MENU PROGRAMA INGENIERÍA DE PROCESOS DESHIDRATACIÓN

AJUSTE DE CURVAS VELOCIDAD DE SECADO

ISOTERMAS G. A. B.

SALIR PROGRAMA
Datos Isotermas

ELIMINAR DATOS

Para comenzar a trabajar Debe eliminar los datos

anteriores presionando el siguiente botón: Eliminar Datos

INGRESAR DATOS

Para Ingresar los Datos con que va a trabajar presione el Ingresar Nº de Datos
siguiente Botón :

Salir de Isotermas
nar Datos

Nº de Datos

Isotermas
Número de Nodos <=10 3 Aw X exp
Nùmero de Vertices 6 1 0.1 3
Criterio de Convergencia 1.00E-06 2 0.2 4.8
Iteraciones 300 3 0.3 6.3
Numero de pares de datos <=20 9 4 0.4 7.6
5 0.5 9.1
6 0.6 10.9
7 0.7 12.9
8 0.8 15.1
Maximo de la Función -0.2067491 9 0.9 17.7
K (Nodo 1) 0.6753928 10
Xm (Nodo 2) 7.5999991 11
C (Nodo 3) 7.8999926 12
13
Valor
Valor de
de las
las Constantes
Constantes para
para Modelo
Modelo de
de GAB
GAB 14
15
16
alfa -0.077618 17
beta 0.098268 18
gamma 0.024661 19
20
Xcalc
Xcalc == Aw
(alfa*Aw^2+beta*Aw+gamma)
(alfa*Aw^2+beta*Aw+gamma) Con
Con Xcalc
Xcalc yy Xexp
Xexp obtenemos
obtenemos el %RMS
%RMS

Aw X exp Xcalc %RMS

1 0.1 3 2.966
2 0.2 4.8 4.853
3 0.3 6.3 6.362
4 0.4 7.6 7.760
5 0.5 9.1 9.193
6 0.6 10.9 10.776
7 0.7 12.9 12.632
8 0.8 15.1 14.926
9 0.9 17.7 17.917
10
11
12
13
14
15
16
17
18
19
20
calc
calc yy Xexp
Xexp obtenemos
obtenemos el
el %RMS
%RMS

1.39
(Xexp-Xcalc)/Xexp
0.011208
-0.011096
-0.009835
-0.021006
-0.010207
0.011364
0.020779
0.011547
-0.012279
((Xexp-Xcalc)/Xexp)^2
0.000126
0.000123
0.000097
0.000441
0.000104
0.000129
0.000432
0.000133
0.000151
CONTENIDO DE HUMEDAD INICIAL DEL ALIMENTO (%) 12
Una vez ingresado todos los
PESO INICIAL DEL ALIMENTO (g) 1 Datos presione el botón
TEMPERATURA (ºC) 20
Nº DE DATOS 5

Datos Nº H.R.(%) Peso Final (g) AW TAU LN(TAU)

1 60 6 0.6 5.818 1.761
2 70 6.8 0.7 6.727 1.906
3 80 7.5 0.8 7.523 2.018
4 90 8.9 0.9 9.114 2.21
5 90 9.3 0.9 9.568 2.258
Una vez ingresado todos los
Datos presione el botón Aceptar

1/LN(AW) LN(1-AW) LN(LN(1/AW)) LN(LN(1/(1-AW))) AW/(1-AW) LN(AW/(1-AW))

-1.958 -0.916 -0.672 -0.087 1.5 0.405
-2.804 -1.204 -1.031 0.186 2.333 0.847
-4.481 -1.609 -1.5 0.476 4 1.386
-9.491 -2.303 -2.25 0.834 9 2.197
-9.491 -2.303 -2.25 0.834 9 2.197
AW/((1-AW)*TAU))
0.258
0.347
0.532
0.987
0.941
MODELOS MODELOS LINEALIZADOS

LN ( 1/ Aw) = B2 * B1 ^X LN ( LN ( 1 / Aw )) = X LN ( B1 ) + B2

Aw = exp ( - B2 / X ^ B1 ) LN ( LN ( 1 / Aw )) = - B1 * LN ( X ) + B2

( 1 - Aw ) = exp ( - [ B2 * X ^ B1 ] ) LN ( LN ( 1 / ( 1 - Aw ))) = LN ( B2 ) + B1 LN ( X )

