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“CALCULOS”

TABLAS DE EXPERIMENTACIÓN
REACTIVO MUESTRA MUESTRA MUESTRA MUESTRA MUESTRA
1 2 3 4 5
SOLUCION 12.5 10 6.25 3.75 1.25
AGUA 12.5 12.5 12.5 12.5 12.5
TOLUENO 0 2.5 6.25 8.75 11.25

Volumen muestra 1 muestra 2 muestra 3 muestra 4 muestra 5


gastado
NaOH
fase 2.6 1.8 1.3 1.2 0.3
acuosa
fase 8.9 8.6 5.1 3.4 0.8
orgánica

CALCULOS
1.- CALCULO DE LAS CONCENTRACIONES EN CADA FASE
𝑉𝑎𝑐𝑢𝑜𝑠𝑎 ∗ 𝐶
[𝐻3 𝑂] =
𝑉𝑎𝑙𝑖𝑐𝑢𝑜𝑡𝑎
(2.6 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]1 = = 0.0078
5𝑚𝑙
(1.8 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]2 = = 0.0054
5𝑚𝑙
(1.3 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]3 = = 0.0039
5𝑚𝑙
(1.2 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]4 = = 0.0036
5𝑚𝑙
(0.3 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]5 = = 0.0009
5𝑚𝑙
𝑉𝑜𝑟𝑔𝑎𝑛𝑖𝑐𝑎 ∗ 𝐶
[𝐻3 𝑂] =
𝑉𝑎𝑙𝑖𝑐𝑢𝑜𝑡𝑎

(8.9 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]1 = = 0.0267
5𝑚𝑙
(8.6 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]2 = = 0.0258
5𝑚𝑙
(5.1 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]3 = = 0.0153
5𝑚𝑙
(3.4 𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]4 = = 0.0102
5𝑚𝑙
(0.8𝑚𝑙)(0.015𝑚)
[𝐻3 𝑂]5 = = 0.0024
5𝑚𝑙
2.- CALCULO DE CW (FASE ACUOSA)

−5
×2
𝐾𝑎 = 6.3 × 10 =
𝐶𝑊 − 𝑋

×2
DESPEJANDO: 𝑀𝑎 = 𝐶𝑊 = 6.3×10−5 +×

0.00782
𝐶𝑊1 = + 0.0078 = 0.9735
6.3 × 10−5
0.00542
𝐶𝑊2 = + 0.0054 = 0.4683
6.3 × 10−5
0.00392
𝐶𝑊3 = + 0.0039 = 0.2453
6.3 × 10−5
0.00362
𝐶𝑊4 = + 0.0036 = 0.2093
6.3 × 10−5
0.00092
𝐶𝑊5 = + 0.0009 = 0.0138
6.3 × 10−5
3.-CALCULO DE α (FASE ACUOSA)
[𝐻3 0]
𝛼=
𝑀𝑎
0.0078
𝛼1 = = 0.008012
0.9735
0.0054
𝛼2 = = 0.01153
0.4683
0.0039
𝛼3 = = 0.01590
0.2453
0.0036
𝛼4 = = 0.01720
0.2093
0.0009
𝛼5 = = 0.06522
0.0138
CALCULO DE LA VARIABLE “X”
𝑋 = 𝐶𝑊 ∗ (1 − 𝛼)
𝑋1 = 0.9735 ∗ (1 − 0.008012) = 0.9657
𝑋2 = 0.4683 ∗ (1 − 0.01153) = 0.4629
𝑋3 = 0.2453 ∗ (1 − 0.01590) = 0.2414
𝑋4 = 0.2093 ∗ (1 − 0.01720) = 0.2057
𝑋5 = 0.0138 ∗ (1 − 0.06522) = 0.0129

CALCULO DE LA VARIABLE “Y”


𝐶𝑇 𝐶𝑇
𝑌1 = =
𝐶𝑊 ∗ (1 − 𝛼) 𝑋
0.0267
𝑌1 = = 0.02765
0.9657
0.0258
𝑌2 = = 0.05574
0.4629
0.0153
𝑌3 = = 0.06338
0.2414
0.0102
𝑌4 = = 0.04959
0.2057
0.0024
𝑌5 = = 0.18605
0.0129

ECUACION: B X
𝐶𝑇
= 𝐾𝑀 + 2𝐾 2 𝑀 ∗ 𝐾𝐷 ∗ 𝐶𝑊 ∗ (1 − 𝛼)
𝐶𝑊 ∗ (1 − 𝛼)
M

B=0.122
M=-0.1203
Y= -0.1203*x + 0.122
Regresión lineal
Y muestra1= -0.1203*0.9657+0.122= 0.005824571
Y muestra2= -0.1203*0.4629+0.122= 0.066318286
Y muestra3= -0.1203*0.2414+0.122= 0.092956143
Y muestra4= -0.1203*0.2057+0.122= 0.097252571
Y muestra1= -0.1203*0.0128+0.122= 0.120453286
Cw vs Ct
0.2

0.18

0.16

y = -0.1203x + 0.122
0.14

0.12
CW

0.1

0.08

0.06

0.04

0.02

0
0 0.2 0.4 0.6 0.8 1 1.2
CT

Cw vs Ct cw vs ct ajustada Linear (Cw vs Ct)


Obtenidos del grafico
KM=b
KM= 0.122
KD= KM/ (2*(KM^2)
KD= -4.041252352
Tabla de resultados

muestra 1 2 3 4 5
ml NaOH fase orgánica 8.9 8.6 5.1 3.4 0.8
CT * 10 ^2 M 2.67 2.58 1.53 1.02 0.24
ml NaOH fase acuosa 2.6 1.8 1.3 1.2 0.3
CW * 10 ^2 M 97.3514286 46.8257143 24.53285714 20.9314286 1.37571429
CT/CW 0.02742641 0.05509793 0.062365341 0.04873055 0.17445483
a 0.00801221 0.01153213 0.015897048 0.01719902 0.06542056
Cw(1-alpha) *10^3 M 965.714286 462.857143 241.4285714 205.714286 12.8571429
CT/Cw(1-alpha) 0.02764793 0.05574074 0.063372781 0.09725257 0.18666667
Kd 0.122 0.122 0.122 0.122 0.122
km -4.04125235 -4.04125235 -4.041252352 -4.04125235 -4.04125235

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