TABLE E.1 Forms: (Q) Ch = a+ MT) + AT + dC) Qh a+KN +aD> Units of C3 are ig molXK oF *C). To convert to eall(e moDXK or °C) = Btu/(1b mody°R or *F), multiply by 0.2390. HEAT CAPACITY EQUATIONS FOR ORGANIC AND INORGANIC COMPOUNDS" Temp. Mol Range Compound Formula = Wi. State Form Ta b-108 +107 Gin) ‘Acetone CH,COCH, 5805. g 1 °C—«7496 20.10 3476 01200 Acetylene CoH 20H g 1 CARA 6.083 1820 0-120 ‘Air 2000 eC RHO =1968 0-150 Bt K 2809011965 =11965 273-1800 Ammonia NH 70300 gL CSS 958 66860-1200 ‘Ammonium sulfate (NHx80. 3215. KS 2189 275-328 Benzene Coils mn 10 1 Kass Bd 279-350 e 1 °C 7406 3295 25.20 ns 0-120 Isobutane Cathie 32 kL C8946 3013 1891 4987 01200 Butane Cathie a2 gt C9230 27.88 1547 3498 0-120 Iobutene Cie SuI0 gL CRAB 2564 17.27 50.50 0-120 Calcium earbige acs suo oe 02K RRB 8.66% 1088 — — eN0 Calcium carbonate CaCO; woo =e 2K R34 ATS AD TxIOVE = 273-1033 Calcium hydroxide Ca(OH) mio © 1 K $95 276-373 Calcium oxide x0 soos ce 2 KB 2.03 4.522100 2173 Carbon c 1201 ct 2 KNB 1.095 4891x1010 273-1373 ‘Carbon dioxide Co: aol gL CSL 4.233 887 7464” 0-1500 ‘Carbon monoxide CO mol g 1 C895 OTTO 013548 2220 _0-1500 Carbon tetrachloride CCl, aed TK 9339 12.98. 273-383 Chlorine a: msg 1 C30 1.367 607 64730-1200 Copper cu se 6 1K 2276 0.06117 21357 Cumene Cos 019g 1 C92 S2.76 39.19 1205 0.1200 (sopropyl benzene) Cylohexane Catia Beg 1 CHM 89.62 =31.50 2063 0.1200 Cylopentane Cotte EE 68.66 0-1200 Ethane Cae sore 1 C937 1382 ~5816 7280 © 0-1200 Ethyl alcoho! CHO aor 11 C03 ° Lo4 1s 100 ge o1 C6134, 182 ~3.169 19.83 0-120 Ethylene CoH mos gL C4075 a7 ~6.891 1766 10-1200 Ferric oxide FeO) 197 6 02 KM 6m =17x1e 4087 Formaldehyde CHO wo gL CB 4.268 0.0000 8694 0.1200 Helium He 400g 01 °C 208 All Hexane Colle wry TL 8 2863 20-100 e 1 °C 174s ass 23.92 57.66 01200 Hydrogen Ms 206g «= 1 C2884 00765 0.3288 018698 0.1500 Hydrogen bromide HBr a2 og 1 "C910 00227 0.9887 48380-1200 Hydrogen chloride HCL say LCN 01341 sus =4335 01200 Hydrogen eyanide HCN m0 og 1 "353 2.908 0-120 Hydrogen sulfide HS co =322 0-150 Magnesium chloride MgClz ya LK OS 138 273.991 Magnesium oxide MgO 432 © 2 K 4844 0.8008 273-2073, Methane He Wot gL CL 5.408 =11.0 0-1200 1K 1987 Soa 1100 273-1500 Methyl alcohol cH,OH 32.04 1 C7886 ° . 8239 £ 0 et °C 4293 8.301 -1.87 803 0-700 Methyl cyclohexane CyHia ms gL CSB SR 37.72 1008 0.1200 Methyl eyelopentane — CeHis Bie gL CRBS BST 3084 381 01200 Nitric acid 60 1 1 %C i100 2s Nitric oxide wool gL C2950 attss_ 0.2925 03552 0.3500 Nitrogen 202g tC 29.00 0.2199 073 -2871 0.1500 Nitrogen dioxide 4601 gL C3607 3.97 01200 Nitrogen tetroxide 02g of C87 RS 0-300 Nitrous oxide Mor gL CG 1037 1200 Oxyeen RO & 1 C10 Lise 130-4300 mPentane MIS 1 1 86 1354 43.68 036 Bot SC Ms 3409 18.99 226 0-120 Propane 44000 g se as. 22.89 13.11 SLL 0-120 Propylene 4208 *cs9s80 1771 10117 460 90-1200 Sodium carbonate ssc 1 KL 288-371 Sodium carbonate 2861S cL CK SBS 298 +GraphiteTABLE [1 HEATS OF FORMATION AND HEATS OF COMBUSTION Standard states of products for AA? are COx(g), Hz0(), Btu/lb mol, multiply by 4306, OF COMPOUNDS ar 25 ct Nate), $0x(8), and HOV aq). To convert to SS —ahy ah ‘Compound Acetic acid ‘Acetaldethyde ‘Acetone Acetylene “Ammonia ‘Ammonium carbonate Formula State (e3/g mol) ‘CH;COOH 7 409.19 ' CHscHo 8 166.4 CsH.0 