ALDEHYDES AND KETONES KEY

1 10 D A D B C D C A ,B,C,D B,D A,C

11 20 A,B,D B C D A C 6 4 9 9

21 23 1 2 3

SOLUTIONS

1)

2) Wittig reaction
3) conceptual
4) NaBH 4 supplies H while NaBD4 supplies D

NOH

5) 2 isomers 6 isomers 2 with ortho,meta and para

each of syn and anti

has 2 isomers
6) Four possible products are
* *
HO CH2 CHO
Aldol condensation
HO CH2 C H(OH) C H(OH)CHO
Tetrose

It can be D, L-erythrose and D, L-threose

7) Electron with drawing group increases reactivity in Benzoin condensation

8) Alkyne gives 1,2dicarbonyl on the other hand alkene gives carbonyl

compounds by breaking double bond in Reductive ozonolysis.

9) Conceptual

10)

O O
ph C H OH
ph C H
OH

R . D .S O
ph C H

ph CH 2 O

PARAGRAPH -1 (12-13)

12. Hydride transfer step is slow step in cannizaro reaction

13. More reactive aldehyde is converted to acid

PARAGRAPH -2 (14- 16 )
CH3 O

A is B is F is G is

18) a ,c d f show positive test for Fehlings test

19. Pinacol-Pinacolone rearrangement

 OH
20. CCCHO C=CC HO C = C C C=COC
OH O
O
C=CCOH O CCC
21.

22. FCH2CHO, O2N CH2CHO

CH2R
+
OMgX
X
+ RH + Mg
CH3O Cl
C
+
MgXO R
23. CH3