Introduction Since 1948 several hundred papers devoted to the Casimir effect have appeared in the literature. The appearance of Casimir forces between rigid bodies is essentially the only macroscopic manifestation of the vacuum structure of quantized fields. It is therefore interesting to consider the effect for various configurations plates, spheres, wedges, cylinders etc. Investigations of Casimir forces between macroscopic bodies includes cases with ideal and semi-permeable walls, rough walls, and cases with moving boundaries. The Casimir effect was also investigated for temperatures other than absolute zero (Bordag, 2001). Casimir Effect aka Van der Waals interaction (one part of, between two molecules Keesom, Debye, London) London force Dispersion force Induced dipole induced dipole interaction Casimir-Polder force (atom-atom and atom-wall interactions) Casimir force (interaction between two macroscopic bodies) Quantum or charge fluctuations Zero-point energy Vacuum energy Casimir and Polder Casimir Force Background I Molecules attract one another when close together, even if they have no electric charge or dipole moment van der Waals, c.1900 London QM description between two molecules, 1937 Dutch physicist Hendrick Casimir predicted in 1948 that two mirrors few m apart experience an attractive force, due to vacuum fluctuations, F/A = 2c/240d4 , A = area of plates Mirror = ideal metal - characterized by perfect reflectivity at all frequencies, perfect conductor Casimir subtracted the infinite vacuum energy between the plates from the infinite vacuum energy of the quantized electromagnetic field in free space finite result above difference in radiation pressure E.g., two mirrors with area 1 cm2 separated by a distance d = 1 m attractive Casimir force of about 10-7 N ~ weight of a water droplet with dia 0.5mm. With d = 10nm F/A ~ 1 atm Becomes important force in MEMS devices can have useful (harness) as well as problematic (sticking) effects Background II Macroscopic quantum effect - example of a QED effect directly influencing a macroscopic, classical, apparatus. There is no force between neutral plates in classical electrodynamics. Finite speed of light retardation effects (Casimir & Polder, 1948). For two molecules ~ 1/r7 For separation range a < 1 m the retarded interatomic potential is not applicable. Vacuum fluctuations - particle antiparticle pairs, Et ~ h. Vacuum is full of fluctuating electromagnetic waves - come in all possible wavelengths. Recall harmonic oscillator, En = (n + ), n = 0, 1, 2, At absolute zero, ground state, E0 = Range of s between plates due to vacuum fluctuations < s outside attractive force between plates Casimir force Background III Can be both attractive as well as repulsive (depending on geometry, separation, materials) Note - get vacuum polarization when external em field is applied Theoretical tools include regularization, normalization, heat kernel expansion Integrals diverge regularize by introducing a frequency cutoff a la QFT Poles result from the heat kernel expansion inserted into the zeta function (another lecture on the mathematics?) Sum over Matsubara frequencies, (i), = 2nkT/, n = 0, 1, 2, Vacuum fluctuations give rise to following effects (QED): Casimir effect Spontaneous emission Lamb shift Anomalous magnetic moment of electron Experiment General requirements for the Casimir force measurements plate surfaces completely free of chemical impurities and dust particles precise and reproducible measurement of the separation between the two surfaces low electrostatic charges on the surface Modern precision measurements (last 20 years) Torsion pendulum Atomic Force Microscope (AFM) Micromechanical torsional oscillator Actual Measurements Derjaguin and Abrikosova (1957) Flat glass plate and sphere Direct measurement of the molecular attraction of solid bodies, Sov. Phys. JETP 3, 819, 1957 Marcus Spaarnay (1958) at Philips in Eindhoven Two parallel conducting plates - attractive force not inconsistent with the 1/d4 prediction - but with 100% uncertainty(!) F = A2c/240d4 van Blockland and Overbeek (1978) J. Chem. Soc., Faraday Trans. 