X = B1 [ Aw / ( 1 - Aw ) ] + B2 X = B1 [ Aw / ( 1 - Aw ) ] + B2

X = [ B1 / LN ( Aw ) ] + B2 X = B1 * 1 / LN ( Aw ) + B2

X = B2 [ Aw / ( 1 - Aw ) ] ^ B1 LN ( X ) = LN ( B2 ) + B1 LN [ Aw / ( 1 - Aw ) ]

X = B2 - B1 * LN ( 1 - Aw ) X = B2 - B1 * LN ( 1 - Aw )

Aw = 1 + Aw ( C - 1 ) Aw = 1 +
( 1 - Aw ) * X Xm * C Xm * C ( 1 - Aw ) * X Xm * C
EALIZADOS

= X LN ( B1 ) + B2

= - B1 * LN ( X ) + B2

Aw ))) = LN ( B2 ) + B1 LN ( X )

) + B1 LN [ Aw / ( 1 - Aw ) ]

Aw ( C - 1 )
Xm * C
CONTENIDO DE HUMEDAD INICIAL DEL ALIMENTO (%) 79.5
PESO INICIAL DEL ALIMENTO (g) 5
TEMPERATURA (ºC) 60
Nº DE DATOS 5

Datos Nº H.R.(%) Peso Final (g) AW TAU LN(TAU)

1 60 6 0.6 4.854 1.58
2 70 6.8 0.70 5.634 1.729
3 80 7.5 0.8 6.317 1.843
4 90 8.9 0.9 7.683 2.039
5 90 9.3 0.9 8.073 2.089
1/LN(AW) LN(1-AW) LN(LN(1/AW)) LN(LN(1/(1-AW))) AW/(1-AW) LN(AW/(1-AW))
-1.958 -0.916 -0.672 -0.087 1.5 0.405
-2.804 -1.204 -1.031 0.186 2.333 0.847
-4.481 -1.609 -1.5 0.476 4 1.386
-9.491 -2.303 -2.25 0.834 9 2.197
-9.491 -2.303 -2.25 0.834 9 2.197
AW/((1-AW)*TAU))
0.309
0.414
0.633
1.171
1.115
 MODELO CONSTANTES

BRADLEY Pendiente = -0.5204522643 LN( B1 ) = -0.5204522643 B1 =

Intercepto = 1.8486892355 B2 = 1.8486892355 B2 =
r= -0.9932732852

HALSEY Pendiente = -3.3291780396 ( - B1 ) = -3.3291780396 B1 =

Intercepto = 4.6383544416 B2 = 4.6383544416 B2 =
r= -0.9939257285

HENDERSON Pendiente = 1.8926059073 B1 = 1.8926059073 B1 =

Intercepto = -3.0640765639 LN ( B2 ) = -3.0640765639 B2 =
r= 0.9938706454

I-CHIRIFE Pendiente = 0.368938005 B1 = 0.368938005 B1 =

Intercepto = 4.6060449033 B2 = 4.6060449033 B2 =
r= 0.982376436

KUHN Pendiente = -0.3676878405 B1 = -0.3676878405 B1 =

Intercepto = 0.5878362369 B2 = 0.5878362369 B2 =
r= -0.9825981075

OSWIN Pendiente = 0.263648044 B1 = 0.263648044 B1 =

Intercepto = 1.485205391 LN ( B2 ) = 1.485205391 B2 =
r= 0.9947945866

SMITH Pendiente = -2.1377245358 ( - B1 ) = -2.1377245358 B1 =

Intercepto = 2.9486131988 B2 = 2.9486131988 B2 =
r= -0.9934326847

B.E.T. Pendiente = 2.9152941176 ( C - 1 ) / Xm * C = 2.9152941176

Intercepto = -1.5455294118 1 / Xm * C = -1.5455294118
r= 0.9583910553
0.5942517284
1.8486892355

3.3291780396
4.6383544416

1.8926059073
0.0466969436

0.368938005
4.6060449033

-0.3676878405
0.5878362369

0.263648044
4.4158723

2.1377245358
2.9486131988
MODELOS PARA OBTENER TAU CALCULADO

BRADLEY HALSEY HENDERSON I-CHIRIFE

KUHN OSWIN SMITH B.E.T.

