CHEMCAD 6.1.

3 Page 1

Job Name: examen Date: 03/12/2018 Time: 16:00:16

XY data for Hydrogen / Ethylene

K value model: SRK

Mole Fractions
T Deg F P Pa X1 Y1
-154.31270 101325.00000 0.00000 0.00000
-18.87566 101325.00000 0.05000 0.78468 ***
65.39561 101325.00000 0.10000 0.73185 ***
82.17686 101325.00000 0.15000 0.77480 ***
68.94505 101325.00000 0.20000 0.84279 ***
48.20668 101325.00000 0.25000 0.89205 ***
38.67503 101325.00000 0.30000 0.30000 ***
17.90635 101325.00000 0.35000 0.94658 ***
8.37062 101325.00000 0.40000 0.97510 ***
-16.18215 101325.00000 0.45000 0.97530 ***
-37.00572 101325.00000 0.50000 0.98454 ***
-57.85014 101325.00000 0.55000 0.99064 ***
-78.71544 101325.00000 0.60000 0.99454 ***
-103.35539 101325.00000 0.65000 0.99721 ***
-128.02000 101325.00000 0.70000 0.99868 ***
-163.98930 101325.00000 0.75000 0.99970 ***
-207.45709 101325.00000 0.80000 0.99990 ***
-217.22215 101325.00000 0.85000 0.99996 ***
-260.78824 101325.00000 0.90000 1.00000 ***
-315.61420 101325.00000 0.95000 1.00000 ***
-359.67001 101325.00000 1.00000 1.00000

*** Bubble point calculation did not converge.

CHEMCAD 6.1.3 Page 1

Job Name: examen Date: 03/12/2018 Time: 16:47:05

XY data for Hydrogen / Ethylene

NRTL Bij Bji Alpha Aij Aji Cij Cji Dij Dji
0.00 0.00 0.000 0.00 0.00 0.00 0.00 0.00 0.00

Mole Fractions
T Deg F P Pa X1 Y1 Gamma1 Gamma2 Phi1 Phi2
-155.010 101325.000 0.00000 0.00000 1.000 1.000 1.000 1.000
-248.183 101325.000 0.05000 0.98998 1.000 1.000 1.000 1.000
-256.934 101325.000 0.10000 0.99514 1.000 1.000 1.000 1.000
-261.718 101325.000 0.15000 0.99690 1.000 1.000 1.000 1.000
-264.974 101325.000 0.20000 0.99780 1.000 1.000 1.000 1.000
-267.424 101325.000 0.25000 0.99834 1.000 1.000 1.000 1.000
-269.379 101325.000 0.30000 0.99870 1.000 1.000 1.000 1.000
-271.000 101325.000 0.35000 0.99896 1.000 1.000 1.000 1.000
-272.381 101325.000 0.40000 0.99916 1.000 1.000 1.000 1.000
-273.582 101325.000 0.45000 0.99932 1.000 1.000 1.000 1.000
-274.642 101325.000 0.50000 0.99944 1.000 1.000 1.000 1.000
-275.591 101325.000 0.55000 0.99954 1.000 1.000 1.000 1.000
 -276.448 101325.000 0.60000 0.99962 1.000 1.000 1.000 1.000
-277.229 101325.000 0.65000 0.99970 1.000 1.000 1.000 1.000
-277.947 101325.000 0.70000 0.99976 1.000 1.000 1.000 1.000
-278.609 101325.000 0.75000 0.99981 1.000 1.000 1.000 1.000
-279.224 101325.000 0.80000 0.99986 1.000 1.000 1.000 1.000
-279.798 101325.000 0.85000 0.99990 1.000 1.000 1.000 1.000
-280.336 101325.000 0.90000 0.99994 1.000 1.000 1.000 1.000
-280.841 101325.000 0.95000 0.99997 1.000 1.000 1.000 1.000
-422.971 101325.000 1.00000 1.00000 1.000 1.000 1.000 1.000

CHEMCAD 6.1.3 Page 1

Job Name: examen Date: 03/12/2018 Time: 16:04:48

Computed Binodal Curve in Mole Percent:

[1] = Hydrogen
[2] = Ethylene
[3] = Ethane

Left Phase Right Phase

[1] [2] [3] [1] [2] [3]
The calculated concentrations on the base line do not form two
liquid phases.
Try another estimation at base line concentrations y1 and y3,
or change the order of the components in the previous screen.

Please make sure the 1st and 3rd components form two liquid phases.

