Documentos de Académico
Documentos de Profesional
Documentos de Cultura
(Chemistry)
Coursebook 2
Suggested answers
Chapter Exercise 3
Class Practice 6
Chapter Exercise 9
Class Practice 12
Chapter Exercise 13
Class Practice 15
Chapter Exercise 16
Class Practice 18
Chapter Exercise 21
Class Practice 26
Chapter Exercise 30
Part Exercise 36
Class Practice 39
Chapter Exercise 40
Class Practice 41
Chapter Exercise 42
Chapter Exercise 46
Class Practice 48
Chapter Exercise 49
Class Practice 51
Chapter Exercise 53
Part Exercise 55
Class Practice
A14.1
1. Zinc granules sink to the bottom.
2. Zinc granules dissolve to give a colourless solution.
3. Effervescence occurs./Colourless gas bubbles evolve.
4. The test tube becomes warm as heat is given out.
5. Hissing sound is heard.
A14.2
1. (a) Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)
(b) ZnO(s) + H2SO4(aq) ZnSO4(aq) + H2O(l)
(c) Fe(OH)2(s) + 2HCl(aq) FeCl2(aq) + 2H2O(l)
(d) CuCO3(s) + H2SO4(aq) CuSO4(aq) + CO2(g) + H2O(l)
(e) Ca(HCO3)2(s) + 2HCl(aq) CaCl2(aq) + 2CO2(g) + 2H2O(l)
2. (a) Magnesium dissolves./Effervescence occurs. (Colourless gas bubbles
evolve.)/The solution becomes warm./The resultant solution is colourless.
(b) Zinc oxide dissolves./The resultant solution is colourless.
(c) Iron(II) hydroxide dissolves./The resultant solution is green.
(d) Copper(II) carbonate dissolves./Effervescence occurs. (Colourless gas
bubbles evolve.)/The resultant solution is blue.
(e) Calcium hydrogencarbonate dissolves. /Effervescence occurs. (Colourless
gas bubbles evolve.)/The resultant solution is colourless.
A14.3
(a) Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)
Mg(s) + 2H+(aq) Mg2+(aq) + H2(g)
(b) ZnO(s) + H2SO4(aq) ZnSO4(aq) + H2O(l)
ZnO(s) + 2H+(aq) Zn2+(aq) + H2O(l)
(c) 2KHCO3(aq) + H2SO4(aq) K2SO4(aq) + 2CO2(g) + 2H2O(l)
HCO3(aq) + H+(aq) CO2(g) + H2O(l)
A14.4
1. Magnesium reacts with the hydrogen ions (from ascorbic acid) to give hydrogen
gas.
Mg(s) + 2H+(aq) Mg2+(aq) + H2(g)
2. (a) There is no colour change to the litmus paper.
When there is no water, liquid ethanoic acid (pure) cannot ionize to give H +
(aq) and thus cannot exhibit acidic properties.
(b) The blue litmus paper turns red.
In the presence of water, ethanoic acid ionizes to give H+(aq) and thus can
exhibit acidic properties.
3. Fizzy drink tablets or powder should be stored in a cool and dry place.
A14.6
(a) 2KOH(aq) + CO2(g) K2CO3(aq) + H2O(l)
(b) (NH4)2SO4(aq) + Ca(OH)2(s) CaSO4(s) + 2NH3(g) + 2H2O(l)
A14.7
Magnesium hydroxide, aluminium hydroxide, zinc hydroxide and lead(II) hydroxide
A14.8
1. (a) (i) Potassium hydroxide
(ii) OH(aq) + H+(aq) H2O(l)
(b) (i) Magnesium oxide, zinc hydroxide and copper(II) oxide
(ii) MgO(s) + 2H+(aq) Mg2+(aq) + H2O(l)
Zn(OH)2(s) + 2H+(aq) Zn2+(aq) + 2H2O(l)
CuO(s) + 2H+(aq) Cu2+(aq) + H2O(l)
2. (a) (i) Pb(NO3)2(aq) + Ca(OH)2(aq) Pb(OH)2(s) + Ca(NO3)2(aq)
(ii) Pb2+(aq) + 2OH(aq) Pb(OH)2(s)
(b) (i) CuSO4(aq) + 2KOH(aq) Cu(OH)2(s) + K2SO4(aq)
(ii) Cu2+(aq) + 2OH(aq) Cu(OH)2(s)
Chapter Exercise
35. (a) Monobasic acid is the acid that gives one hydrogen ion per molecule in
aqueous solution. Dibasic acid is the acid that gives two hydrogen ions per
molecule in aqueous solution.
(b) (i) 2HA(aq) + Zn(s) ZnA2(aq) + H2(g)
(ii) H2B(aq) + Zn(s) ZnB(aq) + H2(g)
(iii) 2HA(aq) + CuO(s) CuA2(aq) + H2O(l)
(iv) H2B(aq) + CaCO3(s) CaB(aq) + CO2(g) + H2O(l)
(v) HA(aq) + NaHCO3(aq) NaA(aq) + CO2(g) + H2O(l)
37. (a) Stir solid calcium hydroxide with water for a long time, then filter the
suspension to get the clear filtrate.
(b) Hydroxide ion
(c) 2NH4NO3(aq) + Ca(OH)2(aq) Ca(NO3)2(aq) + 2NH3(g) + 2H2O(l)
(d) (i) A white precipitate is formed.
Ca2+(aq) + CO32(aq) CaCO3(s)
(ii) A pale blue precipitate is formed.
Cu2+(aq) + 2OH(aq) Cu(OH)2(s)
40. Concentrated hydrochloric acid, nitric acid and sulphuric acid are three
common concentrated acids found in the school laboratory. They would
‘eat away’ other substances such as metals, clothes, paper and the skin.
Concentrated hydrochloric acid is highly corrosive because of its high
concentration of hydrogen ions.
