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CSEC Chemistry
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I June 2009 Paper 1
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CHEMISTRY
I
READ THE FOLLOWING DIRECTIONS CAREFULLY
I. I. In addition to th is test booklet, you should have an answersheet.
! 2. Each item \n this test has four suggested answers lettered (A), (B), (C), (D). Read each item you are
about to aryswer and decide which choice is best.
3. On your answer sheet, find the numberwhich corrCspOnds to your item and shade the space having
I
the same letteras the answer you have chosen. Look at the sample item below .
Sample Item
(A) kilogram
I (B)
(C)
metre
newton
(D) second
I The best answer to this item is "metre", so answer space (B) has been blackened.
4. [fyou want to change your answer, be sure to erase your old answer completely and fill in your new
I 5.
choice.
When you are told to begin, tum the page and work as quickly and ascareli.Iily as you can Ifyou cannot
answer an ite111, om it it and go on to the next one. You can come back to the harder item !ater. Your
'
. score will be the total number of correct answers.
I
9. T~ is test consists of60 items. You v.;i l I have 7 5 minutes to answer them
10 Do not be ccncerni::d that rhe ansvier sheet ~ro . ides spaces for more ans,vers than there are items in
th1stest
~~~~2.0~0-9~~~~~~~~~~~~~~~~~~~~~~,---~~~~~
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1
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[terns 1 - 2 re::~r
resented
(A)
(8)
2,4
2, 8
[0 the following atoms rep-
by their electronlc configuration.
5 Which of che followin~- requires the
LARGEST numberof mo ks of electrons co
liberate one mole of it?
(A)
[
(C)
(DJ
2,8,6
2,8,8,2
(B)
(C)
(D)
Cu 2"'"
o-
r
M.atch each item below with one of the
'
options above. Each option may be used
more than once, once or not at all.
(
6. Which ofthese elements has seven electrons
Which element in its outer shell?
[
l. combines with chlorine to fonn ionic bonds?\, (A) Hydrogen
(B) Oxygen
2. fns many giant structures occuring both (C)
(D)
Nitrogen
Chlorine
[
naturally a.>d artificially? 1
3 In-which cif the following are radioactive 7. The ionic equation for the reaction between ~
isotopes NOT used? an acid and a carbonate may be represented
as
[
(A)
(B)
\GJ.
(D)
Radiotherapy
Carbon dating
Metal extraction
Energy generation
(A) H(aq) + CO,'"(aq) -+ HCO ,_(aq)
il~!ll 9 refers to [hr! follo-.\.' 1 ng illustrations of the electronic structure of fo;..1r :ltoms
I
t
~ (;\
I \::_) ~
1. p Q R s
I
I (A),
(13)
(CJ
(D)
P and
P and S
Q and S
Q and R
Q
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Zooq
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.~
;
1.-1
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4-
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lt~m l~ refer:, to the follo\.v1nggraph \Vh1ch l~ \V h 1ch Gf t...11~ follo\v ing separ.:i.uon [ech n iques
sho\VS the boiling points of some straight- is NOT used during the extr.1.~tion of sucrose
charn alcohol~: from sugar cane?
(A) Filtration
(B) Precipitation
(C)
(D)
Centrifugation
Chromatography r
1 2 3 4 5 6 7
Number of Carbon Atom1 In. Cllain
15. Which of the following does NOT affect the
solubility of a substance?
(A)
(B)
(C)
Catalyst
Pressure
Stining
'
I
(D) Temperature
[
12. The MOST suitable method for separating
the4-carbon alcohol from a mixture with the 16. A piece ofcalcium is added to some distilled
5-carbon alcohol is water in a contaii:ier and a gas is produced_
The gas produced is expected to
(A) fractional distillation
[
(B) solvent extraction (A) relightaglowingsplint
(C) simple distillation (B) give a 'pop'with a lighted splint
(D) simple evaporation (C) decolourize acidified aqueous
(D)
potassium manganate (VII)
tum acidified aqueous potassium
[
13. Which ofthe following is the correctfomnula dichroITlategreen
for ammonium carbonate?
[
(A) NH.co, 17. Which set of elements has atoms with two
elecq-ons in their outer shells?
