27/4/2016

TERMODINAMICA MOLECULAR - 2015739 – 1

PROGRAMA DE INGENIERÍA QUÍMICA
UNIVERSIDAD NACIONAL DE COLOMBIA

PROFESOR: JAIME AGUILAR ARIAS

JAIME AGUILAR – UNIVERSIDAD NACIONAL DE COLOMBIA 1

DIAGRAMA Pxy
ELV Etanol (1) - Agua (2) a 1 atm
105

100

95
T (°C)

90
x1
85 y1

80

75
0 0.2 0.4 0.6 0.8 1

x1
Kojima K., Ochi K., Nakazawa Y., Int.Chem.Eng., 9(2), p342-347, 1969
JAIME AGUILAR – UNIVERSIDAD NACIONAL DE COLOMBIA 2

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ALGORITMO DE CÁLCULO Tburb

ELV Etanol (1) - Agua (2) a 1 atm INICIO
105

100
Definir P, xi
95
T (°C)

90
x1 T=∑xi*Teb,i
85 y1

80

Calcular Pi°, γi
75
0 0.2 0.4 0.6 0.8 1

x1
F(T)=1-∑xi γi Pi°/P

yi = xi γi Pi°/P
TK+1=TK – F(T)/F´(T)
Imprima T, yi

|F(T)|<ε
FIN
SI NO
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FUNCIONES PROGRAMA
Function Pvap1(T_Pv1 As Double) As Double

Function Pvap2(T_Pv2 As Double) As Double

Function Teb1(P_Teb1 As Double) As Double

Function Teb2(P_Teb2 As Double) As Double

Function GmWl1(xg1 As Double, Tg1 As Double) As Double

Function GmWl2(xg1 As Double, Tg1 As Double) As Double

Function FT(x1FT As Double, TFT As Double, PFT As Double) As Double

F(T)=1-∑xi γi Pi°/P

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FUNCIONES PROGRAMA
Function TBurb(xx1 As Double, Presion As Double) As Double
TempIter = xx1 * Teb1(Presion) + (1 - xx1) * Teb2(Presion)
DeltaT = 0.1
FnT = 1 F(T)=1-∑xi γi Pi°/P
While Abs(FnT) > 0.001
FnT = FT(xx1, TempIter , Presion) ' F(T)
FnTdT = FT(xx1, TempIter + DeltaT, Presion) ' F(T+dT)
FTprima = (FnTdT - FnT) / DeltaT ' F'(T)
TempIter = TempIter - FnT / FTprima ‘ T(k+1)=T(k)-F(T)/F'(T)
Wend
TBurb = TempIter
End Function

JAIME AGUILAR – UNIVERSIDAD NACIONAL DE COLOMBIA 5