1 74, van der Waals forces between objects covered with a chrome layer - no errors given(!) Actual Measurements (cont) Steve Lamoreaux (1997) now at Yale landmark experiment Flat plate and sphere - measurements agreed with theory to an accuracy of 5-10% Used copper and gold coated flat plate and sphere 2 F = R(2 c/240d3), independent of plate area 3 U. Mohideen and A. Roy (1998) UC Riverside Used sphere and flat plate AFM 1% error Decca et al, Tests of new physics from precise measurements of the Casimir pressure between two gold-coated plates (2007) Error of 0.2% at d =160nm Mohideen et al - Experiment Taking into account corrections up to the 4th order both in surface roughness and finite conductivity 1% agreement between theory and experiment Conclusions both surface roughness and finite conductivity corrections should be taken into account in precision Casimir force measurements with space separations of the order 1m and less U. Mohideen and A. Roy, Precision Measurement of the Casimir Force from 0.1 to 0.9 m, Phys. Rev. Lett. 81 4549 (1998) Mohideen and Roy - Experiment
Schematic diagram of the experimental setup
Mohideen and Roy - Results
Measured Casimir force as a function of plate-sphere separation - open
squares. Theoretical Casimir force with corrections due to surface roughness and finite conductivity - solid line, without any correction - dashed line. Mohideen and Roy roughness
4th order correction for surface roughness
Frequency dependence Real mirrors do not reflect all frequencies perfectly Frequency-dependent reflection coefficients of the mirrors have to be taken into account Theory given by, for example, Lifshitz (1956), Schwinger (1970), Feinberg (1978) Measured Casimir force between real metallic mirrors 0.1 m apart is half the theoretical value predicted for perfect mirrors Have both reflection from and absorption at metallic surfaces Chromium has two strong absorption bands around 600 nm which make about 40% of the total force (Bordag, 2001) FC = FC() Surface Roughness Real mirrors, of course, are not perfectly smooth 2 F(d) = F0(d)[1 + 6( ) + ], Ar = the average roughness amplitude
Lateral Casimir force - corrugated mirrors the surfaces of which were sinusoidally curved Opportunities for the actuation of lateral motion (tangential to surface) in MEM systems based entirely on the vacuum effects of quantum electrodynamics Chen et al, Demonstration of the Lateral Casimir Force, Phys. Rev. Lett. 88, 101801 (2002) P.J. van Zwol et al, Influence of random roughness on the Casimir force at small separations, arxiv.org/0712.1893 (2007) Mehran Kadar et al at MIT (2011) have calculated a theoretical value for the force between two perfectly reflecting corrugated mirrors - found good agreement with experiment Conductivity Effects Lifshitz (1956) gave Casimir force between two dielectric bodies as 2c 1 2 F/A = 240d4 0 (0), where (0) is a tabulated function +1 2 0
Fluctuating electromagnetic field that is always present in both the
interior and the exterior of any medium. Reproduces the results obtained by London and by Casimir and Polder Perfect conductor, 0 . Recapture Casimir-Polder result Ideal conductors - only the surface layer of atoms interacts with the electromagnetic field Finite conductivity finite penetration depth or skin depth, So Casimir force depends on type of metal - Drude model or free electron model of metals F(d) = F0(d)[1 + f(p)] , p = metal plasma frequency Drude Model First proposed in 1900 by Paul Drude to explain the transport properties of electrons in materials Purely classical model - treats both electrons and ions as solid spheres Conductor is characterized by a plasma frequency, p, and a skin depth, () p = frequency above which the conductivity goes to zero = skin depth is a measure of the depth at which the current density falls to 1/e of its value near the surface; decreases with increasing freq; aka attenuation length p2 = e2n/0me = 2/c2, = ne2 /me( - i) n = number of conduction electrons per unit volume = damping parameter for the Drude oscillators P. Drude, "Zur Elektronentheorie der metalle". Annalen der Physik 306 3 (1900) Free Electron Model Models the behaviour of