The corrosive nature of concentrated nitric acid is mainly due to its
oxidizing property.
Concentrated sulphuric acid is also highly corrosive because of its
dehydrating and oxidizing properties. It is even more corrosive than
concentrated hydrochloric acid and nitric acid. It quickly dehydrates the
skin, causing severe burns.
Concentrated sodium hydroxide and potassium hydroxide solutions are
common concentrated alkalis found in the school laboratory. They are very
corrosive especially when they are hot.
They attack the skin readily and stain it yellow or even black.
Class Practice
A15.1
(a) No. of moles of K2SO4 = 0.15 mol
0.15 mol
Molarity of the solution = 500 dm 3 = 0.30 mol dm3 (or M)
1000
(b) Molar mass of K2SO4 = 39.1 2 + 32.1 + 16.0 4 g mol1 = 174.3 g mol1
Concentration of the solution = 0.30 mol dm3 174.3 g mol1 = 52.3 g dm3
A15.2
10 g
(a) (i) Concentration in g dm3 = = 20 g dm3
0.5 dm3
(ii) Molar mass of KOH = 39.1 + 16.0 + 1.0 g mol1 = 56.1 g mol1
10 g
No. of moles of KOH = = 0.178 mol
56.1 g mol1
0.178 mol
Molarity of the solution (mol dm3) = = 0.356 mol dm3 (or M)
0.5 dm 3
1000
(b) (i) Volume of the solution in dm3 = dm3 = 1.0 dm3
1000
10 g
Concentration in g dm3 = 3 = 10 g dm
3
1.0 dm
(ii) Molar mass of KOH = 39.1 + 16.0 + 1.0 g mol1 = 56.1 g mol1
10 g
No. of moles of KOH = =0.178mol
56.1 g mol1
0.178 mol
Molarity of the solution (mol dm3) = =0.178 mol dm3 (or M)
1.0 dm 3
250
(c) (i) Volume of the solution in dm3 = dm3 = 0.25 dm3
1000
3g
Concentration in g dm3 = = 12 g dm3
0.25 dm 3
(ii) Molar mass of NaNO3 = 23.0 + 14.0 + 16.0 3 g mol1 = 85.0 g mol1
3g
No. of moles of NaNO3 = 85.0 g mol 1 = 0.0353 mol
0.0353 mol
Molarity of the solution (mol dm3) = = 0.141 mol dm3 (or M)
0.25 dm 3
5.3 g
(d) (i) Concentration in g dm3 = = 2.65 g dm3
2 dm3
(ii) Molar mass of Na2CO3 = 23.0 2 + 12.0 + 16.0 3 g mol1 = 106 g mol1
5.3 g
No. of moles of Na2CO3 = 106 g mol 1 = 0.0500 mol
0.0500 mol
Molarity of the solution (mol dm3) = = 0.0250 mol dm3 (or
2 dm 3
M)
A15.3
50.0
No. of moles of Na2SO4 = 0.40 mol dm3 dm3 = 0.0200 mol
1000
A15.4
0.80 mol
Volume of NaOH solution = = 1.6 dm3
0.50 mol dm 3
A15.5
(a) No. of moles of Na2SO4 in 500.0 cm3 of solution
500.0
= 0.50 mol dm3 dm3 = 0.250 mol
1000
Mass of Na2SO4 = 0.250 mol (23.0 2 + 32.1 + 16.0 4) g mol1 = 35.5 g
(b) No. of moles of Na2CO3 in 0.25 dm3 of solution
= 0.15 mol dm3 0.25 dm3 = 0.0375 mol
Mass of Na2CO3 = 0.0375 mol (23.0 2 + 12.0 + 16.0 3) g mol1 = 3.98 g
A15.6
1. 1 mole of Al2(SO4)3 contains 2 moles of Al3+ ions and 3 moles of SO42 ions.
molarity of Al3+ ions = 0.50 M 2 = 1.0 M (or 1.0 mol dm3)
Molarity of SO42 ions = 0.50 M 3 = 1.5 M (or 1.5 mol dm3)
25.0
2. No. of moles of K2CO3 = 0.20 mol dm3 dm3 = 0.0050 mol
1000
1 mole of K2CO3 contains 2 moles of K+ ions and 1 mole of CO32 ions.
number of moles of K+ ions = 0.0050 mol 2 =0.010 mol
Number of moles of CO32 ions = 0.0050 mol
A15.7
1. (MV)before dilution = (MV)after dilution
25.0 250.0
0.1 =M
1000 1000
M = 0.01
Molar concentration of diluted NaOH(aq) = 0.01 M
Chapter Exercise
0.35 mol
26. (a) Molarity of K2CO3 = 250.0 dm 3 = 1.40 M
1000
(b) Molar mass of K2CO3 = 39.1 2 + 12.0 + 16.0 3 g mol1= 138.2 g mol1
Concentration of K2CO3 in g dm3 = 1.40 mol dm3 138.2 g mol1
= 193 g dm3
125.0
28. (a) No. of moles of Mg(NO3)2 present = 1.5 mol dm3 dm3
1000
= 0.1875 mol
29. Molar mass of NaOH = 23.0 + 16.0 + 1.0 g mol1 = 40.0 g mol1
4g
No. of moles of NaOH used = 40.0 g mol 1 = 0.100 mol
0.100 mol 3 3
Volume of solution prepared = 3 = 0.833 dm (or 833 cm )
0.12 mol dm
mol
0.0143 mol
(b) Molarity of oxalic acid = 25.0 dm 3 = 0.572 M
1000
(c) (MV)before dilution = (MV)after dilution
25.0 250.0
0.572 =M
1000 1000
M = 0.0572
Molarity of the diluted oxalic acid = 0.0572 M
35.
