Trabajo PV reveesi ble C Gases ides/es) En un proceso teversibk Par= R tpresion del 925: Para un gos ides! Pv = nRT. “We al pay We = {oar dy 2 -n@T Inve fi Vv v ENTALPIA fu def > = UtPV (func. de ested duzdut pdv tvdp. Pora un sisteus en equilibria mecsnico , ls Primers ley de Is Terradiustuica estoblere de = dg - pdv (se incluye solo Jrbay0 PN, cla = du+ pdv teeupisyando en b> expres] anterior du= dg +Vdp . Si ef procore es P: cle => d= dg : Gpocidad Calorifics- Cvariacien de Tturnde Se Splics Cater) Eo a9 qT De I> primers ley dod -pdv 2: cte du =dg. => & =(4) at/v ae lori}. > Pete: G dus 49. C: Cpr. Clerif 4 p cle > G+/2H TOS p. eo Cp- cv. otihigonde Ddecuadas Se puede [legar >: -¢v = (Dy aye 9) tae (22), (2) r(®) Par, des} (av) =o ara un gos ide (32), =) Cp-cyep(av) =nR. rv r (3%), Neriscion de U bs exp resio nes Si: Ot U (Tw) du “(&),a7 + fs )ev = duz dt +)r(aP) -p )dv Varpcen i ! (Fy } s H=ACTP) aw= (24/7) AT+ (7%)? - > dus Cod ; Pp T+ {VT (aM, Jeli Pais un Gas ideal dus GQdr , dus Cpdt Cp- ve nR 8 Cpr Cum ® PRoceso A DIABATICO (920) Seb primes Tey uz aw - Gs Ides} du= GQdr = w(€,dT . Proceso adiab3tico irreversible Peat” w= -Pext AV Cv aT =- PertTAV = Eponsion adiostics reversible 16a Ide: dw =-pelv haciendo que dw: Cvdt ws Cele, Cydt> -pdv Se puede deuoster = dv Ea Cdr -ner av PM = pave (ford: (nedy om ne (2) Bm AR OQudn Bz -n2 lo Vg 2 qth ‘ on. (x \ haciends c= Cv Jn R nly ach oihhv th Ve, (aye Tl! Ne2.- PRO BLEMAS: Dates T: ete PROCESO QEVERSIBCE N= 0,052 moles Gos: ideal T +260 « Vez £¥a ¢ wi, Solu cron . We. PRIMERA iey, 2 pay (GT, prec. rev., W senat In V2 oe) M W= + 0,062 moles In (' vava Ma we 123 F 27123 d dus dg +dw At: cte | gos Ideal duzo w dg: ae g= - 123 J (i? ley) dw m Cuy Uy = 12,9 ten T, 231° =Ta Pent © ZO mm Hy (! 0,082 dtwxit: B30 J Avo (gos teal ,T ctey + ge dun TO-w? +8aT- Rever sible w = nat re fy, ws -163 J * Gvz0 (62,7 ced . = OU- we - (-169)z+1695) -200 wa llge3, 3d] B+ Ligerete ys 9 ¥so du Tz: 0%€ Pz | ota. cys = 0,0067™% Proceso ISeTeruri ® Pexr= 95 ate (che). dw? Selocon = Peet av Wt ~ 4S atu. (- 0,0067.644¢ we & meles frp? aacate. Ceted. Ts26eok 72+ 285k- Gas : ideal 4d g,au, av? Sewcwn: A pete duzd Pra un gas ides dH= Cpdrt. (observere ze Cpen om) du= nop, dT Se puede DSuutir Pm cte a Us NOL AT | tbbs Ou: % moler w 29,36 £ « (25) twa a due aan (neta: Pim (0% Ssumido ey > z: 298 lees pers teis roxIms > Jo del pacts 260-2: . we - pay (pictey swt -nQ oT wr 3 ual 8,3 5 mole (2s). wee. 620 T D du +w = 2202 S-4£207 qu > is¢2 J > 5 mel 375% 5 NR > g2t4,89 KT Solscion : A pce dug. . 