CHEMCAD 6.1.3 Page 1

Job Name: examen Date: 03/12/2018 Time: 16:10:31

Stream No. 1
Stream Name
Temp F 77.0000*
Pres Pa 101325.0000*
Enth MMBtu/h 1.8178E-007
Vapor mole fraction 1.0000
Total lbmol/h 1.0000
Total lb/h 2.0158
Total std L ft3/hr 0.4613
Total std V scfh 379.48
Flowrates in lb/h
Hydrogen 2.0158
Ethylene 0.0000
Ethane 0.0000

CHEMCAD 6.1.3 Page 1

Job Name: examen Date: 03/12/2018 Time: 16:36:16

FLOWSHEET SUMMARY

Equipment Label Stream Numbers

 1 KREA 1 -2

Stream Connections

Stream Equipment
From To
1 1
2 1

Calculation mode : Sequential

Flash algorithm : Normal

Equipment Calculation Sequence

1

No recycle loops in the flowsheet.

CHEMCAD 6.1.3 Page 2

Job Name: examen Date: 03/12/2018 Time: 16:36:16

Overall Mass Balance lbmol/h lb/h

Input Output Input Output
Hydrogen 1.000 1.000 2.016 2.016
Ethylene 0.000 0.000 0.000 0.000
Ethane 0.000 0.000 0.000 0.000

Total 1.000 1.000 2.016 2.016

CHEMCAD 6.1.3 Page 3

Job Name: examen Date: 03/12/2018 Time: 16:36:16

COMPONENTS
ID # Name Formula
1 1 Hydrogen H2
2 22 Ethylene C2H4
3 3 Ethane C2H6

THERMODYNAMICS

K-value model : NRTL

No correction for vapor fugacity
Enthalpy model : SRK
Liquid density : Library

Std vapor rate reference temperature is 60 F.

Atmospheric pressure is 101324.9793 Pa.

NRTL Parameters: Tij = Aij + Bij/T + Cij * Ln(T) + Dij * T (T Deg K)

I J Bij Bji Alpha Aij Aji Cij Cji Dij Dji

Warning : BIP matrix is less than 50 % full.

CHEMCAD 6.1.3 Page 4

Job Name: examen Date: 03/12/2018 Time: 16:36:17

EQUIPMENT SUMMARIES

Kinetic Reactor Summary

Equip. No. 1
Name
Reactor type 1
Reaction phase 1
Thermal mode 1
Pressure In Pa 101325.0000
Pressure Drop Pa 101325.0000
Tout F 77.0000
Q MMBtu/h -1.8218e-007
No. of Reactions 1

Reaction Stoichiometrics and Parameters for unit no. 1

Reaction 1
RateConst = 1.0000e+000 Act.E = 0.0000e+000 Hrxn = 0.0000e+000
Comp Stoich. Exp.factor AdsorbFac. AdsorbE AdsorbExp.
1 0.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000
2 0.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000
3 0.00e+000 0.0000e+000 0.0000e+000 0.0000e+000 0.0000e+000

CHEMCAD 6.1.3 Page 5

Job Name: examen Date: 03/12/2018 Time: 16:36:17

STREAM PROPERTIES

Stream No. 1 2
Name
- - Overall - -
Molar flow lbmol/h 1.0000 1.0000
Mass flow lb/h 2.0158 2.0158
Temp F 77.0000 77.0000
Pres Pa 101325.0000 0.0000
Vapor mole fraction 1.000 1.000
Enth MMBtu/h 1.8178E-007 -4.0489E-010
Tc F -399.7840 -399.7840
Pc Pa 1295946.5003 1295946.5003
Std. sp gr. wtr = 1 0.070 0.070
Std. sp gr. air = 1 0.070 0.070
Degree API 1889.9286 1889.9286
Average mol wt 2.0158 2.0158
Actual dens lb/ft3 0.0051 0.0000
Actual vol ft3/hr 392.0453 1.#INF
Std liq ft3/hr 0.4613 0.4613
Std vap 60F scfh 379.4786 379.4786
- - Vapor only - -
Molar flow lbmol/h 1.0000 1.0000
Mass flow lb/h 2.0158 2.0158
Average mol wt 2.0158 2.0158
Actual dens lb/ft3 0.0051
Actual vol ft3/hr 392.0453 1.#INF
Std liq ft3/hr 0.4613 0.4613
Std vap 60F scfh 379.4786 379.4786
Cp Btu/lbmol-F 6.8748 6.8733
Z factor 1.0005 1.0000
Visc cP 0.008865 0.008865
Th cond Btu/hr-ft-F 0.0993 0.0993

CHEMCAD 6.1.3 Page 6

Job Name: examen Date: 03/12/2018 Time: 16:36:17

FLOW SUMMARIES

Stream No. 1 2
Stream Name
Temp F 77.0000 77.0000
Pres Pa 101325.0000 0.0000
Enth MMBtu/h 1.8178E-007 -4.0489E-010
Vapor mole fraction 1.0000 1.0000
Total lbmol/h 1.0000 1.0000
Flowrates in lbmol/h
Hydrogen 1.0000 1.0000
Ethylene 0.0000 0.0000
Ethane 0.0000 0.0000