Valoracion de Cd2+ con EDTA Valoracion de Cu2+ con EDTA

Kf= pCd2+ [Cd2+] Phi V[Y4-] kf= pCu2+ [Cu2+] Phi V[Y4-]
2.884032E+16 2 1.00E-02 0.0 0 6.30957E+18 2 1.00E-02 0.0 0
Vo= 3 1.00E-03 0.891 0.8911 V=o
3 1.00E-03 0.891 0.891
10 4 1.00E-04 0.989 0.989 10 4 1.00E-04 0.989 0.989
Co(Cd2+) = 5 1.00E-05 0.999 0.9989 Co(Cu )=2+
5 1.00E-05 0.999 0.999
0.01 6 1.00E-06 1.000 1 0.01 6 1.00E-06 1.000 1.000
Co(EDTA) = 7 1.00E-07 1.001 1.0009 Co(EDTA)= 7 1.00E-07 1.000 1.000
0.1 8 1.00E-08 1.009 1.0094 0.1 8 1.00E-08 1.000 1.000
aY =4- 8.5 3.16E-09 1.030 1.0296 aY =4- 8.5 3.16E-09 1.000 1.000
3.70E-07 9 1.00E-09 1.094 1.0937 3.70E-07 9 1.00E-09 1.000 1.000
kf'= 9.5 3.16E-10 1.296 1.2963 Kf'= 10 1.00E-10 1.004 1.004
1.07E+10 9.8 1.58E-10 1.591 1.5913 2.33E+12 11 1.00E-11 1.043 1.043
C3=10^-B4 10 1.00E-10 1.937 1.9371 H4=10^-G4 11.5 3.16E-12 1.135 1.135
A13=A4*A12 10.1 7.94E-11 2.180 2.1798 F14=F4*F12 11.9 1.26E-12 1.340 1.340
D4=(1+ 10.2 6.31E-11 2.485 2.4852 I4=(1+ 12.2 6.31E-13 1.679 1.679
$A$14*C4- 10.3 5.0119E-11 2.870 2.8698 $F$14*H4- 12.3
(H4+ 5.0118723E-13 1.855 1.855
(C4+
(C4)^2*$A$14) 10.4 3.9811E-11 3.354 3.354 (H4)^2*$F$1 12.4 3.9810717E-13 2.076 2.076
/$A$8)/ 10.5 3.1623E-11 3.963 3.9635 4)/$F$8)/ 12.5 3.1622777E-13 2.355 2.355
($A$14*C4+ ($F$14*H4+
(H4+ 12.6 2.5118864E-13 2.705 2.705
(C4+
(C4)^2*$A$14) (H4)^2*$F$1 12.7 1.9952623E-13 3.147 3.147
/$A$10) 4)/$F$10)

E4=D4*$A$8*$ E4=I4*$F$8*
A$6/$A$10 $F$6/$F$10

14

12

10

8
pM

0
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0
mL EDTA
Curva de Valoracion Cd Curva de Valoracion Cu