Dario. too7/00288 005 Oso Polymer Bulletin Synthesis of Organosoluble and Optically Active Poly(ester-imide)s by Direct Polycondensation with ‘Tosyl Chloride in Pyridine and Dimethyiformamide Shadpour Multakpour (-)', Elaheh: Kovesart oF Technolony, Ifahan, 84196-83111, CR iran, 1-Peevious Name: Shacipene fe: Mallaipour iene MALLAKWOCIUE ACI Roblimed ontine: 7 July 2008 "© Springer Veriag 2008 ‘Summary 4.4-Oxydiphthalic anhydride (1) was reacted with 1-methioni the resulting. N.N"-(4,4"oxydiphthaloy!-bis-1_-methions igh yield. ‘The direct polycondensation reaction of Uus di lols such as bisphenol A (Sa). phenolphthalcia (Sb). 1 Ge), “4.4-dihydroxydiphenyl sulfide (Sd), 2.6-dihydroxytoluene Sihgroxydipheny! sulfone (GP snd 2,4-dihydroxyacetophenone (Sp) swas carried Out ina system of tosyl chloride “(TsCi), pyridine (Py) and. N.N-dimethylformamide (DMF). The ‘reactions "with TsCl Were significantly promoted by conolling slooholysis with diols in the presence of the catalytic amounts of DMF to give a series oF optically ‘active poly(ester Imide)s (PEDs with good yield and moderate infverent Viscosity ranging 0.21-0.71 diJg. ‘The polycondensation reactions were significantly, affected by the amounts of DMP, molar concentration of monomers, TsCl and Pyridine, aging time, addition time of diols, temperature and the reaction time. All oF the above polymers were Tully characterized by HUNMR, FT-IR land specifi rotation, Some structural characteriration and physi new optically acti ve PEIs are reported, ‘Contant ovale et SeonaDiet Tetrahedron var comnacatenet * ELSEVIER Comparisons of O-acylation and Friedel~Crafts acylation of phenols and acyl chlorides and Fries rearrangement of phenyl esters in trifluoromethanesulfonic acid: effective synthesis of optically active homotyrosines Ryo Murashige, Yuka Hayashi, Syo Ohmori, Ayuko Torii, Yoko Aizu’, Yasuyuki Muto’, Yuta Murai, ‘Yuji Oda*, Makoto Hashimoto®* “i interme gn rey et on ‘iifamears wane see muy go ty "2 ene rc eee ae ‘Sean! pete Cl eats hte nr ar aki ae 58 ‘Zansa ae vag perl Grae a es a We ana a apes Oa fate pm 20 ans and Cacao (deals ars and Pies earners) ae enn The enn em Name) Set i he eo tues ald CHOA Wee sala, pes eb ‘Seca Ath ied THM wa aed fer fein Oxy concent VE wa es (de i eft Cans i condo Treats ben eped tev ates GF haeersine eis. Sth es resragenen o iPA- AS OMe a ee Ciats bate. Stun pest wei) ous aro ossyeine aetna He eee ‘htt od dept ed asain ast teey pea Te entai neten 20 rar Al ig ene scone