Salir
I-CHIRIFE

B.E.T.
 ((Te - Tc) / Te)^2

Aw Tau experimental Tcalculado 0

0.66 0.147 5.2395289989 1200.141219156 #DIV/0!
0.68 0.211 5.3827836322 600.7804393102 #DIV/0!
0.7 0.276 5.5329179374 362.7807472273
0.72 0.333 5.6910028055 258.8912702234
0.74 0.376 5.8583377851 212.5963925248
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 Aw Tau experimental
0.6600 0.147
0.6800 0.211
0.7000 0.276
0.7200 0.333
0.7400 0.376
 ((Te -Tc)/Te)^2

Tau calculado 0
3.3125572097 463.7305034031 #DIV/0!
3.5270503008 246.988827685 #DIV/0!
3.7335957279 156.9387762256
3.9146273668 115.6837431549
4.0546895469 95.721740485
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Aw Tau experimental
0.66 0.1470
0.68 0.2110
0.7 0.2760
0.72 0.3330
0.74 0.3760
 ((Te - Tc)/Te)^2

Tau calculado 0
5.2543363091 1207.130555509 #DIV/0!
5.4083373396 606.7320011042 #DIV/0!
5.568091178 367.6516099005
5.7344655727 263.1084267431
5.9085036136 216.5048964083
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Aw
0.66
0.68
0.7
0.72
0.74
 ((Te - Tc)/Te)^2

Tau experimental Tau calculado 0

0.1470 5.3222186777 1239.4321 #DIV/0!
0.2110 5.3900381639 602.4671 #DIV/0!
0.2760 5.4669002483 353.7262
0.3330 5.5547426305 245.8909
0.3760 5.6560992252 197.2007
4.6060449033 #DIV/0!
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Aw Tau experimental
0.66 0.1470
0.68 0.2110
0.7 0.2760
0.72 0.3330
0.74 0.3760
 ((Te-Tc)/Te)^2

Tau calculado 0
1.4727319632 81.3348714956 #DIV/0!
1.541229058 39.7454986777 #DIV/0!
1.6187128006 23.6672661314
1.7071156539 17.0277830104
1.8089641732 14.524292112
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Aw Tau experimental
0.66 0.1470
0.68 0.2110
0.7 0.2760
0.72 0.3330
0.74 0.3760
 ((Te-Tc)/Te)^2

Tau calculado 0
5.2597400952 1209.68630112 #DIV/0!
5.3867156201 601.694305601 #DIV/0!
5.5211921961 361.164161596
5.6644559157 256.332207712
5.8180953841 209.486774061
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Aw Tau experimental
0.66 0.1470
0.68 0.2110
0.7 0.2760
0.72 0.3330
0.74 0.3760
 ((Te-Tc)/Te)^2

Tau calculado 0
5.2548110814 1207.354992964 #DIV/0!
5.3844098229 601.1583117116 #DIV/0!
5.522375403 361.3271223179
5.6698631572 256.8524232242
5.8282855876 210.2720272798
2.9486131988 #DIV/0!
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Aw Tau experimental
0.66 0.1470
0.68 0.2110
0.7 0.2760
0.72 0.3330
0.74 0.3760
 ((Te-Tc)/Te)^2

Tau calculado 0
5.1277270185 1148.02358427 #DIV/0!
4.8641406797 486.325962694 #DIV/0!
4.7121248119 258.338628267
4.6459088673 167.745970274
4.6521879336 129.341495328
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 Ajuste Modelo Bradley Linealizado
2.5
LN ( LN ( 1 / Aw )

1.5

0.5

0
4.500 5.000 5.500 6.000 6.500
Tau 7.000 7.500 8.000 8.500
 Ajuste Modelo Halsey Linealizado
2.5
Ln ( Ln ( 1 / Aw ))

1.5

0.5

0
0.2 0.4 0.6 0.8 1 1.2 1.4
Ln ( Tau )
 Ajuste Modelo Henderson Linealizado
0
0.2 0.4 0.6 0.8 1 1.2 1.4
Ln (Ln (1 / ( 1-Aw ))

-1

-2

-3

-4

-5

-6

-7

-8

-9

-10
Ln ( Tau )
 Ajuste Modelo I-Chirife Linealizado
9.000
( Aw / ( 1- Aw ) )

