I)VAN DER WAALS

*Calculando las ctes. De Van der Waals del aire

Cte.Van der Waals

Gas a b %Xi
O2 1.36 0.03183 0.21
N2 1.39 0.0391 0.79

= 2 2 + 2 2

= (0.21)(1.36) + (0.79)(1.39)=1.3837

= 2 2 + 2 2

= (0.21)(0.03183) + (0.79)(0.0391) = 0.036713

*Volmenes molares idealesinicales

a=1.3837 (atm*L^2/mol^2)
R=0.08206 atm*litro/mol-K
T=298.15K
Vmi=R*T/P

Presion Vmideal=R*T/P
1 24.466189
1.5 16.31079267
2 12.2330945
2.5 9.7864756
3 8.155396333
3.5 6.990339714
4 6.11654725
4.5 5.436930889
5 4.8932378

*Calculando el volumen molar con Newton-Raphson

 ()
+1 =
()

F(Vm)=Vm^3-(b+R*T/P)*Vm^2+(a/P)*Vm-a*b/P

F'(Vm)=3*Vm^2-2*(b+R*T/P)*Vm+a/P

Calculando las iteraciones con ayuda del Microsoft Excel

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

1atm, 2.75E-3 L 1 24.466189 11.8268696 598.18165 0.019771368 24.44641763
2 24.4464176 0.01910593 596.249354 3.20435E-05 24.44638559
3 24.4463856 5.0145E-08 596.246224 8.41018E-11 24.44638559

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

1.5atm, 2.05E-3 L 1 16.3107927 5.24509764 265.766788 0.019735715 16.29105695
2 16.291057 0.01268407 264.481785 4.79582E-05 16.29100899
3 16.291009 7.4808E-08 264.478665 2.8285E-10 16.29100899

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

2atm, 1.75E-3 L 1 12.2330945 2.94401745 149.442224 0.019700038 12.21339446
2 12.2133945 0.00947323 148.480865 6.3801E-05 12.21333066
3 12.2133307 9.9201E-08 148.477755 6.6812E-10 12.21333066

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

2.5atm, 1.55E-3 L 1 9.7864756 1.88010719 95.6100029 0.019664336 9.766811264
2 9.76681126 0.00754679 94.8428287 7.95715E-05 9.766731693
3 9.76673169 1.2332E-07 94.839729 1.30032E-09 9.766731692

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

3atm,1.35E-3 L 1 8.15539633 1.30280778 66.3729046 0.019628609 8.135767725
2 8.13576772 0.00626255 65.7351853 9.52694E-05 8.135672455
3 8.13567246 1.4717E-07 65.7320957 2.23897E-09 8.135672453
-5.7277E-
4 8.13567245 14 65.7320956 -8.71372E-16 8.135672453
Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1
3.5atm, 1.2E-3 L 1 6.99033971 0.95509144 48.7469195 0.019592857 6.970746857
2 6.97074686 0.00534529 48.2016668 0.000110894 6.970635963
3 6.97063596 1.7075E-07 48.1985873 3.54268E-09 6.970635959
-1.9469E-
4 6.97063596 14 48.1985872 -4.03929E-16 6.970635959

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

4atm, 1.07E-3 L 1 6.11654725 0.72965439 37.3089617 0.019557081 6.096990169
2 6.09699017 0.00465738 36.8330579 0.000126446 6.096863723
3 6.09686372 1.9406E-07 36.8299884 5.26914E-09 6.096863718

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

4.5atm, 0.95E-3 L 1 5.43693089 0.57526273 29.4684943 0.01952128 5.417409609
2 5.41740961 0.00412239 29.0465275 0.000141924 5.417267685
3 5.41726769 2.171E-07 29.0434681 7.47509E-09 5.417267678
-7.3951E-
4 5.41726768 15 29.0434679 -2.54623E-16 5.417267678

Presin,Volumen Iteracin i Vmi F(Vmi) F'(Vmi) F(Vmi)/F'(Vmi) Vmi+1

5atm, 0.87E-3 L 1 4.8932378 0.46494682 23.8612253 0.019485454 4.873752346
2 4.87375235 0.00369442 23.4824072 0.000157327 4.873595018
3 4.87359502 2.3987E-07 23.4793579 1.02164E-08 4.873595008
4 4.87359501 4.4912E-15 23.4793577 1.91283E-16 4.873595008

Presin Vmreal(L/mol)
1 24.44638559
1.5 16.29100899
2 12.21333066
2.5 9.766731692
3 8.135672453
3.5 6.970635959
4 6.096863718
4.5 5.417267678
5 4.873595008
*Hallandola constante de Boyle

P1V1=P2V2=..K

K=(#moles)*R*T

#moles=Volumen/VolumenMolar

Presin(atm) Volumen(L) Vmreal(L/mol) #moles=V/Vmreal K=n*R*T

1 0.00275 24.44638559 0.000112491 0.002752228
1.5 0.00205 16.29100899 0.000125836 0.003078734
2 0.00175 12.21333066 0.000143286 0.003505664
2.5 0.00155 9.766731692 0.000158702 0.003882833
3 0.00135 8.135672453 0.000165936 0.004059819
3.5 0.0012 6.970635959 0.000172151 0.004211872
4 0.00107 6.096863718 0.0001755 0.004293818
4.5 0.00095 5.417267678 0.000175365 0.004290517
5 0.00087 4.873595008 0.000178513 0.004367532
Kpromedio= 0.003827002