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1. Yukawa potential
Show that the three–dimensional Fourier transform of
1
f (~r) = e−µr
r
is
4π
f (~k) = .
k2 + µ2
Verify that the integrals are finite for µ > 0.
where
1 − x2 1 + x 1
F (x) = ln + .
4x 1 − x 2
3. Koopman’s theorem
a) Evaluate the total energy of a collection of N electrons in jel-
lium, and show that the answer is
X h̄2 k 2 e2
E= l
− kF F kkFl .
2m π
l
Note that the total energy contains also the interaction of the
positive background with itself,
e−µr
Z
1N 2
Ebb = e d~r ,
2V r
which was neglected in deriving the Hartree–Fock equations in
the lectures. Note also that in order to avoid subtracting in-
finities, it is advisable to use the screened Coulomb (Yukawa)
potential e−µr /r and take the limit µ → 0 only after the infini-
ties are cancelled.
b) Compare the result with the sum over l of the single particle
energies El .
4. Hartree–Fock energy for jellium
Show that the Hartree–Fock energy for jellium
X h̄2 k 2 e2
k
E= − kF F
2m π kF
~k,σ
3 e2 kF
3
E =N EF − .
5 4 π