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1Medicin y unidades
2Presin de vapor y punto de ebullicin de un lquido
3Variacin de la presin de vapor con la temperatura
4Importancia para el Derecho Ambiental
5Vase tambin
Medicin y unidades[editar]
La presin de vapor es medida en unidades estndar de presin. El Sistema Internacional de
Unidades (SI) reconoce la presin como una unidad derivada de la fuerza ejercida a travs de
un rea determinada; a esta unidad se le conoce por el nombre de pascal (Pa). Un pascal es
equivalente a un newton por metro cuadrado (Nm-2 kgm-1s-2).
La medicin experimental de la presin de vapor es un procedimiento simple para presiones
similares que estn entre 1 y 200 kPa. Resultados ms exactos son obtenidos cerca del punto
de ebullicin de cada sustancia en particular y con ndice de error ms significativo en
mediciones menores a 1 kPa. Con frecuencia, algunos procedimientos consisten en purificar
las sustancias que son analizadas, aislando la sustancia deseada en un contenedor, evitando
cualquier gas indeseado y midiendo la presin de equilibrio de la fase gaseosa de la sustancia
en el sistema cerrado a distintas temperaturas. El uso de herramientas, como un isoteniscopio,
genera una mayor exactitud en el proceso.
Vapor pressure
From Wikipedia, the free encyclopedia
The picture shows the particle transition, as a result of their vapor gas,
from the liquid phase to the gas phase and converse.
The "Pistol Test Tube" experiment. The tube contains alcohol and is
closed with a piece of cork. By heating the alcohol, the vapors fill in the
space, increasing the pressure in the tube to the point of the cork popping
out.
Vapor pressure or equilibrium vapor pressure is defined as the pressure exerted by
a vapor inthermodynamic equilibrium with its condensed phases (solid or liquid) at a given
temperature in aclosed system. The equilibrium vapor pressure is an indication of a
liquid's evaporation rate. It relates to the tendency of particles to escape from the liquid (or a
solid). A substance with a high vapor pressure at normal temperatures is often referred to
as volatile. The pressure exhibited by vapor present above a liquid surface is known as vapor
pressure. As the temperature of a liquid increases, the kinetic energy of its molecules also
increases. As the kinetic energy of the molecules increases, the number of molecules
transitioning into a vapor also increases, thereby increasing the vapor pressure.
The vapor pressure of any substance increases non-linearly with temperature according to
theClausiusClapeyron relation. The atmospheric pressure boiling point of a liquid (also known
as thenormal boiling point) is the temperature at which the vapor pressure equals the ambient
atmospheric pressure. With any incremental increase in that temperature, the vapor pressure
becomes sufficient to overcome atmospheric pressure and lift the liquid to form vapor bubbles
inside the bulk of the substance. Bubble formation deeper in the liquid requires a higher
pressure, and therefore higher temperature, because the fluid pressure increases above the
atmospheric pressure as the depth increases. More important at shallow depths is the higher
temperature required to start bubble formation. The surface tension of the bubble wall leads to
an overpressure in the very small, initial bubbles. Thus, thermometer calibration should not rely
on the temperature in boiling water.
The vapor pressure that a single component in a mixture contributes to the total pressure in the
system is called partial pressure. For example, air at sea level, and saturated with water vapor
at 20 C, has partial pressures of about 2.3 kPa of water, 78 kPa of nitrogen, 21 kPa
of oxygen and 0.9 kPa of argon, totaling 102.2 kPa, making the basis for standard atmospheric
pressure.
Contents
[hide]
Liquid mixtures[edit]
Raoult's law gives an approximation to the vapor pressure of
mixtures of liquids. It states that the activity (pressure or fugacity)
of a single-phase mixture is equal to the mole-fraction-weighted
sum of the components' vapor pressures:
where p tot is the mixture's vapor pressure, i is one of the
components of the mixture and i is the mole fraction of that
component in the liquid mixture. The term pii is the partial
pressure of component i in the mixture. Raoult's Law is
applicable only to non-electrolytes (uncharged species); it is
most appropriate for non-polar molecules with only weak
intermolecular attractions (such as London forces).
Systems that have vapor pressures higher than indicated by
the above formula are said to have positive deviations. Such
a deviation suggests weaker intermolecular attraction than in
the pure components, so that the molecules can be thought of
as being "held in" the liquid phase less strongly than in the
pure liquid. An example is the azeotrope of approximately
95% ethanol and water. Because the azeotrope's vapor
pressure is higher than predicted by Raoult's law, it boils at a
temperature below that of either pure component.
There are also systems with negative deviations that have
vapor pressures that are lower than expected. Such a
deviation is evidence for stronger intermolecular attraction
between the constituents of the mixture than exists in the
pure components. Thus, the molecules are "held in" the liquid
more strongly when a second molecule is present. An
example is a mixture of trichloromethane (chloroform) and 2-
propanone (acetone), which boils above the boiling point of
either pure component.
The negative and positive deviations can be used to
determine thermodynamic activity coefficients of the
components of mixtures.