8.000

7.000

6.000

5.000

4.000

3.000

2.000

1.000

0.000
1 2 3 4 5 6 7 8 9 10
Tau
 Ajuste Modelo Kuhn Linealizado
9.000

8.000

7.000

6.000
Tau

5.000

4.000

3.000

2.000

1.000

0.000
-2.4 -2.2 -2 -1.8 -1.6 -1.4 -1.2 -1 -0.8
1 / Ln ( Aw )
Ln ( Aw / ( 1- Aw ))
Ajuste Modelo Oswin Linealizado

1.4

1.2

0.8

0.6

0.4

0.2

0
-2.4 -2.2 -2 -1.8 -1.6 -1.4 -1.2 -1 -0.8 -0.6 -0.4
Ln ( Tau )
 Ajuste Modelo Smith Linealizado
9.000

8.000

7.000

6.000
Tau

5.000

4.000

3.000

2.000

1.000

0.000
-0.2 0 0.2 0.4 0.6 0.8 1
Ln ( 1 - Aw )
Aw / (( 1 - Aw) * Tau )
Ajuste B.E.T. Linealizado
2.5

1.5

0.5

0
0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95
Aw
PROGRAMA PARA EL AJUSTE DE CURVAS

ELIMINAR DATOS

Para comenzar a trabajar Debe eliminar los datos

anteriores presionando el siguiente botón: Eliminar Datos Anteriores

INGRESAR DATOS

Para ingresar el número de Datos con que va a

trabajar presione el siguiente botón: Ingresar Nº de Datos

Salir de Ajuste de Curvas

Anteriores

e Datos

de Curvas
Una vez ingresado todos
los datos, oprima el botón
ACEPTAR.
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DATOS PARA EL AJUSTE DE CURVAS
TEMPERATURA
Nº de DATOS
Opciones de Ajustes

Gráfico de Curvas Gráfico de Modelos Linealizados

Lineal Geométrica Bradley Caurie

Hiperbólica Michaelis-Menten Halsey Kuhn

Exponencial Logarítmica Henderson Oswin

I-Chirife Smith

Resumen Ajuste de Curvas Aceptar

Resumen Ajuste de Modelos Aceptar Salir

 Caurie

Kuhn

Oswin

Smith

Salir
 Cuadro resumen ajuste de curvas linealizados

Curva Curva Número r

Linealizada Observaciones (Coef.correlación)

Y=a+bX Lineal 0 #VALUE!

1/Y = a + b X Hiperbólica 0 #VALUE!

ln(Y) = ln a + X ln b Exponencial 0 #VALUE!

ln (Y) = ln a + b * ln (X) Geométrica 0 #VALUE!

1/Y = (b/a) *1/ X + 1/a Michaelis-Menten 0 #VALUE!

Y = a + b * ln (X) Logarítmica 0 #VALUE!

de curvas linealizados

b a
(Pendiente) (Intercepto)

#VALUE! #VALUE!

#VALUE! #VALUE!

#VALUE! #VALUE!

#VALUE! #VALUE!

#VALUE! #VALUE!

#VALUE! #VALUE!

Cerrar
 Cuadro resumen ajuste de modelos linealizados
Modelo Modelo Número r
Linealizado Observaciones (Coef.correlación)

Tau = ln(ln(1 / Aw)) / ln(B1) - (B2) / ln(B1) Bradley 0 #VALUE!

ln (Tau) = A + (100/B) * Aw Caurier 0 #VALUE!

ln (Tau) =ln(ln(1 / Aw)) / (B1) - ln(B2) / (B1) Halsey 0 #VALUE!

ln(Tau) = ln(ln(1/(1-Aw))) / (B1) - ln(B2) / (B1) Henderson 0 #VALUE!

Y = B1 * (X / (1 - X)) + B2 I - Chirife 0 #VALUE!

Y = B2 + B1 * (1 / lnX) Kuhn 0 #VALUE!

ln (Y) = ln B2 + B1 * ln (X / (1 - X)) Oswin 0 #VALUE!

Y = B2 - B1 * ln (1 - X) Smith 0 #VALUE!
ste de modelos linealizados
b a
(Pendiente) (Intercepto)

#VALUE! #VALUE!

#VALUE! #VALUE!

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#VALUE! #VALUE!

