cw 18

burb P "GAMMA-PHI c/WILSON)

CONSTANTES DE ANTONIE DEL
COMPUESTOA B C
2-propanol 16.678 3640.2 219.62
agua 16.262 3799.89 226.35

DATOS DEL PROBLEMA

T (C°) 80
T(K) 353.15 compuesto
P(Kpa) 74.4 datos 2-propanol agua
x1 0.5 P sat(Kpa) 92.630 47.382
x2 0.5 ɣi 1.303 1.577
R (CAL/mol K 1.987 A Y B 27 Y 28P (Kpa) 97.705
R(cm³ bar/mo 8314 yi 0.6177 0.382
p1sat (Kpa) 92.6297879 ɸi 0.99816 0.99239
p2 sat (Kpa) 47.382176 P (Kpa) RECALCULADA 98.103
a12 (cal/mol) 437.98 ϩP -0.4
a21 (cal/mol) 1238 yi 0.6163 0.38370
v1 (cm³/mol) 76.92 ɸi 0.9980 0.9923
v2 (cm³/mol) 18.07 P (Kpa) 98.113
Ʌ12 0.12584873 ϩP -0.010
Ʌ12 0.72924089 yi 0.6163148394 0.38366318
ɸ1 1 ɸi 0.9980181779 0.9923
ɸ2 1 p (Kpa) 98.1134
ϩP 0.000
yi 0.6163152878 0.38368471
ɸi 0.9980180876 0.99233395
P (Kpa) 98.1133760207
ϩP -0.000007
yi 0.6163152997 0.3836847
ɸi 0.9980180697 0.99233395
P (Kpa) 98.1133771446
ϩP -0.00000112
 compuestos
Datos 2-propanol agua
ω 0.668 0.345
Tc(K) 508.3 647.1
Zc 0.248 0.229
Vc (cm³/mol) 220 55.9

ij 12 11 22
Tc ij (k) 573.516286 508.3 647.1
Zc ij 0.2385 0.248 0.229
Vc ij (cm³/mol)119.837538 220 55.9
pcij (Kpa) 2.26797951 1.14 5.27
ωij 0.5065 0.668 0.345
Tr 0.6158 0.6948 0.5457

B° -0.8338 -0.6727 -1.0291

B´ -1.1792 -0.6550 -2.0497
B ij -719.0409 -984.9043 -423.8159
ϩ12 -29.3616
 ECUACION GAMMA-PHI
𝑦𝑖∗ɸ𝑖 𝑃=𝑥𝑖∗ɣ𝑖 𝑃𝑖 𝑠𝑎�

Ʌ12=𝑣2/𝑣1 exp(−𝑎12/𝑅𝑇)

Ʌ21=�1/�2 exp(−�21/��)

p=Ʃ(��∗ɣ�∗�1 ���)/ɸ�
yi=(𝑥1∗ɣ𝑖∗𝑝𝑖 𝑠𝑎�)/(ɸ𝑖∗𝑃)