CH OH + 1 O   HCHO + H O

3  2 2 2
 

CH OH  HCHO + H
3 2

ΔG   ΔHf   
J J
Compuesto  
 MOL   MOL 
CH OH -162000 -200670
3
O 0 0
2
HCOH -109910 -115900
H O -228590 -241820
2
H 0 0
2

Para K1

ΔG = -176500  
J
ΔG = -109910 - 228590 + 162000 
R R  mol 

ΔH = -157050  
J
ΔH = -115900 - 241820 + 200670 
R R  mol 

Para K2

ΔG = 52090  
J
ΔG = -109910 + 162000 
R R  mol 

ΔH = 84770  
J
ΔH = -115900 + 200670 
R R  mol 

176500
8.314 298
K ( 25°C) = e K = 8.6845E30
1 1

- 52090
8.314 298 K = 7.398E - 10
K ( 25°C) = e 2
2

PARA K1 A 443 K

 ΔHR   1 1 
ln( 8.6845E30 ) + - 157050    1 - 1 
lnK1+  -    
 R   T1 T2 
K = e
8.314   298 443 
K =e
1 1

K = 8.4724E21
1
 PARA K2 A 443 K

 ΔHR   1 1  ln( 7.398E- 10) + 84770    1 - 1 

lnK1+  -    
K = e
8.314   298 443 
 R   T1 T2 
K =e 2
2

K = 5.404E - 5
2

Sistema de Ecuaciones

n ( CH3 OH)   1 - ξ1 - ξ2 

 n   1   -1 -1   
 ( O 2)   0.21   -0.5 0
  0.21 - 0.5 ξ1 
 n       ξ1   
0    ξ
 ( H2 O) 
= 0  +  1 = 1 
 0   1 ξ 
n  1   2  ξ +ξ 
 ( HCOH)       1 2 
 0   0 1   
 n( H )  
ξ
2 
 2 
n 0.79 0.79
( N2)
------------------------------------------------
Total 2 ( 2 + 0.5ξ1 + ξ2 )

Ecuaciones

( )
0.5
 0.21 - 0.5 ξ1  ξ  ξ +ξ
8.472E21 ( 1 - ξ - ξ )  
1 1 2 0.5
- ( 2.5) =0
1 2  2 + 0.5 ξ + ξ 
 1 2 ( 2 + 0.5 ξ + ξ
1 2)

(
5.40E - 5  1 - ξ - ξ
1 2 )(2 + 0.5ξ1 + ξ2) - ξ2 (ξ1 + ξ2)(2.5) = 0