(BJ NH, (C0 3 ) 2
(A) The halogens
[
(C) (NH,) 2 CO,
(B) Period2elements
(D) (NH,) 2 (C0 3 ) 2 (C)
(D)
Group II elements
Thetransitionelements
[
[
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[
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GOONTOTHENEXTPAGE [
f. .. o-.1
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r -5-
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filrn:-; lS - 19 r~fer to tht:: fol1ov.. 1ng rypesof lti!ms 22 -2J refer to the foliO\.vtr:i.g
substances. chemicals
(A) Salt
! (B)
(C)
Base
Alkali
_(A)
(BJ
(CJ
Calcium carbonate
Magnesium metal
Barium chloride
(D) Acid (D) Litmus solution
I Match each item below with one of the In answering items 22 - 23, a particular
optionsabove. Eachoptionmaybeusedmore choice from the above may be made more
I 18.
than once, once ornotat al I.
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I
(A) an oxidising agent
I. Solution (BJ a reducing agent
II. Colloid (C) a dehydrating agent
Ill. Suspension (DJ both an oxidising and reducing agent
(A) !only
(B) III only
I (Cj
(D)
land II only
II and III only
l I
[],
NaH,PO,
Caso,
Ill. Al,Co,
IV KHSO,
2..oO'l
nn nN Tn THl'. NP"l<T P" r.i:
-6-
!tern 25 r~fi::r:; to the fo!\o\.ving information
Different volumes of0.1 i\/1 hydrochloric acid \.vere added to 25 cml of aqueous potassium hydroxide
in a plastic cup and stirred. The rilGHEST temperature reached after each addition \.Va~ recorded and
the results obtained are shown on the graph below.
a. ++~
+''
+t;, .
30
20
10
0 5 10 15 20 25 30 35 40
Volume of 0.1 M HCI added /cm'
(Al 2sc
(B) 27C
(C) 34C
(DJ 38 C
200q
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hems :29-30 r:::fer to the foJlc,.,, ing options
2,:, \iVh1ch of the fotto~v1ng 0ccurs \Vhen a metal
v..'hich represe:1t the ordero f some metals in
ato1n becomes an ion?
the activity serl-~s
I (A)
(Bl
It gains electrons and is oxidised
ltgains electrons and is reduced (A) M~onesiurn
Iron
It loses electrons and is oxidised (8)
(C)
~
It loses electrons and is reduced (C) Lead
(D)
(D) Copper
Which element
,I in dry hydrogen. When the reaction is
complete, 1.68 g ofiron are left.
29. would be liberated at the cathode from
[Rel. at~mic mass: Fe= 56; 0 = 16] the aqueous solution of its salts during
I ~j
reduced
oxidisro
by hydrogen? .t:
which is used to measure the rel8.tive
:I (D) decomposed into its elements
conductivity ofvarious substances.
I 28. Inanexperiment,onheating402gofmercury,
a black powder with a mass of 434 g is
6 V d.c. Supply
~---111111---~
obtained (Rel. atomic mass: Hg = 20 I; Bulb
I O= 16). Thebalancedequationrepresenting
this reaction is
Graphite Graphite rod
rod
(A) Hg (I)+ 0 2(g) = HgO(s)
Liquid under
_.{BJ 2Hg(I) + O,(g) = 2HgO(s) - - - -- investigatiou
(C) Hg(s) + O,(g)= HgO(s)
(D) 2Hg(s) + 0 2(g) = 2Hg0(s)
31. Which of the following solutions will NOT
cause the bulb to light?
..
re'
\
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- 0 -
Two cxperin1ents were carried out 1n order 33 \Vhich of die folto ...v1ng ~1pparatus is the
31
to investigate the effect of changing conditions lvfOST suitable fortheelect[Oly51s of copper
on the reJ.ction bel\.veen hydrochloric 3cid and (II) sulphate between copper electrodes?
excess magnesium f-""'
[
(
(D)
+--- Copper Cm
sulphate (aq)
[
[
[
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[
t
- . _ ... - ........ -'-r"' ..-.r
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Items 36 - 37 refer to the following sequence of reactions involving iron compounds, where I, II, Ill
and IV represent the stages involved.
l I II
FeCO, ----+ FeO ----+Fe,O, ---7
ID N
Fe 2 (SO,), - - - > Fe(OH),
I 36. In which stage is the oxidation state of iron 3 7. A suitable reagent that col.lid be used at N is
increased?
I'
(A) steam
(A) I (B) hydrogen
(Bl. II (C) solidcopperoxide
(C) m OS>l aqueoussodiumhydroxide
{D) IV
(Cl electrolysing a concentrated so Ju ti on
ofsodium chloride
(DJ adding aqueous bromine to aqueous
!
sodium chloride
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r'\I"'\ f'\)r,,f Tl"\ TV1:" W'CVT D 6 r'!'C'
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l\lleta! Reaction '"ith water/steam Products formed when nitrate is
heated
!tt:rn 41 rcL:rs to the properties of four metals,\\/, X, \' anc.l Z, \.Vh1ch Jre summaris-::J in Lhe follovv1ng t.1blt: -
[
--;:
w
x
No reaction
Oxide, N0 2 and 0 2
r
with cold water
I L
IL
!Jl.
