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2016. SPRING Vol(E).

6
Neutron Science and Technology
Korea Atomic Energy Research Institute I Newsletter
Creating Future Innovation

Periodic Safety Review (PSR) of HANARO

1. Background to Improve Regulations of Nuclear Research Reactors” and


In 1996, the International Atomic Energy Agency (IAEA) suggests the introduction of PSR to ensure the safety of the long-
recommended the implementation of a comprehensive and term operation of nuclear research reactors based on cases in
systematic PSR (Periodic Safety Review) to its member countries foreign countries (February 2007)
at the Convention on Nuclear Safety. In 1999, the 11th Nuclear - Following the amendment of the Nuclear Safety Act and its
Safety and Security Commission in Korea finalized directions to Article 34, a PSR of nuclear research reactors becomes subject
implement PSR with respect to nuclear plants. Thus, a PSR has to Article 23 of the Act (May 2014)
been implemented in Korea since May 2000. The amendment - Article 2 and 37 of the Enforcement Decree and Article 20
of the Nuclear Safety Act in May 2014 legalized a PSR for of Enforcement Regulations regarding the Nuclear Safety Act
nuclear research reactors that have been operated for 10 years expands the number of safety factors (November 2014)
or more, and the specific Enforcement Decree and Regulations - Supplementary Provision 3 of the Enforcement Decree of the
regarding the Nuclear Safety Act began to be implemented in Nuclear Safety Act specifying the completion of the first PSR of
November 2014. The amended Nuclear Safety Act expanded the nuclear research reactors that have been operated for 10 years
st
number of safety factors from 11 to 14. Since its first operation or more by 31 December, 2018
in February 1995, HANARO has served as the only 30MW
multipurpose nuclear research reactor and played an important 3. PSR’s Safety Factors
role in developing research on neutrons. Through PSR, HANARO Reflecting the PSR guidelines by the IAEA in 2013, Korea has
will ensure its safety. By implementing the recommendations expanded the number of safety factors from 11 to 14, adding
for safety improvement from PSR and being granted legal three to the existing 11: plant design, probabilistic safety
justification, HANARO will continue to provide services to its assessment, and hazard analysis (Article 37 of the Enforcement
constituents for the next ten years. Decree of the Nuclear Safety Act). Safety factors being subject to
a PSR are as follows.
2. Legal Processes
- Publication of PSR guidelines by the IAEA (1994 and 2005) 1. Plant design
- IAEA recommendation of a comprehensive and systemic PSR to 2. Actual condition of SSCs important to safety
its member countries in the Convention on Nuclear Safety (1996) 3. Equipment qualification
- The government finalizes directions to implement PSR regarding 4. Ageing
nuclear reactors being operated (December 1999): 11th Nuclear 5. Deterministic safety analysis
Safety and Security Commission 6. Probabilistic safety assessment
- Enactment of the Atomic Energy Act as well as its enforcement 7. Hazard analysis
decree and regulations with respect to a PSR (January 2001) 8. Safety performance
- Legalization of continuous operation: enforcement decree and 9. Use of experience from other plants and research findings
regulations with respect to legalization (September 2005) 10. Organization, the management system and safety culture
- IAEA General Conference approves the Code of Conduct, 11. Procedures
which recommended the implementation of PSR regarding 12. Human factors
nuclear research reactors (September 2004) 13. Emergency planning
- The Korea Institute of Nuclear Safety conducts a “Study 14. Radiological impact on the environment

2016 newsletter Spring Vol. 6 1


HANARO Issue & Focus
4. PSR Implementation submission of a comprehensive PSR report by the end of 2018.
Jongsoon Kim
1. Composition of the members of PSR, preparation for a Senior Researcher,
detailed plan for a PSR and budgetary/personnel resources, and 6. Future Plan Development of a high-performance cathode Neutron Instrumentation
Division
beginning of the implementation of PSR tasks In 2016, HANARO will work with its contractors including
2. Explanation of PSR to the regulatory body (schedule and KEPCO E&C to develop programs with respect to the system
electrode for Na ion batteries jongsoonkim@kaeri.re.kr

