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Received: July 28, 2016 Accepted: October 02, 2016 Online: December 31, 2016
Abstract
The was conducted to assess the impact of (r=0.6284, p<0.05), TDS & Biochemical
various types of anthropogenic religious oxygen demand (BOD) (r=0.6757, p<0.05),
activities on water quality of three ponds Total hardness & Calcium (r=0.9545,
Ishwargangi Pond, Kurukshtera Pond and p<0.01) and Total hardness & Magnesium
Pushkar Pond of Varanasi. The physico- (r=0.9985, p<0.01). The value of Phosphate
chemical parameters studied were pH, shown statistically significant negative
Turbidity, Total Dissolved Solids (TDS), correlation with turbidity (r=-0.6169,
Total Hardness, Calcium, Magnesium, Total p<0.05), Sulphate (r=-0.7068, p<0.05). This
Alkalinity, Chloride, Phosphate, Sulphate, study revealed all three ponds have
Dissolved Oxygen (DO), Biochemical objectionable water quality especially with
Oxygen Demand (BOD) and Chemical respect to human health, biotic life and entire
Oxygen Demand (COD). The water quality ecosystem. Therefore, water of these water
characteristics revealed significant increase bodies needed to be regularly changed after
in the values of turbidity, Chloride, mass bathing to protect the aquatic
Phosphate, Dissolved Oxygen (DO), component from different contaminations.
Biochemical Oxygen Demand (BOD) and Therefore water from these water bodies
Chemical Oxygen Demand (COD) as need to be changed regularly to protect the
compared to the permissible limit of drinking aquatic life from different contaminations.
and irrigation water quality standard (BIS, The other measures includes establishment of
IS-10500, FAO). The result of Pearson comprehensive water quality monitoring,
correlation analysis exhibited statistically citizen awareness with a proper urban drain
significant positive correlations between disposal system to prevent water bodies of
Total dissolved solids (TDS) & pH Varanasi from pollution.
(r=0.8671, p<0.05), TDS & Total Alkalinity Keywords: Anthropogenic | Physico-
For Correspondence:
1
chemical parameters | Correlation analysis |
Department of Food & Nutrition, Sri Agrasen Kanya
P.G. College, Varanasi. India Contaminations
2
Department of Science, Sampurnanad Sanskrit
University, Varanasi. India
Email: sailendraji@gmail.com
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Tripathi & Tripathi/Vol. VII [2] 2016/53 - 60
Irrigation Drinking
Ishwargangi Kurukshtera Pushkar
Water Quality Parameter Standard Standard
Pond Pond Pond
BIS, FAO BIS
pH 6.75 7.50 7.50 6.5 - 8.5 6.5 - 8.5
Turbidity (in NTU) 56.50 33.00 17.50 - 5-10
TDS (in mg/l) 760.00 860.00 1035.00 2100.00 2000.00
Total Hardness (in mg/l) 315.00 193.50 217.00 - 600.00
Calcium (in mg/l) 80.50 49.26 56.07 - 200.00
Magnesium (in mg/l) 265.96 163.49 182.84 - 150.00
Total Alkalinity (in mg/l) 153.90 148.51 143.12 140 600.00
Chloride (in mg/l) 740.61 582.63 745.70 500.00 250.00
Phosphate (in mg/l) 87.00 94.00 128.50 0-2 5.00
Sulphate (in mg/l) 131.15 134.50 123.00 - 100.00
COD (in mg/l) 166.80 121.66 212.74 - -
BOD (in mg/l) 160.00 139.00 141.00 100.00 -
DO (in mg/l) 1.54 2.21 3.07 - -
Table 2: Physico-chemical characteristics of water
samples
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TDS were ranging from 760 to 1035 mg/l exceeded the permissible limit for both
and all were below the permissible value for irrigation (FAO) and drinking water (BIS, IS-
both irrigation (FAO) and drinking water 10500). The higher alkalinity may be due to
(BIS). The highest concentration was the large scale use of banks as open latrine
observed as 1035 mg/l in Pushkar pond and and washing of excrete in nearby the ponds.
lowest as 760 mg/l in Iswargangi pond. Total Alkalinity also increases the amount of
dissolved solids in pond water come from dissolved carbonate, which leads to gives
urban discharge of sewage waste, soap, undesirable taste to water (Radhakrishnan et
detergents (Tripathi and Viswakarma 2015). al. 2007; Tripathi and Viswakarma 2015).