valence electrons in a metallic solid. Combines the classical Drude model with quantum mechanical Fermi-Dirac statistics Ion cores surrounded by a sea of electrons Conduction electrons are not allowed to get close to the ion cores due to the Pauli exclusion principle - orbitals closest to the ion core are already occupied by the core electrons. Furthermore, the core electrons shield the ion charge magnitude seen by the conduction electrons. The result is an effective nuclear charge experienced by the conduction electrons which is significantly reduced from the actual nuclear charge. Temperature Dependence Experiments are never carried out at absolute zero At nonzero temperatures, the fluctuations also have a thermal contribution - quantum and thermal fluctuations. Thermal fluctuations at room temperature are only important at distances above 1 m, below which the wavelength of the fluctuations is too big to fit inside the cavity (Bordag, 2001) Temperature dependence must be included in calculations of the force at separations above 1 m In general, the quantum fluctuations dominate the force at small separations, while at separations large compared to the thermal wavelength T, thermal effects prevail (Kruger, 2011) 720 F(d) = F0(d)[1 + 2 f(T) + ] => attraction > 0 K case (see, for example,
Obrecht, 2007). In conclusion, we have made the first measurement discerning the temperature dependence of the Casimir-Polder force. The strength of this force was shown to increase by a factor of nearly 3 as the substrate temperature doubles. Other models? Is Casimir effect due to vacuum fluctuations or solely due to material properties? Casimir effects can be formulated and Casimir forces can be computed without reference to zero-point energies (source theory - Schwinger, 1978) Concept of zero point fluctuations is a heuristic and calculational aid in the description of the Casimir effect, but not a necessity (Jaffe, 2005) Uses Drude model of metals Zero point fluctuation approach currently won out derivation is mathematically much simpler (than 4th order perturbation theory). Current Research Casimir force in nanoscale device fabrication - fundamental in the design and construction of MEMS and NEMS (Micro and Nano Electro Mechanical Systems) Corrections to the Casimir effect due to various factors as finite conductivity of the boundary metal, surface roughness, and nonzero temperature Both static and dynamic micromachines actuated by the normal Casimir force have been demonstrated Adhesion and sticking of moving parts in micromachines due to the Casimir effect have been investigated stiction. Influences the performance and fabrication of nanodevices Growing interest in calculating Casimir Forces for complicated geometries A complete understanding of the material and shape dependences of the Casimir effect is necessary to improve the design, performance and yield of nanodevices. Stiction MEMS device MEMS - illustrations Geometries Two parallel plates Sphere plate Two spheres Two cylinders (e.g., micro- and nanotubes) Many (three) body - numerical Different temperatures e.g., 0K, and 300K Curved surfaces, often use Proximity Force Approximation - PFA sphere and plate surfaces are well approximated by a collection of infinitesimal parallel plates Not valid for larger separations and for surfaces that are not smooth Emig & Kardar - MIT Extended and generalized calculations to include: n arbitrarily shaped objects, whose surfaces may be smooth or rough or may include edges and cusps objects with arbitrary linear electromagnetic response, including frequency-dependent lossy electric permittivity and magnetic permeability tensors objects separated by vacuum or by a medium with uniform, frequency-dependent isotropic permittivity and permeability zero or nonzero temperature and objects outside of one another or enclosed in each other Rahi, S.J., Emig, T., Graham, N., Jaffe, R.L., Kardar, M., Scattering theory approach to electrodynamic Casimir forces, Phys. Rev. D 80, 085021 (2009) Scattering theory approach Characterizes each object by its electromagnetic scattering amplitude Translation matrix separations and orientations