cutoff dates for technical standards and PSR materials) and equipment training and an understanding of a PSR
3. Writing specifications for PSR contract and making a purchase implementation in order to facilitate such implementation. The energy storage systems (EESs) industry is growing was successfully analyzed using Rietveld refinement. It has
agreement (plant design and their aging management) Additionally, with its contractors, HANARO is planning the explosively. Li ion batteries (LIBs) have been considered as a the highest redox voltage among vanadium-based cathodes
4. Writing specifications for PSR contract and making a hosting of a seminar by inviting foreign experts and collecting promising candidate for large-scale applications such as electric reported thus far for NIBs; this property results from the close
purchase agreement (other safety factors) information on PSR cases and experiences. In 2017, HANARO vehicles (EVs) because of their high energy density. However, connectivity between vanadium ions and phosphorus. Its ~4.13
5. Evaluation of 14 safety factors (internal investigation, will examine a mid-PSR report prepared by its contractors as there are growing concerns about the accessibility of secure Li V redox potential was clearly identified through a combination of
contracting out, management, and review of evaluation report) well as its radiological protection and safeguard division. Once resources to satisfy the rapidly rising global demand for LIBs. first-principles calculations and experiments. Additionally, these
6. Writing a comprehensive PSR report and a comprehensive the examination is completed, HANARO will review a preliminary Na ion batteries (NIBs) are an attractive alternative to LIBs analyses revealed that the volume of change during sodium
safety improvement plan comprehensive repor t containing all the materials and because the underlying electrochemical reaction is similar to de/intercalation is as low as 1% during a charge process; this
7. Submission of the PSR report and its summary report to the evaluations with respect to a PSR and submit it to the regulatory that of LIBs but is based on the nearly unlimited resources of Na. finding contrasts with the belief that a large volume change
regulatory body body. In May 2018, HANARO will obtain and review a PSR report +
However, the redox potential of Na /Na (-2.71 V vs. SHE) is lower typically accompanies Na ion de/intercalation in NIB electrodes
8. Assessment of PSR report submitted and preparation of and its summary report from its contractors and radiological than that of Li+/Li (-3.04 V vs. SHE), and the larger radius of because of the large ionic size of Na ions. This unexpectedly
assessment reports by the regulatory body, exchange of protection and safeguard division and submit a final PSR report Na+ ions (r=1.02 Å) compared with Li+ ions (r=0.59 Å) causes a small volume change is attributed to the open crystal framework
questions and answers with the regulatory body, and reflecting and the integrated implementation plan of safety improvements considerable change in the host structure upon (de)intercalation, of Na7V3(P2O7)4 and leads to an outstanding cycle stability of
recommendations made by the regulatory body to the regulatory body by the end of December 2018, which is which often results in a poor cycle life and low energy density. Na 7V 3(P 2O 7) 4 (75% retention of the initial capacity after 600
9. Securing approval from the regulatory body (completion of the legal deadline for the submission of the PSR report. Starting Dr. Jongsoon Kim at the Neutron Instrumentation Division, and cycles). These results were published in Advanced Energy
PSR) in January 2019, the regulatory body will review and inspect the his collaborators, Prof. Kisuk Kang’s group in Seoul National Materials on 18th January 2016. The title of this paper is “Tailoring
10. Implementation of the integrated safety improvement plan PSR report. Modifying the report with an exchange of questions University, introduced a new 4V-class cathode material in NIBs, a new 4V-class cathode material for Na ion batteries.”
and answers with suggestions by the regulatory body, HANARO Na 7V 3(P 2O 7) 4 for the first time. The structure of Na 7V 3(P 2O 7) 4
5. HANARO’s PSR Implementation Strategies will secure the approval from the regulatory body with respect
Initially, HANARO considered the implementation of a PSR to the completed PSR by the end of 2019, and starting in 2020,
with its internal experts alone. However, since a PSR of HANARO will implement matters specified in the integrated
nuclear research reactors is to be done for the first time, it was implementation plan of safety improvements derived from the
considered better for HANARO to contract out the PSR to an PSR report.
organization that has had experience in performing a PSR for
the Korea Hydro & Nuclear Power Corporation. In this way,
HANARO can gain experience of the implementing of a PSR for
nuclear research reactors and use it for the next PSR through
strengthening its technical personnel and trainings. These Schematic of Na7V3(P2O7)4 structure Refined XRD pattern and electrochemical performance of Na7V3(P2O7)4
matters were reported to the top executives of HANARO. The
PSR implementation began in 2015 and HANARO contracted out
the implementation to KEPCO E&C, which would be responsible
for evaluating seven safety factors including aging management,
Byung-hun Hwang
plant design, and PSA. In 2016, the safety factors of emergency Researcher,
HANARO Management
planning and radiological impact on the environment will be
reviewed by the radiological protection and safeguard division
HANARO Outer Wall Reinforcement well in Progress Divison
hbh@kaeri.re.kr
of KAERI, which, following the same schedule of KEPCO E&C,
will evaluate the 13th and 14th safety factors specified by Article
The safety of the HANARO building will be further reinforced with But some part of the reactor building wall can only withstand 0.2g,
37 of the Enforcement Decree of the Nuclear Safety Act and
the additional installation of an outer wall that will surround the which is equivalent to a Richter scale of 6.5. The safety authority
prepare for a report based on this evaluation. The evaluation of
Reactor Concrete Island (RCI). Installation began in February of the Korean government, therefore, recommended HANARO
the remaining five safety factors including a deterministic safety
2016 and is expected to be completed by August 2016. The to reinforce the safety of the reactor building wall to meet the
analysis (emergency operation procedure), safety performance,
reactor, pool, and other major reactor systems are housed in the seismic criteria of HANARO.
human factors, organization and procedures along with
RCI. The outer wall reinforcement project is being carried out Following the NSSC's (Korean Nuclear Safety and Security
operation experience will be contracted out to an organization
as a part of the Korean government's strong recommendations Commission) recommendation, HANARO immediately formed
in April 2016. Once the contracting out and evaluation of the
regarding post-Fukushima measurements. After the government’s a special task force team to study the most feasible ways to
14 safety factors is completed, HANARO will prepare for the
checkup, the RCI can sufficiently withstand certain conditions. reinforce the reactor building. Emphasis was placed particularly

