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Refining-corrosion cycle:
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Mechanical degradation:
Corrosion reduces the thickness of the metal, which causes
in loss of mechanical strength and failure of the structure.
Efficiency of the machine is reduced due to corrosion.
Because of corrosion, pipes are blocked and pumps are
difficult to operate. It also damages boilers.
Corrosion seriously shortens the predicted design life.
Chemical Impact:
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Uniform or general corrosion:
It is the uniform thinning of a metal without any localized attack.
Corrosion does not penetrate very deep inside. Uniform corrosion is more likely
to take place in acidic environments (more severe in the case of SOx).
rusting of iron or structural steels in open air or tarnishing
of silver or electrical contacts or “Fogging ” of nickel
Corrosion of offshore drilling platforms or galvanized steel
stairways or underground pipes
In localized type of attack, rate of corrosion being greater at some areas than
at others. Here the anode is very small and fixed area of corroding part of metal. So
remaining area of the metal acting as cathode. Local corrosion is more likely to take
place in alkaline, neutral, or slightly acidic environments.
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2. Wet or Electrochemical corrosion
Corrosion is due to the formation of large number of galvanic cells in wet condition.
Corrosion occurs at anode whereas corrosion products are accumulated at cathode.
Corrosion is fast, due to electrochemical cells.
Important condition:
Corrosion increases with
O2 and moisture
rise in temperature
rise in concentration of H+ ions
increases with O2 and moisture
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Sl.No. Wet or Electrochemical corrosion Dry or chemical corrosion:
1 Corrosion is due to the formation of large Corrosion is due to direct attack
number of galvanic cells in wet condition chemicals in dry condition
2 Corrosion occurs at anode whereas corrosion Corrosion products are formed at
products are accumulated at cathode the place of corrosion
3 Corrosion is fast, due to electrochemical Corrosion is slow, depending on the
cells nature of the chemical reaction
4 Explained by electrochemical reactions Explained by adsorption
mechanism
5 Corrosion takes place at active centre only Corrosion is uniform
i.e., not uniform
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Why ?
–economics, safety, and conservation
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Losses sustained by industry and by governments ~$ 276 billion in the
United States, or 3.1% of the GDP
Economic losses can be divided into direct and indirect losses
Direct losses:
Indirect losses:
Sudden failure can cause explosions and fire, release of toxic products
and collapse of structures.
Safety is a critical consideration in the design of equipment for nuclear
power plants and for disposal of nuclear wastes.
Medicals metals used for hip joints, screws, heart valves, etc – high
reliability is of paramount importance.
Corrosion products could make sanitizing of equipment more
difficult,eg. milk and dairy product plant.
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Loss of metal by corrosion is a waste not only of the metal, but also of
the energy, the water, and the human effort that was used to produce and
fabricate the metal structures
Corrosion destroys the aesthetic appeal of the product and damages the
product image
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1. Discuss the five important consequences of corrosion.
2. Discuss the economic aspect of corrosion
3. Describe with an example how corroded structures can lead to
environmental pollution.
4. What is the relationship between depletion of natural resources
and corrosion?
5. Explain how corrosion can be considered as extractive
metallurgy in reverse.
6. Name three cities in Southeast Asia and the Middle East which
have the most corrosive environment.
7. State two important corrosion websites.
8. What is corrosion? Why do metals corrode?
9. Why most of the metals are found in the ore form and not in the
pure form? Explain.
www.intercorrosion.com
Websites www.learncorrosion.com
www.nace.org
www.iom3.org
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