Cromatogramas de Curva de calibrado

uS/cm
Detector A

1
0.0

-0.5

-1.0

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma del blanco

uS/cm
Detector A

3
2

2
1

1
0

-1

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de patron de 0,5 ppm

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.061 1689 0.142 0.082 1.068 -- 3368.465
2 2.262 10364 0.274 0.160 1.577 0.965 1090.180
3 2.834 21033 0.292 0.170 1.342 2.022 1507.354

uS/cm
5.0 Detector A
3

2.5
2
1

0.0

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de patron de 1,0 ppm
Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.077 1812 0.137 0.078 0.990 -- 3676.667
2 2.266 21950 0.272 0.157 1.653 0.926 1109.109
3 2.843 41955 0.291 0.169 1.352 2.050 1530.798

uS/cm
Detector A

3
10

2
5

1
0

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de patron de 2,5 ppm

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.055 2243 0.128 0.072 0.938 -- 4093.875
2 2.242 64426 0.267 0.154 1.557 0.944 1125.530
3 2.816 128637 0.287 0.166 1.339 2.071 1539.296

uS/cm
Detector A
20

3
2

10
1

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de patron de 5,0 ppm

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.054 2069 0.118 0.067 0.916 -- 4840.231
2 2.245 127220 0.271 0.155 1.489 0.982 1101.499
3 2.812 190534 0.285 0.165 1.340 2.043 1558.056
 uS/cm
Detector A

4
50

3
25

2
1
0
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de patron de 10,0 ppm ( primera inyeccion)

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 1.752 31455 0.200 0.111 1.402 -- 1222.016
2 2.049 76770 0.143 0.079 1.077 1.732 3280.029
3 2.246 172446 0.247 0.144 1.387 1.006 1321.396
4 2.803 519070 0.281 0.162 1.318 2.113 1594.573

uS/cm
Detector A

3
50

2
25
1

0
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de patron de 10,0 ppm ( segunda inyeccion)

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.040 25136 0.132 0.073 1.033 -- 3818.629
2 2.236 216436 0.265 0.153 1.395 0.986 1135.647
3 2.794 518965 0.281 0.163 1.318 2.042 1582.039
 uV
50000

40000

30000

20000

10000

0
0.0 0.5 1.0 1.5 2.0 2.5 3.0

Cromatograma de todos los puntos de loa curva calibrado

uS/cm
Detector A
7.5 1

5.0

2
2.5

0.0

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de la muestra problema (primera inyeccion)

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.224 72990 0.271 0.155 1.587 -- 1078.373
2 2.793 44911 0.286 0.166 1.347 2.043 1524.304
 uS/cm
Detector A
7.5

1
5.0

2
2.5

0.0

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de la muestra problema (segunda inyeccion)

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.229 72308 0.270 0.154 1.578 -- 1091.386
2 2.796 45232 0.286 0.166 1.343 2.043 1531.451

uS/cm
Detector A
7.5

1
5.0

2
2.5

0.0

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5

Cromatograma de la muestra problema (tercera inyeccion)

Peak# Ret. Time Area USP Width Width(50%) Tailing F(10%) Resolution T.Plate#
1 2.218 73133 0.270 0.153 1.593 -- 1080.594
2 2.783 46088 0.286 0.166 1.350 2.036 1518.121

El tiempo muerto es de 1,503 min eso es para calcular el

Si es <1 no hubo selectividad
Si es >1 si hubo selectividad

Selectividad () = tiempo de retencin / tiempo muerto

La grafica es Concentracin en funcin del rea