aq, 200 410.03 © 216.69 Calta ' 226.75 NH ' 6720 e 46.191 (NH).CO5, e aq 941.86 Ca) w1.8 919.73 1192.36 1821.38 1299.61 382.88 ‘Ammonium chloride NHAC € 3138 —eer SSS eee”: Compound ‘Amoniom hydronide ‘Ammonium nitrate Ammonium sulfate Benzaldehyde Benzene Boron oxide Bromine Butane Trobutane 1Butene (Calcium arsenate Calcium carbide Calcium carbonate Calcium chloride Calcium cyanamide Calcium hydroxide Calcium oxide Calcium phosphate Calcium silicate Calcium sulfate Calcium sulfate (gypsum) Carbon Carbon dioxide Carbon disulfide ooroethane 2umene (isopropylbenzene) Dupri sulfate 2yelohexane ~aAy — — aA? Formula State (siamo!) (ki/gmoty NH.OH aa 3665 NHWNO, e z 4 (NH):804 e aq CéltsCHO, I ® Cite ' 32676 * ® —82927 301.5 B05 e Ir Bry 1 ® Cathie ' 5 Cathie r ® Cotte ' CAA: € Cay € Caco, © ach € CaCNy e Ca(OH), © cao e Cay(PO0): « GaSio, e Caso, e aq CaS04-2H1:0 c c © 0 393.51 Graphite (A) coy ® 303.51 ' anz92 cs: It 8186 10752 8 -153 11026 co . 11032 242.99 cc t Les 3522 ® 10669 384.9 CHCl ® 1080 14at. CoH,CH(CH,) ' 41200 s71s.44 . =393 5260.59 CuSO, € 769.86 a 43.12 CoHlis 1 1562 3919.9 pawoqut ‘UH 20U0}45 Bs é \ es z= E £8 PPPS SsEe B82 over 09°38 cooI-0 wsi-0 zg geee £ a gees § EL ae z ose & 2885 S Bses ¢ 2 o8sk & eerie sror 26E-896 prayed 101-2 201 £ wor ams aM ejnunog. punodwo3 Ow - or uu stung, dup@)1OH aves preps yf 230 wyep Jo sSn:N05, "Spur 'y “| ssouatajey ‘cr mpuaddy jo Suruuitoq ogi ve 3 109 TON PROP uaBORN £ oes ue 3 oor ON 3p OUTIN, 3 be 1 UK ! zoo ‘ont ioe umn 3 : me i Ost s suUadoIaK [Ayryy 1 =i i zar'es 2 : ‘ros 1 re 3 ' qi wore i eres SHH a is09t be 2 zor 1 50°86 vost 2 3 59008 fos 2 3 3909 Fos > 1 soset sis > (eunpouow) 3 2 3 uquio4s) 2 2 s : oan spONG UaBOID KH, > rosN, ! > FONEN 1 aumdoqw 3 SONEN ‘ spyepreatioy > NOEN > puns sno 4 Pee & 3prt0 snoxze, a om 7 spuoR snouieg > POSHEN 2 2pnv0 aunojos03z04 2 SOHN spurns uo puns aura > fos spHOIp wooKs 2 soe oye, 5 > spun asso i SHOTHO- HYD auacuagisdosga 3 3 Ot rogoat iSdoug-e 1 went ne : "uf ovate 2 spun 28o(cur 3 a : a i ave ore) suedoig 3 snow Han 2 S6lrt 50d epporud sxsoyssoug 3 2 osect ‘a seuoudsogd 1 seg ug Compe 8 2 00786 roa‘ PI stogdsou. 1 royoore anar : : aang 1 siz Ht, surieage 3 3 wove ON appeo snot, t suruador ss TOW nO Punoawo.y Gomsie) Yow sir) arms unodwoy tv tv suv~ tev(005'905 656706 be s8e368 be ZSU's68 be nom op aD Of OT OH S00 vost OH = SeeeeeTTeTarag eregzzEs gegeg Wesel ‘cess sre ouLsot 819 991 HOW 566° i 06-991 be 8H ond ———_Serr Oto tie (low 8/e) (ow sje) ais onduomq ——ynmaog domain) — ais ends ——enusnog. Nev “vty 4av— ———. ———_____ 4uV: bs seal (002) ew aneve a 9.8% LV NOULATIG QNY NOLLNIOS 40 SLVIH IWHOALNI FH THevL (avjqjoumissHla) LiCi(s) Figure 13.7 Heats of solution af 25°C. (Based on data, suppl 2.1982) SMITH Y VAN NESS 0 20 30 0 4 moles H0/mole of solute ‘80-100 00 300400600. $00 1000 Srom “The NBS Tables of Chemical Thermodynamic Properties” J. Phys. Chem. Ref. Data, vol 300 10 § os 3 « g B06 fe v3 BE os Bk ged | ECE EL ooLel | i i i o ma © © Weighs percent Hesou Figure P9.2¢0 Figuea P9280 Freezing Point of Sulfurid Acid Solutions Vapor Pressure of le, : Wi% S04 nc mm Hg nC oe o ° 438 ° 0 -s 19s 10 20 5 0.76 -20 30 -35 0.286 -30 40 -a 0.0966 40 50 =35 a Model 4 Reid 20 <0 oo ‘80 Weight per cent Hesos An Final solution