The mean value of total hardness was The degradation of plants, other organism
observed between 193.50 to 315 mg/l in all and organic waste might also increase in
pond water, which is below the permissible carbonates and bicarbonates thereby the
limit for drinking water (BIS, IS-10500). The alkalinity (Chaurisa and Pandey, 2007). The
high content of calcium and magnesium in value of chloride was observed between
addition to sulphate and nitrate in the sewage 582.63 to 745.70 g/l. The all three ponds
waste discharge in responsible for increasing samples chloride value were exceeded the
total hardness of pond water. The hardness permissible limit for both irrigation water
of water helps to protect aquatic organisms (FAO) and drinking water (BIS, IS-10500)
against harmful effects of pH fluctuation and except Kurukshetra pond (582.63 mg/l).
metal ions (Thakor et al., 2011; Matta et al., Chloride exceeding 250 mg/l in drinking
2015b). The concentration of Calcium in water imparts salts taste to water and causes
water samples were observed between 49.26 laxative effects. The higher value of chloride
to 80.50 mg/l and all samples were within the is toxic to fish and aquatic organisms, even in
permissible limit of drinking water (BIS, IS- very small amounts (Tripathi and
10500). Higher concentration of Calcium Viswakarma 2015). Phosphate values varied
may cause incrustation in water supply from 87 to 128.50 mg/L, which is above the
structure and adversely affect on domestic permissible limit for both irrigation (FAO)
use (Raghavendran, 1992). The values of and drinking water (BIS, IS-10500). This
magnesium observed between 163.49 to might be due to discharge of domestic
265.96 mg/l and all the values were above sewage, or leaching of fertilizers used in
the permissible limit for drinking water (BIS, nearby agricultural field. The phosphorus
IS-10500). Higher concentration of nutrient is needed for the algal growth, which
Magnesium in water is probably due to the is a key element in metabolic reactions of
high decomposition rate of organic matter, aquatic organisms and responsible for
high evaporation and other anthropogenic eutrophicaton of ponds (Sachin Mishra et al.,
activities. Magnesium associated with the 2014; Matta et al., 2015c). Sulphate value of
sulphate ion has a laxative effect on persons all three ponds of Varanasi ranged between
unaccustomed to it (Parveen et al., 2012). 123 to 134.50 mg/l, which is below the
The mean total alkalinity was varied from permissible limit for drinking water (BIS, IS-
143.12 to 153.90 mg/l. All the values were 10500). Sulphate remains in the pond and
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does not biodegrade hence higher Tripathi, 2016; Eucharista et al, 2016). The
concentration of sulphate in pond water can values of Phosphate shown statistically
be toxic to fish and other organisms. significant negative correlation with turbidity
COD value varied from 121.66 to 212.74 (r=-0.6169, p<0.05), Sulphate (r=-0.7068,
mg/L. This may be due waste water p<0.05) and positive correlation with
discharge from dying units located near chemical oxygen demand (COD) (r=0.8261,
ponds. The BOD value was observed p<0.05). The positive correlation of COD
between 139.00 to 166 mg/l, which is above and phosphate indicates that increased load
the permissible limit for irrigation water of COD through urban discharge in water
(FAO). This may be due to high temperature bodies increases Phosphate concentration,
and algal bloom in ponds and water hyacinth which leads to cause eutrophication. The
that covered the whole pond so no sunlight negative correlation of Phosphate and
can penetrate in the pond. It is harmful for turbidity indicates that the oxidation of
the aquatic life present in that pond. BOD Phosphates improves the clarity of water
depends on temperature, extent of through increasing settling rate of suspended
biochemical activities and concentration of solids (James et al., 2013).
organic matter and microbial population such
Level of Positively correlated Negatively
as bacteria and fungi (Prasanna and Ranjan, Significance Parameters correlated
Parameters
2010; Sachin Mishra et al., 2014). The DO TDS & pH (r=0.8671)
value of all three ponds varied from 1.54 to Total Alkalinity & Turbidity
(r=0.7206) Phosphate
3.07 mg/l. The lower DO value of Total Alkalinity & TDS & Turbidity
(r=0.6284) (r=-0.6169 )
Iswargangi pond was might be due to the α= 0.05
BOD & TDS (r=0.6757) Phosphate
Sulphate & Chloride & Sulphate
high rate of oxygen consumption by (r=0.7158) (r=-0.7068)
oxidisable matter, which may affect the COD & Phosphate
(r=0.8261)
diversity of aquatic life living in it (Gupta et Calcium & Total Hardness
(r=0.9545)
al, 2011; James et al, 2013). Magnesium & Total
α= 0.01 -
Hardness (r=0.9985)
Correlation analysis Calcium & Magnesium
(r=0.9366)
Among the various physiochemical Table 3: List of significant positive and
negative correlated water quality
parameters of surface water, only few
parameters exhibited significant correlations
Total hardness was found to have significant
(Table 3). In present study the value of Total
positive correlation with Calcium (r=0.9545,
dissolved solids (TDS) shown a statistically
p<0.01) and Magnesium (r=0.9985, p<0.01).
significant positive correlation with pH
Similarly the value of Calcium and
(r=0.8671, p<0.05), Total Alkalinity
Magnesium also shown significant positive
(r=0.6284, p<0.05), Biochemical oxygen
correlation (r=0.9366, p<0.01). Significant
demand (BOD) (r=0.6757, p<0.05). This
positive correlation between turbidity and
indicates that an increased load of dissolved
total alkalinity (r=0.7206, p<0.05) indicates
solids influence the pH, total alkalinity and
that the transparency of water is influenced
BOD value of surface water (Dabgerwal and
by the increasing concentration of carbonate,
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