of the objects The scattering amplitudes and translation matrices are combined in a simple algorithm that allows efficient numerical and, in some cases, analytical calculations of Casimir forces T-operator approach objects can have any shape or material properties, as long as the scattering amplitude can be computed in a multipole expansion Concrete implementation of the proposal emphasized by Schwinger (1975) Translation matrices for common separable coordinate systems, obtained from the free Greens function, are applied in the Casimir force calculations For small separations, sufficient accuracy can only be obtained if the calculation is taken to very high partial wave order e.g., as two spheres come into contact an infinite number of spherical waves are needed to capture the dominant contribution. Conclusions The Casimir effect has become the subject of diverse studies of general physical interest in a variety of fields. It is equally interesting and important for Quantum Field Theory, Condensed Matter Physics, Gravitation, Astrophysics and Cosmology, Atomic Physics, and Mathematical Physics. Currently the Casimir effect has been advanced as a new powerful test for hypothetical long-range interactions, including corrections to Newtonian gravitational law at small distances, predicted by the unified gauge theories, supersymmetry, supergravity and string theory. It is also gaining in technological importance in vital applications such as in nanoelectromechanical devices and biophysics. References F. London, The General Theory of Molecular Forces, Trans. Faraday Soc., 33, 826 (1937) H. B. G. Casimir, On the attraction between two perfectly conducting plates. Proc. Kon. Nederland. Akad. Wetensch. B51: 793 (1948) H. B. G. Casimir, and D. Polder, The Influence of Retardation on the London-van der Waals Forces, Phys. Rev. 73, 360372 (1948) E.M. Lifshitz, The Theory of Molecular Attractive Forces between Solids. Soviet Physics Jetp-Ussr 2, 73-83 (1956) M. J. Sparnaay, Measurements of attractive forces between flat plates, Physica (Utrecht) 24, 751 (1958) G. Feinberg and J. Sucher, General theory of the van der Waals interaction: A model-independent approach, Phys. Rev. A 2, 2395 (1970) J. Schwinger et al, Casimir effect in dielectrics, Ann., Phys. (N.Y.) 115, 1 (1978) References B. V. Derjaguin et al, Direct measurement of molecular forces, Nature, 272, 313 (1978) Y. Srivastava, Microchips as Precision Quantum-Electrodynamic Probes, Phys. Rev. Lett. 55, 2246 (1985) A. Nieto, Evaluating Sums over the Matsubara Frequencies, arXiv:hep- ph/9311210v1 (1993) P.W. Milonni, The Quantum Vacuum, Academic Press (1994) S. K. Lamoreaux, Demonstration of the Casimir Force in the 0.6 to 6 m Range, Phys. Rev. Lett. 78, 58 (1997) U. Mohideen and A. Roy, Precision Measurement of the Casimir Force from 0.1 to 0.9 m, Phys. Rev. Lett. 81 4549 (1998) E. Buks, Stiction, adhesion energy, and the Casimir effect in micromechanical systems, Phys. Rev. B 63, 033402 (2001) M. Bordag et al, New Developments in the Casimir Effect, arXiv/0106045 (2001) 275 page review paper R.L. Jaffe, The Casimir Effect and the Quantum Vacuum, Phys. Rev. D 72 021301 (2005) References J. M. Obrecht et al, Measurement of the Temperature Dependence of the Casimir-Polder Force Phs. Rev. Let. 98, 063201 (2007) R. S. Decca et al, Tests of new physics from precise measurements of the Casimir pressure between two gold-coated plates, Phys. Rev. D, 75, 077101 (2007) J.N. Munday et al, Measurements of the Casimir-Lifshitz force in fluids: The effect of electrostatic forces and Debye screening, Phys. Rev. A 78, 032109 (2008) U. Mohideen et al, The Casimir force between real materials: Experiment and theory, Rev. Mod. Phys 81, 1827 (2009) P. Rodriguez-Lopez, Pairwise Summation Approximation of Casimir Energy from First Principles, Physical Review E 80, 061128 (2009) S.K. Lamoreaux, Progress in Experimental Measurements of the Surface-Surface Casimir Force, arXiv/1008.3640v1 (2010) T. Emig, Casimir Physics: Geometry, Shape and Material, arxiv/1003.0192v1 (2010) M. Kruger et al, Non-equilibrium Casimir forces: Spheres and sphere-plate, arxiv/1105.5577v1 (2011)