Molar Molarity
Formula of Mass of Volume of Concentration of
mass
solute solute (g) solution solution cation anion solution (in g dm3)
(g mol1)
(a) NaCl 58.5 117 2.00 dm3 1.00 M 1.00 M 1.00 M 58.5
(b) AgNO3 170 17.0 1.00 dm3 0.100 M 0.100 M 0.100 M 17.0
(c) Na2CO3 106 2.65 500 cm3 0.050 M 0.100 M 0.050 M 5.30
(d) MgCl2 95.3 29.4 1.50 dm3 0.206 M 0.206 M 0.412 M 19.6
Class Practice
A16.1
(a) pH = log [H+(aq)] = log (1.000) = 0
(b) pH = log [H+(aq)] = log (0.100) = 1
(c) pH = log [H+(aq)] = log (0.010) = 2
(d) pH = log [H+(aq)] = log (0.001) = 3
A16.2
1. A: weakly acidic
B: strongly acidic
C: weakly alkaline
D: neutral
2. (a) The pH of the solution would increase. Magnesium reacts with the
hydrogen ions in aqueous solution to give hydrogen gas.
Mg(s) + 2H+(aq) Mg2+(aq) + H2(g)
When H+(aq) ions are removed, [H+(aq)] decreases and the pH of the
solution increases.
(b) The pH of the solution would decrease. Hydrogen chloride gas dissolves in
water and ionizes completely to give H+(aq) ions. When H+(aq) ions are
formed, [H+(aq)] increases and the pH of the solution decreases.
A16.3
B: Incorrect conclusion. When the litmus is blue, the pH of solution must be greater
than 8 which is alkaline.
C: Incorrect conclusion. Phenolphthalein is colourless when the pH of the solution
is below 8.3. This solution can be acidic, neutral or weakly alkaline.
Chapter Exercise
1. (a) higher
(b) equal
(c) lower
2. H+(aq), pH, pH
3. [H+(aq)]
4. higher, [H+(aq)]
5. colour, ethyl orange, itmus, henolphthalein
6. Universal, Universal, pH
7. pH meter
8. B
9. A
10. C
11. A
12. A
13. A
14. A
15. D
16. B
17. A
18. C
19. A
20. A
21. C
22. B
23. A
Class Practice
A17.1
(a) OH(aq)/hydrated hydroxide ion
(b) NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH(aq)
(c) NaOH(aq) is a stronger alkali than NH3(aq). (Being a stronger alkali, NaOH(aq)
can dissociate to a greater extent to give a high concentration of mobile ions (Na +
(aq) and OH(aq)) in aqueous solution. This explains the higher electrical
conductivity of 0.1 M NaOH(aq).)
(d) As NaOH(aq) is a stronger alkali than NH3(aq), 0.1 M NaOH(aq) is more alkaline
than 0.1 M NH3(aq). Thus, the former has a higher pH.
A17.2
(a) Sulphuric acid molecules
(b) Water molecules, hydrogen ions, nitrate ions, hydroxide ions
(c) Water molecules, citric acid molecules, hydrogen ions, citrate ions, hydroxide
ions
(d) Water molecules, ammonia molecules, ammonium ions, hydroxide ions,
hydrogen ions
A17.3
Put equal volumes (about 80.0 cm3) of 0.1 M HCl(aq) and 0.1 M CH3COOH(aq) into
two 100 cm3 beakers separately. Use the electronic balance to weigh equal masses
(about 0.4 g) of lumps of calcium carbonate and put them into the two acids. Observe
and compare the rates of evolution of gas bubbles from the two reaction mixtures.
The acid that has a higher rate of evolution of gas should be the stronger acid ―
HCl(aq) in this case. It can be explained that the stronger acid can ionize more
completely to give a higher concentration of hydrogen ions and its reaction with
calcium carbonate will be faster.
A17.4
1. (a) concentrated/weak
(b) dilute/weak
(c) dilute/strong
(d) concentrated/strong
2. (a) H2SO4(aq) + Na2CO3(aq) Na2SO4(aq) + CO2(g) + H2O(l)
2H+(aq) + CO32(aq) CO2(g) + H2O(l)
(b) CH3COOH(aq) + KHCO3(aq) CH3COOK(aq) + CO2(g) + H2O(l)
CH3COOH(aq) + HCO3(aq) CH3COO(aq) + CO2(g) + H2O(l)
or H+(aq) + HCO3(aq) CO2(g) + H2O(l)
A17.5
(a) The statement is wrong. Hydrochloric acid is a strong acid which can ionize in
water completely. It has such a high pH (5) because it is only a dilute solution. It
should be noted that pH is a measure of [H+(aq)] but not a measure of strength of
acid or alkali.
(b) The statement is wrong. Ethanoic acid is only a weak acid whatever its
concentration is.
Chapter Exercise
13. In the presence of water, NH 3(aq) reacts with water to give OH (aq) ions which
make the solution alkaline.
NH3(g) + H2O(l) ⇌ NH4+(aq) + OH(aq)
14. (a) Ethanoic acid is a weak acid while hydrochloric acid is a strong acid.
(b) A strong acid is one which completely/highly ionizes in water.
A weak acid is one which only slightly/incompletely/partially ionizes in
water.
(c) Since hydrochloric acid is a stronger acid than ethanoic acid, the former
ionizes more completely than the latter. For the same molar concentration of
the two acids, hydrochloric acid has a higher molar concentration of
hydrogen ions. Thus, it has a lower pH.
(d) By using pH meter
(e) 1. Put a known volume of 1.1 M hydrochloric acid into the container and
record the brightness of the light bulb.
2. Repeat step 1 using the same volume of 1.1 M ethanoic acid.
3. Compare the brightness of the light bulb in steps 1 and 2.
4. The brightness of the light bulb indicates the strength of the acid. The
brighter the light bulb, the stronger the acid is.