2 2016 newsletter Spring Vol. 6 3


on identifying the possible interference between the RCI and the out HANARO-related research projects during the construction Wakimot from JAEA and Dr. Chang-Hee Lee from KAERI made research by Prof. Soo Yeol Lee from Chungnam Nat. Univ., by
reactor systems. Moreover, considerations were also placed to period without difficulty, KAERI plans to rearrange project plans special presentations on the current status of J-PARC, JRR-3 and Dr. Stefanus Harjo from J-PARC, and alloys using SANS by Dr.
satisfy not only the seismic performances of the reactor building such as the project duration, and even plans to conduct some HANARO. Eunjoo Shin from KAERI and Prof. Yojiro Oba from Kyoto Univ.
but also the site conditions. necessary experiments at foreign research reactors. Through the This year's meeting has six sessions, i.e., (1) Bio, Soft Matter & At the Instruments Software & Advanced Data Analysis Session,
An installation using steel H-beams that will support the reactor HANARO reinforcement project, KAERI wishes to demonstrate Liquids, (2) Hard Matter, (3) Mini-workshop on Inelastic Neutron Dr. Jeong-Soo Lee and Dr. Ji-Yong So from KAERI presented
building from both the inside and outside was planned. Structural again that the nation's sole research reactor is a safety- Scattering of Strongly Correlated Systems of J-PARC and other on neutron reflectometry and DC-TOF, respectively. Dr. Yajuhiro
steel is used to reinforce the flexural performance, which has guaranteed large-scale research facility that is wholly used for Neutron Sources, (4) Industrial Applications, (5) Young Neutron Inamura from J-PARC made a presentation on data analysis
been identified at some parts of the rector building. In addition, the people. Scientists, and (6) Instruments, Software & Advanced Data software for inelastic instruments at J-PARC, whereas Dr. Tatsuy
a PS (Pre-Stressed) Steel tendon is used to reinforce the tensile Analysis. Kikichi presented a G(r.t) analysis method. At the mini-workshop
strength. The highlights at the Bio, Soft Matter & Liquids Session included on inelastic neutron scattering, presentations were made on
HANARO has been temporarily shut down during the discussions on ionomoer by Prof. Moon Jeong Park from the latest research activities on inelastic neutron scattering as
reinforcement period. To supply locally needed medical and POSTECH, block copolymer blends by Prof. Du Yeol Ryu from well as the recent status of instruments by six experts (three
industrial radioisotopes in time, KAERI plans to import some Yonsei Univ., amphiphilic co-network gels by Prof. Mitsuhiro from Japan and three from Korea). It was mutually agreed to
radioisotopes such as I-131 and Ir-192 source materials from Shibayama from Tokyo Univ., and kinetics in protein by Prof. conduct advanced neutron research through a more elaborate
abroad and produce end products. Meanwhile, in order to carry Masaaki Sugiyama from Kyoto Univ.. At the Industrial Applications collaboration
Conceptual diagram of the HANARO reinforcement scheme
Session, valuable presentations were also made on deformation

