P [Kpa] X1 Y1 X2 Y2 γ1* γ2* ln γ1* ln γ2* (GE/RTx1x2)*

P2 sat. 19.953 0 0 1 1 ꚙ 1 ꚙ 0 ꚙ
39.223 0.1686 0.5714 0.8314 0.4286 1.57198438 1.01338565 0.45233876 0.01329686 0.622935049
42.984 0.2167 0.6268 0.7833 0.3732 1.47028545 1.02638934 0.38545656 0.02604715 0.612292271
48.852 0.3039 0.6943 0.6961 0.3057 1.31984693 1.07522153 0.27751577 0.07252671 0.637325489
52.784 0.3681 0.7345 0.6319 0.2655 1.24552668 1.11150204 0.21955848 0.10571229 0.634641258
56.652 0.4461 0.7742 0.5539 0.2258 1.16268199 1.15744301 0.15072939 0.14621327 0.599882794
60.614 0.5282 0.8085 0.4718 0.1915 1.09718365 1.23303551 0.09274658 0.20947902 0.593170629
63.998 0.6044 0.8383 0.3956 0.1617 1.04970234 1.31102791 0.04850664 0.27081149 0.570682036
67.924 0.6804 0.8733 0.3196 0.1267 1.03097269 1.34953731 0.03050272 0.2997618 0.536007314
70.229 0.7255 0.8922 0.2745 0.1078 1.02132989 1.38224394 0.02110559 0.32370822 0.523073772
72.832 0.7776 0.9141 0.2224 0.0859 1.01247532 1.4098484 0.01239815 0.34348218 0.497467973
P1 sat. 84.562 1 1 0 0 1 ꚙ 0 ꚙ ꚙ

0.5

0.4

0.3
LN gama1
LN Gama 2
0.2
Poly. (LN gama1)
Poly. (LN Gama 2)
0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

-0.1
GE GE/RTX1X2 LNγ₁ γ₁ LNγ₂ γ₂ GE/RT
0 0.68 0.68 1.97387773 1 0
-264.293265 0.65628921 0.44476534 1.56012405 0.0218634 1.02210415 0.09199471
-200.210604 0.64982492 0.38508682 1.46974192 0.03540972 1.03604411 0.110302
-148.63022 0.63842486 0.28814271 1.33394766 0.06721914 1.06952983 0.13505545
-125.936003 0.63028409 0.22674602 1.2545112 0.09612056 1.10089178 0.14660559
-104.623341 0.62066852 0.16374325 1.17791184 0.13689761 1.14671073 0.15336396
-85.8266892 0.61085944 0.11065267 1.11700687 0.18590512 1.20430799 0.15222908
-70.1901707 0.60202868 0.07253931 1.07523507 0.23642601 1.26671383 0.14394544
-5.6432414 0.59347181 0.04403041 1.04501413 0.29116608 1.33798677 0.12905391
-47.3525928 0.58850802 0.03108168 1.03156976 0.32553042 1.38476496 0.11720123
-38.0124494 0.58287618 0.01937906 1.01956806 0.36684034 1.44316748 0.10080158
0 0.56 1 0.56 1.7506725 0

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.2 0.4 0.6 0.8 1 1.2
P[Kpa] X1 Y1
19.953 0 0
39.223 0.1686 0.5714
42.984 0.2167 0.6268
48.852 0.3039 0.6943
52.784 0.3681 0.7345
56.652 0.4461 0.7742
60.614 0.5282 0.8085
63.998 0.6044 0.8383
67.924 0.6804 0.8733
70.229 0.7255 0.8922
72.832 0.7776 0.9141
84.562 1 1

90

80

70

60

50

40

30

20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
Consistencia termodinamica.

δ(LN(γ₁/γ₂) δ(GE/RT)
0
-0.0161399 0.00467539
-0.0097323 0.00637083
0.0159345 0.00023257
0.01677927 -0.00101349
0.0223295 0.00513605
0.0414 0.00440814
0.0584181 0.007495
0.0221234 0.01249599
0.0081538 0.01303121
-0.01637724 0.01477034
0
0.0119141 0.0056335 promedio
 componente X1 X1 azeotropo X1 X1 X1 X1
1 acetona 0.25 0.345 0.5 0.75 0 1
2 cloroformo 0.75 0.655 0.5 0.25 1 0
RTLnγ1 -334.153125 -242.9564851 -130.25535 -27.99955 -667.0786 0
RTLnγ2 -46.2567 -84.78821242 -166.76965 -334.153125 0 -521.0214
γ1 0.60773927 0.700707533 0.82355497 0.95913051 0.37001938 1
γ2 0.9333821 0.878279885 0.7799308 0.60773927 1 0.46001327

componente X1 X1 azeotropo X1 X1 X1 X1
1 acetona 0.25 0.345 0.5 0.75 0 1
2 cloroformo 0.75 0.655 0.5 0.25 1 0
lnγ1 -0.48055869 -0.342970747 -0.18951413 -0.04304593 -0.99413635 0
lnγ2 -0.06970722 -0.128470492 -0.24123364 -0.48201016 0 -0.77660251
γ1 0.61843778 0.709658971 0.82736102 0.9578674 0.37004289 1
γ2 0.93266684 0.879439512 0.78565804 0.61754079 1 0.45996609

componente X1 X1 azeotropo X1 X1 X1 X1
1 acetona 0.25 0.345 0.5 0.75 0 1
2 cloroformo 0.75 0.655 0.5 0.25 1 0
lnγ1 -0.74728957 -0.5513251 -0.2817163 -0.0438353 -0.99413635 0
lnγ2 -0.06570266 -0.11207461 -0.1937826 -0.37055008 0 -0.6102741
γ1 0.4736486 0.576185783 0.7544876 0.95711153 0.37004289 1
γ2 0.93640926 0.893977554 0.823836 0.69035448 1 0.54320193
x interacion ᴧ ij ᴧ jj ᴧ ii
0.3333333 12 1.20101 0 0
0.3333333 13 0.86494 0 0
0.3333333 23 0.7704 0 0

1.31365127 1 0 0.80438423 0.52888913

0.4198379 1 0.38153278 0 0.47111087

0.60673098 1 0.61846722 0.19561577 0

0.98037791 ɣ1= 2.66546336 1

0.56719426 ɣ2= 1.76331271 1
0.79264798 ɣ3= 2.20923872 1

A B C T P PB

16.6513 2940.46 -35.93 328.15 726.917385 1909.24363

18.9119 3803.98 -41.68 328.15 279.525199

16.0828 2511.29 -41.95 328.15 1492.491

 Ki xi F pr
103.378982 0.1812981 1.0005243
26.2981247 0.71269013
175.925521 0.10653607
ɣ Ki Xi F pr
2.6654633 103.378982 0.18129811 1.0005243
componente A B C T°K P°i
1.76331271 26.298124 0.71269013
acetona 16.6513 2940.4 -35.93 328.15 726.917385
2.2092387 175.92552 0.106536
etanol 18.9119 3803.98 -41.68 328.15 279.525199
eter etilico 16.082 2511.29 -41.95 328.15 1492.491