ECUACION PARA LA CORRELACION DE LAS CONSTANTES DE EQUILIBRIO A PRESION Y TEMPERATURA DADA

VALORES DE LOS
COEFICIENTES
PARA
COMPONENTE
HIDROCARBUROS aT1 aT2 aT3 aT4 aT5 aT6 aP1 aP2 aP3
LIGEROS PARA
Metano
CALCULAR LA c1 -292,860.0000 0 0 0 0 8.24450 -0.89510 59.84650 0
Etileno
CONSTANTE DE c2= -600,076.8750 0 0 0 0 7.90595 -0.84677 42.94594 0
EQUILIBRIO EN
Etano
FUNCION DE LA
c2 -687,248.2500 0 0 0 0 7.90699 -0.88600 49.02654 0
Propileno
PRESION (psia) Y c3= -923,484.6875 0 0 0 0 7.71725 -0.87871 47.67624 0
LA TEMPERATURA -970,688.5625 0 0 0 0 7.15059 -0.76984 0 6.90224
Propano c3
(R)
Isobutano ic4 -1,166,846.0000 0 0 0 0 7.72668 -0.92213 0 0
n-Butano nc4 -1,280,557.0000 0 0 0 0 7.94986 -0.96455 0 0
Isopentano iC5 -1,481,583.0000 0 0 0 0 7.58071 -0.93159 0 0
nPentano nC5 -1,524,891.0000 0 0 0 0 7.33129 -0.89143 0 0
n-Hexano nC6 -1,778,901.0000 0 0 0 0 6.96783 -0.84634 0 0
n-Heptano nC7 -2,013,803.0000 0 0 0 0 6.52914 -0.79534 0 0
n-Octano nC8 0.0000 -7,646.81641 0 0 0 12.48457 -0.73152 0 0
n-Nonano nC9 -2,551,040.0000 0 0 0 0 5.69313 -0.67818 0 0
n-Decano nC10 0.0000 -9,760.45703 0 0 0 13.80354 -0.71470 0 0

a p 4 Ln 2 P a P 5 Ln
aT 1 aT 2 aP 2 aP3
Ln K 2
AT3 Ln T AT4 T AT5T 2
AT6 AP1 Ln P 2

T T P P

aT 1 aT 2 aP2 aP3

k e
2
a T 3 LnT a T 4 T a T 5 T a T 6 a P 1 LnP a P 4 Ln 2 P a P 5 Ln 3 P P
T 2 T P 2 P
e ln K
dk
dT
k
d aT 1 aT 2

dT T 2

T
a a
P

aT 3 LnT aT 4 T aT 5T 2 aT 6 a P 1 LnP P22 P 3 a P 4 Ln 2 P a P 5 Ln 3 P P
P
dk
dT
k
d aT 1 aT 2
dT T 2

T
a T 3 LnT aT 4 T a T 5 T 2
a T 6 a P 1 LnP
aP2
P2

aP3
P
a P 4 Ln 2
P a P
5 Ln 3
P P

dk 2 a T1 a T2 a T3
k 3
2
a T4 2a T5 T
dT T T T
 aP4 aP5 COMPONENTE

0 0 Metano

0 0 Etileno

0 0 Etano

0 0 Propileno

0 0 Propano

0 0 Isobutano

0 0 n-Butano

0 0 Isopentano

0 0 nPentano

0 0 n-Hexano

0 0 n-Heptano

0 0 n-Octano

0 0 n-Nonano

0 0 n-Decano

p4 Ln 2 P a P 5 Ln 3 P P

P
e ln K

P a P 5 Ln 3 P P


P a P 5 Ln 3 P P