16. (a) HCl(aq) is a strong acid. 0.1 M HCl will ionize completely to give 0.1 M
[H+(aq)].
(b) pH = log [H+(aq)] = log (0.1) = 1
18. When a piece of blue litmus paper is dipped in some solid citric acid, there
is no colour change of the litmus paper. When some solid citric acid is
dissolved in some deionized water, the aqueous solution turns the blue
litmus paper red.
When a magnesium ribbon is put in some solid citric acid, there is no gas
formed. When a magnesium ribbon is put into an aqueous solution of citric
acid, colourless gas bubbles (H2(g)) are evolved.
When sodium carbonate powder is mixed with solid citric acid, there is no
sign of gas formed. When some sodium carbonate powder is dissolved in
aqueous solution of citric acid, colourless gas bubbles (CO2(g)) are evolved.
Class Practice
A18.1
(a) 2NaOH(aq) + H2SO4(aq) Na2SO4(aq) + 2H2O(l)
OH(aq) + H+(aq) H2O(l)
(b) CH3COOH(aq) + KOH(aq) CH3COOK(aq) + H2O(l)
CH3COOH(aq) + OH(aq) CH3COO(aq) + H2O(l)
or H+(aq) + OH(aq) H2O(l)
(c) Fe2O3(s) + 6HCl(aq) 2FeCl3(aq) + 3H2O(l)
Fe2O3(s) + 6H+(aq) 2Fe3+(aq) + 3H2O(l)
A18.2
(a) 20 cm3
(b) (i) Alkaline
(ii) For equal concentrations of NaOH(aq) and HCl(aq), equal volumes would
neutralize each other. As there is 30 cm 3 alkali added, it is in excess. Thus,
the resultant solution is alkaline.
(c) Neutralization is an exothermic reaction. No more heat is given out when the
neutralization is complete. Addition of excess alkali will cool down the mixture.
Thus, the temperature drops.
(d) The temperature change will be more or less the same as the change when 20.0
cm3 of 2 M HCl is used. Although the volumes of the two solutions are doubled,
the numbers of moles of H+(aq) and OH(aq) ions reacting are also doubled.
Twice as much heat is given out, but this is used to heat up twice the volume of
the solution. For this reason, both experiments have the same rise in temperature.
A18.3
1. (a) Soluble
(b) Insoluble
(c) Soluble
(d) Soluble
(e) Insoluble
(f) Insoluble
(g) Soluble
(h) Soluble
2. (a) NaNO3
(b) KNO3
(c) CuSO4
(d) PbSO4/PbCl2
(e) MgCO3
(f) AgCl
(g) BaSO4
A18.5
(a) Yes. HNO3(aq) and NaOH(aq)
(b) Yes. HCl(aq) and NH3(aq)
(c) No. Mg(OH)2 is insoluble in water, so no standard solution can be prepared for
titration.
(d) No. Pb(OH)2 is insoluble in water, so no standard solution can be prepared for
titration.
A18.6
1. (a) (i) AgNO3(aq) + NaBr(aq) AgBr(s) + NaNO3(aq)
(ii) Mg(NO3)2(aq) + Na2CO3(aq) MgCO3(s) + 2NaNO3(aq)
(b) (i) Ag+(aq) + Br(aq) AgBr(s)
(ii) Mg2+(aq) + CO32(aq) MgCO3(s)
2. (a) Impracticable. All salts are soluble. They cannot be separated by
crystallization.
(b) Practicable.
(c) Impracticable. PbSO4 is insoluble. Pb2+ ions in the solid cannot combine
with the Cl ions in the aqueous solution.
A18.7
1. (a) Copper(II) chloride, hydrochloric acid
(b) Iron(III) sulphate, sulphuric acid
(c) Zinc nitrate, nitric acid
2. (a) (CH3COO)2Ca
(b) Pb(NO3)2
(c) (NH4)2SO4
© Aristo Educational Press Ltd. 2009 19
HKDSE CHEMISTRY A Modern View (Chemistry) Coursebook 2
A18.8
1. (a) CaCO3(s) + 2H+(aq) Ca2+(aq) + CO2(g) + H2O(l)
(b) Ca(OH)2(s) + 2H+(aq) Ca2+(aq) + 2H2O(l)
2. Sodium hydroxide is corrosive.
A18.9
(a) (i) Sodium hydrogencarbonate, magnesium hydroxide and aluminium
hydroxide
(ii) NaHCO3(s) + HCl(aq) NaCl(aq) + CO2(g) + H2O(l)
Mg(OH)2(s) + 2HCl(aq) MgCl2(aq) + 2H2O(l)
Al(OH)3(s) + 3HCl(aq) AlCl3(aq) + 3H2O(l)
(b) Calcium oxide: it reacts with acid and water producing a lot of heat which causes
chemical burns.
Sodium hydroxide: it is irritating and corrosive, so it will cause serious burns in
the mouth and oesophagus.
Ammonia: it is a toxic gas with an irritating smell.
A18.10
(a) Na2CO3 + H2SO4 Na2SO4 + CO2 + H2O
(b) 2NH3 + H2SO4 (NH4)2SO4
Chapter Exercise
1. hydrogen, H+, hydroxide, OH, oxide, O2, water
2. given out, liberated, exothermic
3. soluble, insoluble
4. (a) metal, base, carbonate
(a) (i) metal, hydrogen
(a) (ii) base, water
(a) (iii) carbonate, carbon dioxide, water, filtration, crystallization
(b) alkali, carbonate, alkali, water, crystallization
5. precipitation, precipitate
6. ionizable, metallic, ammonium
7. (a) pH
(b) acid
(c) waste
(d) fertilizers
8. C
9. B
10. C
11. A
12. C
13. D
14. C
15. A
16. C
17. C
18. D
19. D
20. D
21. A
22. B
23. B
24. B
25. D
26. A
27. C
28. A
29. B
30. D
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(b) Temperature rises because the reaction between an acid and an alkali is
exothermic.