Solids[edit]
with:
Dhring's rule[edit]
Main article: Dhring's rule
Dhring's rule states that a linear relationship
exists between the temperatures at which two
solutions exert the same vapor pressure.
Examples[edit]
The following table is a list of a variety of
substances ordered by increasing vapor pressure
(in absolute units).
Xenon
600 0.00
difluori 4.50 25 C
Pa 6
de
5.83 0.05
Ethanol 43.7 20 C
kPa 83
Methyl
2.66 0.02 19.9
isobutyl 25 C
kPa 66 5
ketone
220
Butane 2.2 1650 20 C
kPa
435.
Formal 4.35
7 3268 20 C
dehyde 7
kPa
997.
Propan 9.97 26.85
8 7584
e[9] 8 C
kPa
Carbon 1.25
12.5
yl 5 9412 25 C
5
sulfide MPa
5.66
Nitrous 56.6 4245
0 25 C
oxide[10] 0 3
MPa
Meaning in meteorology[edit]
In meteorology, the term vapor pressure is used
to mean the partial pressure of water vapor in the
atmosphere, even if it is not in equilibrium,[14] and
the equilibrium vapor pressure is specified
otherwise. Meteorologists also use the
term saturation vapor pressure to refer to the
equilibrium vapor pressure of water
or brine above a flat surface, to distinguish it from
equilibrium vapor pressure, which takes into
account the shape and size of water droplets and
particulates in the atmosphere.[15]
See also[edit]
Vapour pressure of water
Absolute humidity
LeeKesler method
Reid vapor pressure
Relative humidity
Relative volatility
Saturation vapor density
Triple point
True vapor pressure
Vaporliquid equilibrium
Vapor pressures of the elements (data page)
References[edit]
1. Jump up^ Rika, K.; Fulem,
M. & Rika, V. "Vapor
Pressure of Organic
Compounds. Measurement and
Correlation" (PDF).
2. ^ Jump up to:a b What is the
Antoine Equation? (Chemistry
Department, Frostburg State
University, Maryland)
3. ^ Jump up to:a b Sinnot, R.K.
(2005). Chemical Engineering
Design] (4th ed.). Butterworth-
Heinemann. p. 331. ISBN 0-
7506-6538-6.
4. Jump up^ Wagner, W. (1973),
"New vapour pressure
measurements for argon and
nitrogen and a new method for
establishing rational vapour
pressure
equations", Cryogenics, 13 (8):
470
482, Bibcode:1973Cryo...13..47
0W,doi:10.1016/0011-
2275(73)90003-9
5. Jump up^ Perry's Chemical
Engineers' Handbook, 7th Ed.
pp. 415
6. Jump up^ Perry, R.H.; Green,
D.W., eds. (1997). Perry's
Chemical Engineers'
Handbook (7th ed.). McGraw-
Hill. ISBN 0-07-049841-5.
7. Jump up^ Dreisbach, R. R. &
Spencer, R. S. (1949). "Infinite
Points of Cox Chart Families
and dt/dP Values at any
Pressure". Industrial and
Engineering Chemistry,. 41 (1).
p. 176. doi:10.1021/ie50469a04
0.
8. ^ Jump up to:a b Moller B.;
Rarey J.; Ramjugernath D.
(2008). "Estimation of the
vapour pressure of non-
electrolyte organic compounds
via group contributions and
group interactions". Journal of
Molecular Liquids. 143:
52.doi:10.1016/j.molliq.2008.04.
020.
9. Jump up^ "Thermophysical
Properties Of Fluids II
Methane, Ethane, Propane,
Isobutane, And Normal
Butane" (page 110 of PDF,
page 686 of original document),
BA Younglove and JF Ely.
10. Jump
up^ "Thermophysical
Properties Of Nitrous
Oxide" (page 14 of PDF, page
10 of original document),
ESDU.
11. Jump up^ Pankow, J. F.;
et al. (2008). "SIMPOL.1: a
simple group contribution
method for predicting vapor
pressures and enthalpies of
vaporization of multifunctional
organic compounds". Atmos.
Chem. Phys. 8 (10): 2773
2796. doi:10.5194/acp-8-2773-
2008.
12. Jump up^ "Vapour
pressure of pure liquid
compounds. Estimation by
EVAPORATION".
tropo.aeronomie.be
13. Jump up^ Compernolle,
S.; et al.
(2011). "EVAPORATION: a
new vapour pressure estimation
method for organic molecules
including non-additivity and
intramolecular
interactions". Atmos. Chem.
Phys. 11 (18): 9431
9450.Bibcode:2011ACP....11.9
431C. doi:10.5194/acp-11-
9431-2011.
14. Jump
up^ Glossary (Developed by
the American Meteorological
Society)
15. Jump up^ A Brief
Tutorial. jhuapl.edu (An article
about the definition of
equilibrium vapor pressure)
External links[edit]
Fluid Characteristics Chart
Hyperphysics
MSDS Vapor Pressure
Online vapor pressure calculation tool
(Requires Registration)
Prediction of Vapor Pressures of Pure Liquid
Organic Compounds