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SISTEMA Fe S - O

REACTIONS Cal/mol
427 C 650 C 750 C
Fe 0 0 0
2Fe + 1.5 O2(g) ->Fe2O3 -151645 -138221 -132308
3Fe + 2 O2(g)->Fe3O4 -210324 -194184 -187103
Fe + 0.5 S2(g) -> FeS -24837 -24510 -23135
Fe + S2(g) ->FeS2 -32759 -27699 -22998
2Fe +1.5 S2(g) + 6 O2(g)->Fe2(SO4)3 -435617 -375094 -344545
0.5 S2(g) + O2(g) ->SO2(g) -71565 -70379 -68643

G / cal
REACTIONS 427 C 650 C 750 C
1 2 Fe + 1.5 O2(g) -> Fe2O3 -151645.4 -138221.4 -132307.9
2 3 Fe + 2 O2(g) -> Fe3O4 -210324.1 -194184.0 -187103.1
3 Fe + SO2(g) -> O2(g) + FeS 46728.3 45868.8 45508.0
4 Fe + SO2(g) -> O2(g) + FeS2 110370.9 113058.2 114287.5
5 2 Fe + 3 O2(g) + 3 SO2(g) -> Fe2(SO4)3 -220922.1 -163957.8 -138617.2
6 1.5 Fe2O3 -> 0.25 O2(g) + Fe3O4 17144 13148.1 11358.75
7 0.5 Fe2O3 + 1 SO2(g) -> 1.75 O2(g) + FeS 122551 114979.5 111661.95
8 0.5 Fe2O3 + 2 SO2(g) -> 2.75 O2(g) + FeS2 186193.6 182168.9 180441.45
9 Fe2O3 + 1.5 O2(g) + 3 SO2(g) -> Fe2(SO4)3 -69276.7 -25736.4 -6309.3
10 1/3 Fe3O4 + SO2(g) -> 5/3 O2(g) + FeS 116836.333 110596.8 107875.7
11 1/3 Fe3O4 + 2 SO2(g) -> 8/3 O2(g) + FeS2 180478.933 177786.2 176655.2
12 2/3 Fe3O4 + 5/3 O2(g) + 3 SO2(g) -> Fe2(SO4)3 -80706.033 -34501.8 -13881.8
13 FeS + SO2(g) -> O2(g) + FeS2 63642.6 67189.4 68779.5
14 2 FeS + 5 O2(g) + SO2(g) -> Fe2(SO4)3 -314378.7 -255695.4 -229633.2
15 2 FeS2 + 7 O2(g) -> SO2(g) + Fe2(SO4)3 -441663.9 -390074.2 -367192.2

SISTEMA Pb S - O

Cal/mol
REACTIONS 827 C 700 C 750 C 950 C
Pb 0 0 0 0
Pb + 0.5 O2(g) -> PbO -26141 -29124 -27944 -23634
2 Pb + 0.5 S2(g) + 2.5 O2(g) -> PbO*PbSO4 -152642 -168330 -162121 -137724
3 Pb + 0.5 S2(g) + 3 O2(g) -> *2PbO*PbSO4 -181711 -200496 -193062 -163829
5 Pb + 0.5 S2(g) + 4 O2(g) -> *4PbO*PbSO4 -235058 -259550 -249856 -211767
Pb + 0.5 S2(g) -> PbS -15773 -18453 -17395 -13204
Pb + 0.5 S2(g) + 2 O2(g) -> PbSO4 -120300 -133177 -128079 -108365
0.5 S2(g) + O2(g) -> SO2(g) -67309 -69510 -68643 -65184
G / cal
REACTIONS 827 C 700 C 750 C 950 C
1 Pb + 0.5 O2(g) -> PbO -26141.3 -29123.5 -27944.3 -23633.5
2 2 Pb + 1.5 O2(g) + SO2(g) -> PbO*PbSO4 -85332.8 -98819.8 -93477.9 -72540.1
3 3 Pb + 2 O2(g) + SO2(g) -> *2PbO*PbSO4 -114401.9 -130986.0 -124419.5 -98644.6
4 5 Pb + 3 O2(g) + SO2(g) -> *4PbO*PbSO4 -167749.1 -190039.9 -181212.8 -146583.4
5 Pb + SO2(g) -> O2(g) + PbS 51536.2 51056.9 51248.0 51980.2
6 Pb + O2(g) + SO2(g) -> PbSO4 -52991.3 -63666.6 -59436.4 -43180.6
7 2 PbO + 0.5 O2(g) + SO2(g) -> PbO*PbSO4 -33050.2 -40572.8 -37589.3 -25273.1
8 3 PbO + 0.5 O2(g) + SO2(g) -> *2PbO*PbSO4 -35978.0 -43615.5 -40586.6 -27744.1
9 5 PbO + 0.5 O2(g) + SO2(g) -> *4PbO*PbSO4 -37042.6 -44422.4 -41491.3 -28415.9
10 PbO + SO2(g) -> 1.5 O2(g) + PbS 77677.5 80180.4 79192.3 75613.7
11 PbO + 0.5 O2(g) + SO2(g) -> PbSO4 -26850.0 -34543.1 -31492.1 -19547.1
12 1.5 PbO*PbSO4 -> 0.25 O2(g) + 0.5 SO2(g) + *2PbO*PbSO4 13597.3 17243.7 15797.4 10165.6
13 2.5 PbO*PbSO4 -> 0.75 O2(g) + 1.5 SO2(g) + *4PbO*PbSO4 45582.9 57009.6 52482.0 34766.9
14 0.5 PbO*PbSO4 + 0.5 SO2(g) -> 1.75 O2(g) + PbS 94202.6 100466.8 97987.0 88250.3
15 0.5 PbO*PbSO4 + 0.25 O2(g) + 0.5 SO2(g) -> PbSO4 -10324.9 -14256.7 -12697.5 -6910.6
16 5/3 *2PbO*PbSO4 -> 1/3 O2(g) + 2/3 SO2(g) + *4PbO*PbSO4 22920.7 28270.1 26153.0 17824.3
17 1/3 *2PbO*PbSO4 + 2/3 SO2(g) -> 5/3 O2(g) + PbS 89670.2 94718.9 92721.2 84861.7
18 1/3 *2PbO*PbSO4 + 1/3 O2(g) + 2/3 SO2(g) -> PbSO4 -14857.3 -20004.6 -17963.2 -10299.1
19 0.2 *4PbO*PbSO4 + 0.8 SO2(g) -> 1.6 O2(g) + PbS 85086.0 89064.9 87490.6 81296.9
20 0.2 *4PbO*PbSO4 + 0.4 O2(g) + 0.8 SO2(g) -> PbSO4 -19441.5 -25658.6 -23193.8 -13863.9
21 PbS + 2 O2(g) -> PbSO4 -104527.5 -114723.5 -110684.4 -95160.8