(c) When all the acid has just been reacted completely, no more neutralization
occurs. This means that no more heat is given out. Thus, the rise in
temperature stops and a maximum point is established.
(d) As neutralization has completed, no more heat is given out. Addition of
excess alkali will cool down the mixture. Thus, the temperature drops.
(e) H+(aq) + OH(aq) H2O(l)
(f) (i) 40.00 cm3
(ii) Same/more or less the same. Although the amount of heat released is
doubled, the volume of the solution to be heated is also doubled.
filtrate (Zn(NO3)2(aq))
100.0
(f) No. of moles of HNO3 used = 1.0 mol = 0.100
1000
mol
0.100
No. of moles of Zn(NO3)2 produced = mol = 0.0500 mol
2
Formula mass of Zn(NO3)2
= 65.4 + (14.0 + 16.0 3) 2 g mol1 = 189.4 g mol1
Theoretical mass of Zn(NO3)2 = 0.0500 mol 189.4 g mol1 = 9.47 g
HCO3
39.
Salt Parent acid Parent base/alkali
Ca(NO3)2 HNO3 CaO/Ca(OH)2
NH4Cl HCl NH3
Fe2(SO4)3 H2SO4 Fe2O3/Fe(OH)3
CH3COOK CH3COOH KOH
41. (a) Most plants cannot grow well in soils which are too acidic. To decrease the
acidity of the soils, farmers often add slaked lime to neutralize acids in soil.
Ca(OH)2(s) + 2H+(aq) Ca2+(aq) + 2H2O(l)
(b) ‘Milk of Magnesia’ neutralizes the excess acid in the stomach which causes
stomach pain.
Mg(OH)2(s) + 2H+(aq) Mg2+(aq) + 2H2O(l)
43. Use a pipette to transfer 25.0 cm3 of dilute nitric acid to a clean conical
flask. Add two drops of phenolphthalein indicator to give a colourless
solution.
Run dilute sodium hydroxide solution from a burette into the flask until
the solution just turns to pink colour. The resultant solution is a sodium
nitrate solution together with the phenolphthalein indicator.
Sodium salt can be obtained as follows:
Add a little activated charcoal to the above pink solution to absorb the
phenolphthalein indicator. Then remove the charcoal by filtration. The
filtrate should be a colourless solution of sodium nitrate. (OR Repeat the
experiment with exactly the same volumes of nitric acid and sodium
hydroxide needed for neutralization (as found by the above experiment).
But, this time do not add phenolphthalein indicator at the start. A solution
of sodium nitrate is formed.)
Boil to concentrate the sodium nitrate solution. Then cool the hot
concentrated solution slowly to room temperature to separate out the
sodium nitrate crystals.
Finally, filter, wash and dry the sodium nitrate crystals with some filter
paper.
Class Practice
A19.1
1. (a) Beaker
(b) Volumetric flask
(c) Pipette filler
(d) Electronic balance
(e) Pipette
2. (a) Pipette (25.0 cm3 type)
(b) Measuring cylinder
(c) Electronic balance
(d) Volumetric flask (250.0 cm3 type)
A19.2
500.0
(a) No. of moles of (COOH)22H2O(s) required = 0.1 mol = 0.0500 mol
1000
Mass of (COOH)22H2O(s) required
= 0.05 (12.0 + 16.0 2 + 1.0) 2 + 2 (1.0 2 + 16.0) g = 6.30 g
6.45
126
(b) Molarity = M = 0.102 M
500.0
1000
(c) Yes. This is because the accurate molarity of the solution is known.
(d) No. of moles of (COOH)22H2O(s) remains unchanged on dilution.
(MV)before dilution = (MV)after dilution
V 250.0
0.102 = 0.0150
1000 1000
V = 36.8
Thus, the volume of 0.102 M ethanedioic acid solution required is 36.8 cm3.
A19.3
(a) After washing the burette, some distilled water (a few drops) may be left inside
the burette. When the given standard hydrochloric acid fills the burette, it is
diluted and the molarity of the acid is no longer known. The given hydrochloric
acid is not a standard solution any more.
(b) The burette should be washed one or two times with the given standard
hydrochloric acid, i.e. the solution it is to deliver.
(c) Pipette
A19.4
(a) H+(aq) + OH(aq) H2O(l)
(b) Pipette
(c) Yellow to orange
(d) Methyl orange
A19.6
2HCl(aq) + Na2CO3(aq) 2NaCl(aq) + CO2(g) + H2O(l)
2.65 g
250.0 cm3
26.30 cm3 (25.0 cm3 used)
?M
Molar mass of Na2CO3 = 23.0 2 + 12.0 + 16.0 3 g mol1 = 106 g mol1
2.65
No. of moles of Na2CO3 in 250.0 cm3 of solution = mol = 0.0250 mol
106
25.0
No. of moles of Na2CO3 in 25.0 cm3 of solution = 0.0250 mol = 2.50 103
250.0
mol
From the equation, mole ratio of HCl : Na2CO3 = 2 : 1.
no. of moles of HCl in 26.30 cm3 = 2.50 103 2 mol = 5.00 103 mol
5.00 10 3
Molarity of HCl solution = 26.30 M = 0.190 M
1000
A19.7
(a) Molar mass of sodium hydroxide = 23.0 + 16.0 + 1.0 g mol1 = 40.0 g mol1
20.0
No. of moles of sodium hydroxide present = mol = 0.500 mol
40.0
0.500
Molarity of solution = 250.0 M = 2.00 M
1000
18.0
(b) No. of moles of HnA present = mol = 0.200 mol
90.0
0.200
Molarity of solution = 100.0 M = 2.00 M
1000
50.0
(c) (i) No. of moles of NaOH = 2.00 mol = 0.100 mol
1000.0
25.0
(ii) No. of moles of HnA = 2.00 mol = 0.0500 mol
1000.0
(iii) 2 mol
A19.8
(a) 2NaOH(aq) + H2X(aq) Na2X(aq) + 2H2O(l)
25.0 cm3 30.00 cm3
0.120 M ?M
25.0
No. of moles of NaOH present = 0.120 mol = 3.00 103 mol
1000
From the equation, mole ratio of NaOH : H2X = 2 : 1.
