COMPLEJOS

Datos
Co= 10-2 0.01 10+7.3= 19952623.15
MOH= 0
KMY= 10-8.7= 0.000000002
YH= 1.4
g= 100= 1
pH= 9
Mg2+ + Y4- MgY2-
Inicio Co
Agregado xCo
A.P.E Co(1-x) 0 xCo
P.E. co co Co
D.PE. 0 Co(x-1) Co

Clculo de K' MY x=0

K'MY= KMY = 10-8.7= 10+7.3 |Mg2+|=Co
Y(H) M(global) 101.4 * 100 pM=logg-logCo
pM=log(10+0)-log10-2
pM= 2

Cuantitatividad Indicador
%q=(1-1/K'MY)*100 A.P.E. 1% Co= 10-4 M= 0.0001
%q=(1-1/10 *10 )*100
7.3 -2 pM=logg-logCo(1-x)
%q= 99.77612789 pM=log100-log10-4
pM= 4

D.P.E 1% Y4-= Co=10-4

MY= Co=10-2
K'MY= |MY| |M'|= |MY|
|M'||Y| |K'MY||Y'|

|M'|= 10-2 = 10-5.3

107.3 * 10-4
 M(OH)= |M'| |M|= |M'|
|M| M(OH)

|M|= 10-5.3 = 10-5.3

10+0

pM=-log10-5.3
pM= 5.3
 COMPLEJOS

x=0.5 x=1 x=1.5

0<x<1 MgY=Co x>1
|Mg2+|= Co(1-x) pM=logg+1/2logK'MY-1/2logCo |Y4-|=Co(x-1)
|MgY|= xCo pM=log10+0+1/2log107.3-1/2log10-2 |MgY2-|=Co
pM=logg-logCo(1-x) pM= 4.65 pM=logg+logK'MY+log(x-1)
pM=log10 -log[10 (1-0.5)]
+o -2
pM=log100+log107.3+log(1.5-
pM= 2.301029996 pM=
 x=2
x>1
|Y4-|=Co(x-1)
|MgY2-|=Co
M=logg+logK'MY+log(x-1) pM=logg+logK'MY+log(x-1)
M=log100+log107.3+log(1.5-1) pM=log100+log107.3+log(2-1)
6.998970004 pM= 7.3
Concentracin de 10--2

X pM Grfica de mL de EDTA vs pM
0 2
8
0.5 2.3
1 4.65 7
1.5 6.99
6
2 7.3
5

4 pM

pM
3

0
0 0.5 1 1.5 2 2.5
mL de EDTA

Concentracin de 101

X pM Grfica de mL de EDTA vs pM
0 -1
0.5 -0.69 8
1 3.15 7
1.5 6.99
6
2 7.3
5

4
pM
pM

0
0 0.5 1 1.5 2 2.5
-1

-2
mL de EDTA
 Concentracin de 10--3

pM X pM Grfica de mL de EDTA vs
0 3
8
0.5 3.3
1 5.15 7
1.5 6.99
6
2 7.3
5

pM 4

pM
3

0
2.5 0 0.5 1 1.5 2
mL de EDTA

pM

pM

2.5
e mL de EDTA vs pM

pM

1 1.5 2 2.5
mL de EDTA