SISTEMA Ni S - O
Cal/mol
REACTIONS 500 C 700 C 800 C 900 C

Ni + 0.5 O2(g) -> NiO -40.262 -36.067 -33.991 -31.926


Ni + 0.5 S2(g) -> NiS -20.138 -16.507 -14.732 -12.988
Ni + S2(g) -> NiS2 -28.372 -19.985 -15.848 -11.748
3Ni + S2(g) -> Ni3S2 -48.874 -42.937 -40.676 -38.933
Ni + 0.5 S2 + 2 O2(g) -> NiSO4 -140.893 -119.978 -109.638 -99.373
0.5 S2(g) + O2(g) -> SO2(g) -72.991 -69.510 -67.776 -66.047
G / cal
REACTIONS 500 C 700 C 800 C 900 C
1 Ni + 0.5 O2(g) -> NiO -40261.6 -36067.2 -33990.7 -31925.5
2 Ni + SO2(g) -> O2(g) + NiS 52852.6 53003.6 53044.1 53058.7
3 Ni + 2 SO2(g) -> 2 O2(g) + NiS2 117608.8 119035.6 119705.0 120346.7
4 3 Ni + 2 SO2(g) -> 2 O2(g) + Ni3S2 97107.0 96083.4 94876.4 93161.0
5 Ni + O2(g) + SO2(g) -> NiSO4 -67902.0 -50467.9 -41861.3 -33326.0
6 NiO + SO2(g) -> 1.5 O2(g) + NiS 93114.2 89070.8 87034.8 84984.2
7 NiO + 2 SO2(g) -> 2.5 O2(g) + NiS2 157870.4 155102.8 153695.7 152272.2
8 3 NiO + 2 SO2(g) -> 3.5 O2(g) + Ni3S2 217891.8 204285.0 196848.5 188937.5
9 NiO + 0.5 O2(g) + SO2(g) -> NiSO4 -27640.4 -14400.7 -7870.6 -1400.5
10 NiS + SO2(g) -> O2(g) + NiS2 64756.2 66032.0 66660.9 67288.0
11 3 NiS + O2(g) -> SO2(g) + Ni3S2 -61450.8 -62927.4 -64255.9 -66015.1
12 NiS + 2 O2(g) -> NiSO4 -120754.6 -103471.5 -94905.4 -86384.7
13 3 NiS2 + 4 O2(g) -> 4 SO2(g) + Ni3S2 -255719.4 -261023.4 -264238.6 -267879.1
14 NiS2 + 3 O2(g) -> SO2(g) + NiSO4 -185510.8 -169503.5 -161566.3 -153672.7
15 1/3 Ni3S2 + 5/3 O2(g) + 1/3 SO2(g) -> NiSO4 -100271.0 -82495.7 -73486.8 -64379.7