Me.ListBox1.

ColumnCount = 2
Me.ListBox1.ColumnWidths = "70 pt; 150 pt; 55 pt; 60 pt; 60 pt"
For Each celda In Range("A2:A" & Range("A65000").End(xlUp).Row)
If InStr(valores, celda) = 0 Then
valores = valores & "," & celda.Value
End If
Next
valores = Mid(valores, 2, Len(valores) - 1)
valores = Split(valores, ",")
For x = 0 To UBound(valores)
ComboBox1.AddItem valores(x)
Next
End Sub