4= fr Py AT é —— Pm te = 35,06 q= n Pu oT. Taz 403 Kk. Tabby aw eed 1G, (Te -k)GS - Gos dest , nz moles Or= 255 p: cle 9 = +229 J © Chim Wm cE Splucion : Ap ce 2 On= GOT (Pm: ote). "Says g/nar Spmz 29,9 Y/ mol. @r Com Cv,m = R + Gye 21,6 S]uelk, 8, C393 X)z 28,9 GF ang) N) = 0,030 mo} ker Proceso : reversible =T22 333K Vy = 5,25 Gu> 5 Voz 6,99 cod Qu= 83,5 z Gos obedece Ecusc. dal Vina ¢d wiqi dH ? Solvcion Bc. det vices) pVat Rr{6 BY New a “Fey ~~ S§ Vi AS ae Ww: > We “ows = hme Inve werp(t 4) n = 33,0 J. H=zorpy ea saRT {47 nB viral pyer ces “QWs aur WerB(y-t teeeaplozonde Gue 4 = aU—w = 83,54- (27eJenp 5. 8. co,7 2 moles MypeVet 18/0 dae? 5 q2 2,35KF T= 3@0% 5 Taz yl k Gas Van der Waals. dw, au,dH? Solucien ? . We -Pex AV o vi che wro- * Ss Wie s OU29F 2,35 KT * = UtPV Bae Sao pay + vdp Nicte = dh= durvap- Sequn Von der Waals. A a (Pde) ( Nm -b) = QT. dp: f dr. ’ dns du ev R ja , bed.zeanied (4 3S dpe pice 5 mug T= 290 & Js - !200 J 94 4auy Cp? ad a a = ~I20e Ks me KS = 253° Fo = 295 K> 9.- ¢ Solve Lextrocecon Fe Cabr + Ap cte SGU 1200 4 cpdr Cp eted & ax tte. AH ~ - {oo . dus si = at eiieod At (295-290) K Bo S)k Tr 2s0 K Ccte> pr jso uu My N= 0,5 rol uy,= 26,0 KI Jrmrd fo. - (ete) _ No. : Gas ideaf co 4,ul,au,4aH? Solucion « OU = ayer ay = 260 K! .o,5 = 13,0 X)-Continvacion prob. 10 - * Bop chew as dis |3,0 Ks + De He usgy Uz H-py Cprete Qu:zdye- pav Ou sdu- p veg ing) aust Vvop (Mp? Mi) Si Wap Vas deal, SS Vs nQr yp Que fay - P (nar) P doz Ou- net Weuwtlss.-» JUS 12 C00 a wes eo aT. (1? ley) W 12000 7 ~ [3000 3 fz - loos J. ty 3 Mem Mos 4 Ys 20 due T= 270K Q:=o (cte) : desl 3 Pat 7 COO Le ot Hey Nn23Mi 5} Gos e 4, Ww) 00,44? Solucion Gxo Cdisbs tres) ewe Peer anv Cpt ete> - Wz -3,19 KS> I W: Wat = du (Asaiends ©: A Apts W/ty=-3'foT 2Qg5 «4 7 mete OT= -33,8 gabe : Sus aut near reaasph3.—> TH s -44s0 ST pe 4. 12.- m= 3 urek T= 200K 5 Ps 20 shu Jee | Te = 250 Ky procs reve Vue 205 TF mol Ke ¢ 1%) 40,0 3 Vey Pe? Solved gz0 (proceso 2e296, + dws Cvdr Wr at (@ ete). reauapls W = Yyiz KS . aqu=w C1 Jey gy so) ut Giz Kd + GH :Urpyv D> Os dus nRdtT reeeuples du= 5367 T * Ma = MRT Ly mt oosz atta! Pa it 210 af. Nis 24,6 dard. c Ng = Uh (¢= a Te ne * a a N2 = 118 du? © Pe nRh No Feeuup 23 Pox pint : . Boney Gas: monoatouca ide Cpz 228 2 5 Pus 3:25 ote. T= Blo kK 5 <0 Proc. tev. Pas Zs0 atm. a V2, yw? Selcih = w= CyaT (Adabste, Cw ek Gos idet Cp-Cyz n2 Qe p-nRz 20,8 S- 4 wd, K Qe i245 3 ' v= N&h ma