3.00 10 3
no. of moles of H2X needed = mol = 1.50 103 mol
2
1.50 10 3
Molarity of H2X(aq) = 30.00 M = 0.05 M
1000
(b) Since 1 dm3 H2X contains 6.30 g or 0.05 mol of the solute,
6.3
molar mass of H2X = g mol-1 = 126 g mol1
0.05
A19.9
H2AnH2O(s) + 2KOH(aq) K2A(aq) + (n+2)H2O(l)
1.26 g
0.126 g (25.0 cm3 used) 0.100 M
n=? 20.00 cm3
Molar mass of H2AnH2O = (90.0 + 18.0n) g mol1
20.00
No. of moles of KOH needed = 0.100 mol = 2.00 103 mol
1000
From the equation, mole ratio of H2AnH2O : KOH = 1 : 2.
2.00 10 3
no. of moles of H2AnH2O present = mol = 1.00 103 mol
2
mass of H2 A nH2O
No. of moles of H2AnH2O =
molar mass of H2 A nH2O
0.126
1.00 103 =
90.0 18.0n
n=2
There are 2 molecules of water of crystallization per molecule of the hydrated acid.
A19.11
(a) About 6.5 g of sodium carbonate solid was weighed accurately using an
electronic balance.
(b) The solution was transferred to a 250.0 cm3 volumetric flask using a filter funnel.
(c) 2 or 3 drops of methyl orange indicator solution were added to the conical flask.
Chapter Exercise
1. volumes
2. molarity, solid, concentrated
3. volumetric
4. pipette, pipette
5. burette
6. water, hold/deliver, conical flask, water
7. burette, conical flask, end point, endpoint, indicator, conical flask
8. end point
9. strength
(a) methyl orange, phenolphthalein
(b) methyl orange
(c) phenolphthalein
10. molarity, standard
11. past, third, passive, grammatical
12. B
13. D
14. B
15. D
16. D
17. D
18. D
19. A
20. B
21. A
22. C
23. A
24. B
25. C
26. B
27. B
28. B
29. C
30. B
31. B
32. A
33. B
00500
Molarity of the acid = 20.00 M = 0.250 M
1000
40.00
40. No. of moles of NaOH used = 0.11 mol = 4.40 103 mol
1000
The equation of the reaction is:
FeSO4nH2O(s) + 2NaOH(aq) Fe(OH)2(s) + Na2SO4(aq) + nH2O(l)
From the equation, mole ratio of FeSO4nH2O : 2NaOH = 1 : 2.
4.40 x 10 3
no. of moles of FeSO4nH2O present = mol = 2.20 103 mol
2
mass
No. of moles =
molar mass
0.611
2.20 103 = (55.8 32.1 16.0 4 18n)
n=7
42. (a) In step (1): A 25.0 cm3 type pipette should be used to transfer 25.0 cm 3 of
the drain cleaner sample to the volumetric flask.
In step (2): Add distilled water to volumetric flask until the bottom of the
meniscus reaches the graduation mark.
In step (4): The burette should be washed with the standard hydrochloric
acid right before the titration.
In step (5): A 25.0 cm3 type pipette should be used to transfer 25.0 cm 3 of
the diluted drain cleaner sample to a conical flask but not a beaker. Also, it
is not necessary to use 1–2 cm3 methyl orange indicator, 1–3 drops of
methyl orange indicator will be enough to allow the end point to be
detected.
In step (6): The colour change of the indicator at the end point should be
from yellow to orange; otherwise, the end point may have passed.
(b) (1) 25.0 cm3 of the drain cleaner sample were transferred to a 250.0 cm 3
volumetric flask by using a pipette.
(2) The flask was filled with distilled water until the bottom of the
meniscus reached the graduation mark.
(3) The flask was stoppered and inverted several times.
45. The burette should be cleaned using deionized water and then the solution
it is going to hold or deliver. The main idea is that we should never affect
the molarity of any given solutions: the standard solution and the solution
of unknown molarity.
The burette cannot hold too hot or too cold solutions because the volume
of the burette will change under these conditions.
When the burette is filled, make sure that the jet is filled completely, i.e. no
air bubbles are trapped inside the jet.
During the titration, the burette should be clamped upright. This reduces
the error when taking readings on the burette.
When we take readings on the burette, we should keep our eyes at the
same level as the meniscus.
Part Exercise
1. A
2. C
3. B
4. A
5. C
6. C
7. D
8. B
9. C
10. A
11. C
12. (a) Zinc carbonate reacted with dilute hydrochloric acid to give carbon dioxide.
13. (a)
15. (a) Methyl orange was added as an indicator to mark the end point of the strong
acid-weak alkali titration. The colour would change from yellow to orange.
(b) 3HCl(aq) + Al(OH)3(s) AlCl3(aq) + 3H2O(l)
26.80
(c) No. of moles of HCl used = 0.806 mol = 0.0216 mol
1000
From the equation, mole ratio of HCl : Al(OH)3 = 3 : 1.