HANARO News

Mr. Hoan-Sung Jung as Vice-President for “Department of Research Reactor


Utilization” and Mr. Myong-Seop Kim as “Director of Neutron Utilization
Technology Division”
The participants of the 15th Japan-Korea Meeting on Neutron Science Business Session at the 15th Japan-Korea Meeting on Neutron Science
Mr. Hoan-Sung Jung was named the Vice-President for the worked at HANARO Management Division and Neutron Utilization
Department of Research Reactor Utilization of KAERI on 1 st Technology Division.
January 2016. He joined KAERI in 1987 and was primarily
associated with the Research Reactor Division and KMRR
Engineering Management Division. Later, he was appointed as
Director of HANARO Management Division, Director of Nuclear Young-Sam Chung
Control & Safety Division, and Vice-President of Department of KAERI-KRISS Joint Research Center for Principal Researcher
Neutron Utilization
Nuclear Safety and Security, respectively. In addition, Mr. Myong-
Seop Kim was nominated as Director of Neutron Utilization
Production of Certified Reference Materials Technology Division,

yschung@kaeri.re.kr
Technology Division. He joined KAERI in 2000 and previously
Mr. Hoan-Sung Jung Mr. Myong-Seop Kim
KRISS (Korea Research Institute of Standards and Science).
To facilitate the Joint Research Center, an agreement was
concluded between the two institutes on 15th December 2015.
Jaseung Koo
The 15th Japan-Korea Meeting on Neutron Science, Senior Researcher,
The agreement details the joint research endeavors by the two
Neutron Science Division institutes to produce Certified Reference Materials (CRMs), and
Busan, Korea, from 6th to 8th January 2016 jkoo@kaeri.re.kr outlines the operational aspect of the center.
At the signing ceremony of the agreement, Dr. Jong Kyung Kim,
The 15th Japan-Korea Meeting on Neutron Science was held Prof. Sungkyun Park of Busan Nat. Univ. as the local organizers. President of KAERI, emphasized the importance of establishing
during 6 th-8 th January 2016 at the Hotel Nongshim in Busan. The next meeting will be held in Japan in 2018 because the and maximizing the collaborative R&D systems among the
Seventy-six experts (twenty-six from Japan, fifty from Korea) International Conference on Neutron Science (ICNS) will be Tape cutting of the KAERI-KRISS Joint Research Center at RIPF Building
affiliated government. He also expected that the KAERI-KRISS
of KAERI
participated in this meeting, which has been held in both arranged in Korea. Prof. Sung-Min Choi from KAIST, who is joint research project would be a model for effective and
countries every other year. There were thirty oral presentations the President of the Korean Neutron Beam Users Association, successful cooperation among government supported research
The mutual agreement to produce cer tified reference
(sixteen from Japan, fourteen from Korea) and twenty-six made the welcoming remarks. Dr. Kenji Nakajima from J-PARC institutes. A Certified Reference Material (CRM) is a particular
materials using a research reactor will soon be fulfilled with
poster presentations (seven from Japan, nineteen from Korea). reported on the recent Japan-Korea collaborative activities on form of measurement standards. CRMs are very important for
the establishment of a Joint Research Center by KAERI and
Recognition should go to Dr. Kenji Nakajima of J-PARC, and neutron research. Dr. Toshiji Kanaya from J-PARC, Dr. Shuich