Cerrar
 Ajuste de Curva Lineal
12

10
Tau

0
0 0.1 0.2 0.3 0.4 Aw
0.5 0.6 0.7 0.8 0.9 1
 Ajuste de Curva Hiperbólica
12

10
1/Tau

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Aw
 Ajuste de Curva Exponencial
12

10
ln(Tau)

0
0 0.1 0.2 0.3 0.4 Aw
0.5 0.6 0.7 0.8 0.9 1
 Ajuste de Curva Geométrica
12

10
ln (Tau)

0
0 2 4 ln6 (Aw) 8 10 12
 Ajuste de Curva Michaelis-Menten
12

10
1/Tau

0
0 2 4 1/Aw
6 8 10 12
 Ajuste Curva Logarítmica
12

10

8
Tau

0
0 2 4
ln 6(Aw) 8 10 12
 Ajuste Modelo Bradley
12

10

8
Tau

0
0 2 4 6 8 10 12
ln(ln (1/Aw))
 Ajuste del Modelo Caurie
12

10
ln (Tau)

0
0 0.1 0.2 0.3 0.4 Aw
0.5 0.6 0.7 0.8 0.9 1
 Ajuste del Modelo Halsey
12

10
ln (Tau)

0
0 2 4 6 8 10 12
ln (ln (1/Aw))
 Ajuste del Modelo Henderson
12

10
ln (Tau)

0
0 2 4
ln (ln 6(1 / (1-Aw))) 8 10 12
 Ajuste del Modelo I - Chirife
12

10

8
Tau

0
0 2 4 Aw/(1
6 - Aw) 8 10 12
 Ajuste del Modelo Kuhn
12

10

8
Tau

0
0 2 4 1 /6 ln(Aw) 8 10 12
 Ajuste del Modelo Oswin
12

10
ln (Tau)

0
0 2 4 ln (Aw / (1
6 - Aw)) 8 10 12
 Ajuste del Modelo Smith
12

10

8
Tau

0
0 2 4 ln (1
6 - Aw) 8 10 12
Datos para la obtención de la Velocidad de Secado

Para comenzar a trabajar Debe eliminar los datos

anteriores presionando el siguiente botón: Eliminar Datos

Para Ingresar los Datos con que va a trabajar

presione este Botón Ingresar Nº de Datos

Salir del Programa

CONTENIDO DE HUMEDAD INICIAL DEL ALIMENTO (%) 78.9 Una vez igresados todos los
Datos presione el botón
PESO INICIAL DEL ALIMENTO (g) 3 Aceptar
TEMPERATURA (ºC) 20
Nº DE DATOS 5

Datos Nº Tiempo (min) Peso Final (g) TAU Tiempo prom Tau prom
1 0,0 3 3.739 0 0
2 10 2.9 3.581 5 3.66
3 20 2.7 3.265 15 3.423
4 30 2.5 2.949 25 3.107
5 40 2.3 2.633 35 2.791
20 1.3165
0 0
0 0
0 0
0 0
0 0
0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
0 0
Una vez igresados todos los
Datos presione el botón
Aceptar Aceptar

(-dTau) d0 (-dTau/d0)
0 0 0
0.158 10 0.0158
0.316 10 0.0316
0.316 10 0.0316
0.316 10 0.0316
2.633 -40 -0.065825
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CONTENIDO DE HUMEDAD INICIAL DEL ALIMENTO (%) 78.9
PESO INICIAL DEL ALIMENTO (g) 3
TEMPERATURA (ºC) 20
Nº DE DATOS 5

Datos Nº Tiempo (min) Peso Final (g) TAU Tiempo prom Tau prom
1 0,0 3 3.739 0 0
2 10 2.9 3.581 5 3.660
3 20 2.7 3.265 15 3.423
4 30 2.5 2.949 25 3.107
5 40 2.3 2.633 35 2.791
#DIV/0! 0 #DIV/0!
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(-dTau) d0 (-dTau/d0)
0 0 0
0.158 10 0.016
0.316 10 0.032
0.316 10 0.032
0.316 10 0.032
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 Curva de Secado
Tau (Kg agua/Kg s.s.)

4.000

3.500

3.000

2.500

2.000

1.500

1.000

0.500

0.000
0,
0 20 40
Tiempo (min)
 Curva de Cinética de Secado
0.035

0.030
(-dTau/d0)

0.025

0.020

0.015

0.010

0.005

0.000
0 15 35 Tiempo prom
 Curva de Cinética de Secado

0.035

0.030
(-dTau/d0)

0.025

0.020

0.015

0.010

0.005

0.000
0 3 1
42 7 9
3. 2 .
Tau promedio