0.0216
no. of moles of Al(OH)3 in one tablet of Y = mol = 0.00720 mol
3
Molar mass of Al(OH)3 = 27.0 + (16.0 + 1.0) 3 g mol1 = 78.0 g mol1
Mass of Al(OH)3 in one tablet of Y = 0.00720 78.0 g = 0.562 g
$0.80
(d) For X, price per gram of Al(OH)3 = = $1.82
0.440
$1.00
For Y, price per gram of Al(OH)3 = = $1.78
0.562
Hence, Y is the better buy.
test tube
eggshell limewater
heat
Class Practice
A20.1
This is due to the movements of the Earth’s crust.
A20.2
There is physical separation but no chemical decomposition.
Chapter Exercise
18. (a) The liquid alkanes in crude oil act as a solvent to dissolve the solid alkanes.
(b) The difference in boiling points among the hydrocarbons
(c) Fraction 1
(d) Fraction 1: Refinery gas
Fraction 2: Petrol and naphtha
Fraction 3: Kerosene
Fraction 4: Gas oil
(e) As fuel oil/lubricating oils and waxes/bitumen
(f) It is a liquid. It has lower density than water and is immiscible with water.
Thus, it floats on the water surface and prevents the mosquito larvae from
getting enough oxygen supply.
Class Practice
A21.1
(a) No. Electricity is an important source of energy, but not a fuel. Electricity is a flow
of electrons, not a substance that can be burnt to give out heat.
(b) Yes. It can be burnt to give out heat.
2C4H10(g) + 13O2(g) 8CO2(g) + 10H2O(l)
A21.2
Carbon monoxide, formed by the incomplete combustion of fuel, will build up to
dangerous levels in an enclosed space. It may cause death.
A21.3
1. No. This is because many pollutants (e.g. sulphur dioxide, carbon monoxide,
hydrocarbons) are colourless gases.
2. Carbon monoxide, nitrogen oxides (nitrogen monoxide, nitrogen dioxide),
hydrocarbons, and suspended particulates (e.g. lead, lead(II) compounds, smoke,
soot)
3. Sulphur dioxide/nitrogen oxides/carbon monoxide (Any TWO)
A21.4
1. Both statements are correct, but the second one does not explain the first one.
Actually, the low pH of acid rain is caused by the dissolved sulphur dioxide and
nitrogen dioxide.
2. Probably at that time, many factories in the Kwun Tong industrial district used
fuels of high sulphur content. A large amount of sulphur dioxide was produced
which caused acid rain.
A21.5
1. Burning fossil fuels produces carbon dioxide. More fossil fuels are burnt in
winter to keep warm. Less fossil fuels are burnt in summer.
2. (a) Sulphur dioxide and nitrogen oxides
(b) SO2(g) + H2O(l) ⇌ H2SO3(aq)
4NO(g) + 2H2O(l) + O2(g) ⇌ 4HNO2(aq)
2NO2(g) + H2O(l) HNO3(aq) + HNO2(aq)
(c) CaCO3(s) + 2H+(aq) Ca2+(aq) + CO2(g) + H2O(l)
(d) Sulphur dioxide: burn fuels of lower sulphur content.
Nitrogen oxides: burn less fuels.
A21.6
(a) No
(b) Nuclear power is very clean, since it produces no air pollutants such as sulphur
dioxide, carbon monoxide and nitrogen oxides.
A21.7
(c) It is a cheap, clean and renewable source of energy.
(d) Many countries have neither sufficient rainfall nor high grounds to make
hydroelectricity possible.
Chapter Exercise
1. gives out
2. takes in
3. ossil
y y
4. x+ ,x,
4 2
5. Carbon monoxide, oxic, olourless, dourless
6. leakage, as
7. Safety
8. Air pollution
9. arbon monoxide, ulphur dioxide, itrogen oxides, ydrocarbons, particulates
10. oxic, nitrogen oxides, respiratory
11. 5.6
12. sulphur dioxide, nitrogen oxides
13. lants, water, building
14. unleaded, catalytic converter
15. low sulphur, crubbers
16. ilters, lectrostatic precipitators
17. nfrared radiation, arbon dioxide, warm
18. rise, lobal warming
19. pollutants, spillage
20. save, alternative
21. olar, ydroelectric, idal, ind, nuclear, iomass, non-renewable
22. C
23. D
24. D
25. B
26. D
27. D
28. B
29. D
30. D
35. (a) Naphtha. Alkanes with 5 to 10 carbon atoms are found in naphtha.
(b) Hydrogen and methane
(c) PbO(s) + CO(g) Pb(s) + CO2(g)
PbO(s) + H2(g) Pb(s) + H2O(l)
(d) Carbon monoxide
(e) Town gas contains hydrogen. It forms a mixture with air. The mixture is
explosive. A spark can ignite the mixture, causing an explosion.
Class Practice
A22.1
CO, CO2, Na2CO3, KHCO3, H2O, NH3, KOH, HCl, HNO3, NaCl (or other acceptable
answers)
A22.2
(a)
(b)
(c)
A22.3
(a) Put n = 5 in CnH2n+2. The molecular formula is C5H12.
(b) Put n = 11 in CnH2n+2. The molecular formula is C11H24.
A22.4
(a) A and B; alkanoic acid series.
(b)
A22.5
(a) Yes. This is because they have the same functional group (OH).
(b) A < B < C < D. Van der Waals’ forces are greater between larger molecules.