4 2016 newsletter Spring Vol. 6 5


analytical chemistry and clinical analysis, and are used for enhance the production of reference materials as required. It was Kimyung Song
various purposes, even for determining environmental pollution. noted that the NAA together with IDMS (Isotopic Dilution Mass 2016 HANARO Winter School, INTEC, Postdoctoral Researcher,
Neutron Science Division
To this end, it is absolutely necessary to produce certified Spectrometry) can evaluate the accuracy of other analytical
KAERI from 22nd to 26th February 2016 kmsong@kaeri.re.kr
reference materials. KAERI's NAA (Neutron Activation Analysis) methods. In this connection, the CIPM (Le Comité International
facilities of HANARO can contribute to this purpose. des Poids et Mesures: International Committee for Weights and
The HANARO Winter School for on Advanced Neutron Diffraction excellent research results. For effective practice, thirty-eight
The NAA method is widely used in many advanced countries Measurements) fully recognized the NAA as the primary method
Data Analysis using the FullProf Suit was held at INTEC for five students were selected to participate in the HANARO Winter
around the world for developing and producing CRMs and for for a quantitative chemical analysis of the elements.
nd th
days between 22 February and 26 February, 2016. As part School based on their research plans.
quality control and assurance. However, Korea is still a far way KAERI and KRISS plan to jointly develop advanced technologies
of the training courses for the HANARO Winter School, the A survey conducted among students at the end of the HANARO
off from applying the method to develop the necessary CRMs. for a state-of-the art measurement and analysis through
Neutron Science Division invited Dr. Juan Rodriguez Carvajal of Winter School showed that they were greatly satisfied with the
In this regard, the establishment of the KAERI-KRISS Joint amalgamating inherent technologies that the two institutes have
the Institut Laue-Langevin (ILL) in France, who is the author of analysis instruction and methods, lectures, and instructors. Still,
Research Center will indeed be a good momentum to further established in the past.
the FullProf Suite. Dr. Carvajal is a globally recognized expert students found certain details of the lectures to be somewhat
in neutron diffraction who served as the Head of the Diffraction difficult. As for the lecture and practice hours, the students
Group in ILL between March 2006 and October 2013. He is overall were relatively satisfied with the format through which
currently participating in the project of developing the European lectures took place in the morning with practice taking place in
Spallation Source (ESS), a new neutron facility in Europe. the afternoon and at night for the five days of the training period.
The HANARO Winter School, led by Dr. Seongsu Lee and Some students advocated for the expansion of practice hours.
Dr. Kimyung Song of the Neutron Science Division under the All students indicated that they were willing to recommend
Sung-Taek Hong
Senior Researcher, guidance of Dr. Juan Rodriguez Carvajal, offered insightful the HANARO course to their colleagues. As for other needs
HANARO Management
lectures on how to analyze and conduct research on neutron or suggestions, many students proposed that the course add
Low-Power Research Reactor Workshop Division
hong79@kaeri.re.kr diffraction using the FullProf Suite, and provided students with an training on an analysis of the magnetic structure.
opportunity to practice the analysis of neutron diffraction results. The 2016 HANARO Winter School is expected to offer great
The HANARO Winter School aimed at providing the users of help to researchers from academia, industry, and government
In this workshop, Dr. In-Cheol Lim (KAERI) presented "Conceptual
HANARO tools to analyze neutron powder diffraction: obtaining institutes in conducting research on energy materials using
design of a hybrid low power RR". Prof. Dongseong Sohn (UNIST),
fundamental knowledge including peak indexing and improving neutron powder diffraction as well as analyzing neutron
Prof. Gyun-Young Heo (Kyung Hee Univ.) and Prof. Ji-Hwan
the ability to analyze neutron diffraction results through practice. diffraction data. In the future, the Neutron Science Division plans
Jeong (Pusan National Univ.) also presented the performance
The HANARO Winter School was also intended to introduce to invite Korean and international experts in neutron scattering
results of the Research Reactor New Technology Development
advanced neutron diffraction analysis methods such as rigid- and expand training opportunities for neutron utilization and
project.
body constraints/AMPLIMODES so that users can apply them analysis, helping stimulate the use of HANARO.
In particular, Dr. Danas Ridikas, who is Research Reactor Officer
to an actual analysis of neutron diffraction results and produce
of IAEA (International Atomic Energy Agency), presented "Needs
on Low Power Research Reactor in view of characteristics and
utilization" at this workshop. Prof. Cheol-Ho Pyeon (Kyoto Univ.
Research Reactor Institute, Japan), Dr. Sang-Yong Shim (Bechtel
Corporation, USA) and Prof. Myeong-Hyeon Kim (Kyunghee
st
On the 1 of February, 2016, the Low-Power Research Reactor Univ.) shared their operation and regulatory experiences with

Workshop sponsored by Advanced Research Center for Nuclear international and domestic research reactor facilities.

Excellence (ARCNEX) was held at the International Nuclear Many researchers who worked on the ARCNEX project were

Education and Training Center (INTEC) at KAERI. interested in other institution’s project results. The Kijang and

The members of the Research Reactor New Technology Jordan research reactor project members were also interested in

Development project (KAERI, UNIST, Pusan National Univ. and this workshop.

Kyung Hee Univ.) presented the results of their work, which was Through the workshop, the participants learned that many

carried out jointly. countries have considered the introduction of a low-power


The 2016 HANARO Winter School Dr. Juan Rodriguez Carvajal Lecturing on the FullProf Suite
The participants had an opportunity to share the experience in research reactor, but actual on-going projects were found to be

low-power research reactor research of domestic and foreign limited.

experts. In addition, a variety of applications including education and

The Research Reactor New Technology Development project is training, taking advantage of a variety of secure, safe and optimal

a project receiving financial support for a total research period of models through the "Graded Approach," confirmed the direction

five years from 2011 from the NRF (National Research Foundation of low-power research reactors.

of Korea).

6 2016 newsletter Spring Vol. 6 7


Publishing Organization_ Korea Atomic Energy Research Institute Publisher_ Jong-Kyung Kim Editor_ Hoan-Sung Jung
8 Editorial Board_ Jong-Sub Woo, Yong-Sam Chung, Hyon-Soo Han, Jeong-Soo Lee, In-Hwan Oh, Pyung-Hoon Choi Published Date _ May 9, 2016

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