS/I
norganic)

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