A22.6
1. (a) Hexyl group
(b) Octyl group
2. (a) CH3(CH2)3CH2
(b) CH3(CH2)5CH2
A22.7
(a) 2-methylpropane
(b) 2,3-dimethylbutane
(c) 4-ethyl-3-methylheptane
A22.8
(a) 2-methylbut-2-ene
(b) Propene
A22.9
(a) Butan-1-ol
(b) Pentan-2-ol
A22.10
(a) 3-methylbutanoic acid
(b) 3,3-dimethylbutanoic acid
A22.11
(a)
(b)
(c)
Chapter Exercise
1. carbon
2. organisms
3. hydrogen
4. slow, carbon dioxide; water
5. saturated, unsaturated
6. functional group
7. general formula, CH2, physical, chemical
8. alkane, alkenel alkanol, alkanoic acid
9. IUPAC
10. Alkyl; hydrogen
11. hydroxyl; carboxylic
12. C
13. D
14. B
15. C
16. A
17. B
18. (a) 2, 4
(b) Four
(c)
20. (a)
(b)
(c)
(d)
© Aristo Educational Press Ltd. 2009 46
HKDSE CHEMISTRY A Modern View (Chemistry) Coursebook 2
Class Practice
A23.1
2C4H10(g) + 13O2(g) 8CO2(g) + 10H2O(l)
A23.2
Chloromethane, dichloromethane, trichloromethane, tetrachloromethane and
hydrogen chloride.
A23.3
More and more petrol is required as fuel for the ever-increasing number of motor
vehicles.
A23.4
(a) An oil fraction
(b) The first few cm3 of gas is mainly air expelled from inside the apparatus.
(c) The delivery tube should be removed from water before stopping heating. This is
to prevent sucking back of water which may crack the hot reaction tube.
A23.5
Ethene can decolorize purple acidified potassium permanganate solution, but ethane
cannot. OR
In the dark, ethene can decolorize the red-orange bromine solution, but ethane cannot.
Chapter Exercise
1. CnH2n+2
2. homologous, increase, similar
3. alogens, xygen
4. substitution
5. initiation, propagation, termination, Free radicals
6. petrochemical
7. cracking, alkene
8. petrol, alkenes
9. , nsaturated, addition
10. two, more, single
11. C
12. D
13. B
14. B
15. A
16. C
17. B
19. (a)
20. (a) This is to avoid the paraffin vaporizing too quickly without being cracked.
(b) High temperature, absence of air and presence of catalyst.
(c) This is to avoid sucking back of water, which can crack the combustion
tube. (When the burner is removed, the combustion tube is cooled down and
then the air inside contracts. As the air pressure inside the tube is lower,
water is sucked up. The cool water will lead to a sudden contraction of the
tube that may crack the tube.)
(d) The bromine water will be decolorized. The gas may be ethene.
(e) This is because under high temperatures, air inside the combustion tube
expands. The gas collected by the first test tube thus usually contains a lot
of air, which will not be used for testing.
(ii)
Class Practice
A24.1
Computer keyboard/mouse/CD case/pen(s)/antenna shield of mobile phone (Any
FOUR)
A24.2
1. Yes. They are made from chemicals derived from petroleum.
2. (a) Yes
(b) No
A24.3
(a) (i) and (iii) can undergo addition polymerization.
(i)
(iii)
(b) Propene
(c) Polypropene
A24.4
(a) (i) Polyethene/polythene
(ii) Polypropene/polypropylene
(iii) Polyvinyl chloride
(b) (i) Ethene
(ii) Propene
(iii) Chloroethene/vinyl chloride
(c) (i) Flexible and good insulator of electricity.
(ii) Resistant to many chemical solvents, alkalis and acids.
A24.5
A24.6
(a) Weak intermolecular forces
(b) The polymer chains vibrate vigorously when heated. The intermolecular forces
are overcome, and the chains can slide over one another easily. The plastic bottle
thus softens and deforms.
(c) Thermoplastic
(d) (i) The bottle softens and melts.
(ii) The bottle burns.
(e) (i) The melting point of polypropene is low. The milk feeding bottles may
soften when they are sterilized by hot water or steam.
(ii) PVC is poisonous.
Chapter Exercise
1. Petroleum
2. ethane, aphtha, as oil
3. polymers
4. ight, unreactive, heat, electricity
5. Polyethene
6. Polymerization, polymers
7. addition
8. monomer, polymer, small,
9. repeating unit
10. natural
11. incinerators
12. Reduce, Reuse, Recycle, biodegradable
13. D
14. A
15. D
16. C
17. C
18. C
19. (a) C
Repeating unit:
(ii)
(ii)
(ii)
22. (a)
(b)
(c) Tetrafluoroethene
(d) It is non-toxic, heat and chemical resistant. Besides, it has a smooth and
slippery surface.
Part Exercise
1. B
2. B
3. C
4. C
5. A
6. C
7. B
8. B
9. D
10. B
11. (a)
thermometer (0360C)
oil fraction
rocksil soaked with crude oil
water
heat
13. (a) Volume of one mole of a gas at room conditions = 24 dm3 mol1
molar mass of gas Q = 1.75 g dm3 24 dm3 mol1= 42 g mol1
relative molecular mass of gas Q = 42
14. (a)
(b) No. This is because alkanes do not contain carbon-carbon double bond.
(c) For ethane, there is no observable change. For ethene, the bromine water is
decolorized.
(d) There is no observable change. It is because polyethene does not contain
any carbon-carbon double bond.
(e) (i) Plastic bags/wrapping film for food/food boxes/flexible cold water
pipes/kitchen wares (Any ONE)
(ii) Polyethene is light and flexible.
For polymer B:
For polymer B:
(c) All of them are thermoplastics because they all consist of chain-like giant
molecules which are attracted by weak intermolecular forces.
Heat the sample gently on a hot plate. It softens or melts because it is a
thermoplastic.
16. Coal contains sulphur. Sulphur dioxide is formed when coal is burnt in a
power station.
S(s) + O2(g) SO2(g)
Suspended particulates are carbon particles present in the flue gas
generated in the power station.
Nitrogen oxides are formed when fuels are burnt at very high temperatures
in a power station.
N2(g) + O2(g) 2NO(g) and 2NO(g) + O2(g) 2NO2(g)
Possible ways to reduce the emission of air pollutants:
Sulphur dioxide: installation of scrubbers/use coal of lower sulphur
content
Suspended particulates: installation of electrostatic precipitator