Decomposition
Combustion
Photosynthesis
(A)
(B)
Aluminium is higherup in the activity serie:
than iron, therefore it is more resistanttc
corrosion than iron.
Bothmetalsformoxidecoatsbutaluminiurr
l
[
42. Which of these reactions would be oxide prevents further reaction, whih
responsible forretuming carbon d iox.ide to the the iron oxide does not.
atmosphere? (C) Both metals form hydroxide coats butth
aluminium hydroxide prevents furthe
reaction, while the iron hydroxide doe
[
(A) I only
(B) !II only not
((:0
ID)
[and[! only
l,lland][!
(D) Aluminium is lowerthan iron in the activit.
series, therefore it reacts less read ii
[
with air than iron.
'
~refers to the follov,,1ing equarion
H l:l H B
I I I I
[ !! - c
I
c c c
I
- H + Br2 ~ X
H H
I (A)
H
I
H-C-C-C -C -H
H
I
H
I
H
I
I I I
I Br Br H H
H H H H
I (Ii)
I
H-C-C-C -C -H
I I I
I I I
H
I H
H
Br
H
Br
H H
I I I I
:I
,( (C)
(D)
H-C-C-C-C -H
Br
H
I
H-C-C-C.-C -H
H
H
I
I
I
H
H
I
Br
H
I
I H
I I
Br
I
H Br
I
t
r
l
.. nn ()"J Tn TH"I' NFJCT PAGF
l
[
- I2 -
[
The compound, ethene, is described as being Item -48 refers to the fc.ilowing structure:>
unsatura[cd. This means that the
(C)
atoms
carbon atoms in the molecule are
~ I I
fl [
H -C- II
very reactive I
(D) molecule contains at least onedouble H
bond
ll
[
I
H-C-H
47. All members of a homologous series have
similar
II.
I f f [
H-C-C-C-H
I I I
(A)
(Bl
densities
boilingpoints H H ll [
(C) chemical properties
(D) physical properties H
H-C-H
.I
~
1 f
ID.
[
H-C - C-ll
~ll-C-ll
I
I
II
[
H
rv.
H-C-ll
1
I
I f
H-C-C-H
[
I ~
H-C-Il
ll
I [
48 Which structures represent branched [
alkanes?
(A)
(B)
land U only
I and TV only
L
(C) ill and JV only
I, JI an_d ][]only
l
(D)
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[l '
rf
r - I3 -
'f
Lti;n1 4q refers to ['.'JO organic compounds, I and II, of molecLilar formulz c. . f-1~0, \Vith the fol)ov..1ng
structures
fl
I I
..I
LJ
H
I
H
I
H
I
' H-C-C-C-H H-C-C-C-OH
r H
I
I
I
OH H
I I
H
I
H
II
I
H
l1 (A)
(B)
(C)
isomersofC,H,O
isotopes ofC,H.O
condensed formulae ofC,H,O
,. (D) , molecular formulae of C,H,O
fI Items 50-51 refer to the following 52. Which of' the following is used in the
compounds. breathalyser tesi to detect the presence of
:I
r alcohol?
L Fats
II. Nylon (A) Lime water
III. Proteins (BJ Lightersplint
I IV. Terylene (C)
JP)_.
Bromine water
Potassium dichromate
2.00'I ,..,... ,._, ..... I"\ -'""''-fT'!'V_,. 'rl" ,..,_
..
....
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[)ur111g th~ manur"acrure of erh.::inul by
fe.rmenrat1:-in, the gas evol\'ed
(A)
(B)
(C)
relights a glowing splint
bums with a blue flame
turnsl1mewatermilky
58 \Vh1ch c-.vo group~ <ir'..; Pr:.esenr in !h.::
mo!ecules Jfamino acids".'
(A)
(B)
(C)
-NH, group and -COOH group
-NH, group and -OH group
-OHgroupand -COOHgroup
[
(D) turns potassium di chromate green (D) -COOHgroupand C=Cgroup
[
SS. The reaction of fats with concentrated
aqueous sodium hydroxide is commonly
59. Which ofthe following names refers to the
product fanned in the reaction [
referred to as 3n(CH, = CH,) --t f CH 1CH,CH 2CH,CH,CH;J,"?
IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST.
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