GET EQUIPPED FOR IIT JEE Advanced

Only one option correct

1)

(B)

4 B.P and Zero L.P is SiF4.

2)

(D)

ICl2 has 2 B.P and 2 L.P.

Sp 3 hybridization and bent shape.

3)

(C)

Sp 2 hybridization and trigonal planar geometry.

4)

(D)

BrF5 : 5 B.P + 1 L.P

Sp 3d2 hybridization and square pyramidal geometry.
8 F Por F angles at 900.

F
F

Br

5)

(C)

6)

(D)

7)

(A)

8)

ClO4 : 4 B.P + Zero L.P Sp3 hybidiation.

HS+ OS
u C
C
S+
S
u
H
O

Bond order of

O22 1

; O2 2

O 2 = 1.5 ; O 2+ 2.5

Hence, Stability O2 O2 O2 O22 ; Ans : (B)

17)

NO2 Sp

18)

(B)

NO3 Sp2

NH 4 Sp3

;
2

NH3 Sp3 ;

PHl4

PCl5 Sp3d ;

BCl3 sp 2 .

dSp 2

(3)

(Square planar)

19)

(A)

All are 14 e squares with B.O = 3.

20)

(A)

The e density lies above and below the inter-nuclear / molecular axis.

21)

(B)

22)

(C)

O2 : / s 2 * / s 2 2s 2 2 pz2 z 2 pn2 z y 2 pn2 * 2 pz z 2 py 2 z y 2 py1

23)

(B)

More than number of H atoms, more is the H Bonding hence, Due to higher intermolecular
forces of attraction, higher is the M. pt.
CH
H C
3

24)
25)

(A)
(D)

H 3C

Lead Oxide PbO2.

12

OH

OH

11

12

10

OH

5
O

aa

7
OH

OH

O
O

NH 2

26)
27)

(C)
(C)

Dipole Moment of u

u
u

3 1.5 D

2.6 D.

P1 P2 .

p12 p22 2 p1 p2 cos 600

28)

(D)

O H bond is more polar than N H bond. & SO + on H is more in O H bond. Also N is

better donor than O

29)

(C)

H
C

C
120 0

CH3

Comprehension Type
Passage 1:
1) (D)

Both F atoms are present in axial positions.

2) (A)

uF3 has Sp3d hybridization ; 3 B. P + 2 L.P

3) (D)

PI5 and PBr6 donot exist due to steric factors. In PH5, Because of its low electronegative

H atom cannot effect the contraction of dz2 orbital to form Sp 3 hybridized P = atom.

4) (B)

PBr6 doesnot exist since P cannot accommodate 6 Br atoms around it due to steric

hindrance.

5) (D)

30

i)

31

Cl + P Cl + P Cl + P Cl 4
P Cl Cl
P Cl Cl

P

35

30

37

35

31

35

31

37

31

37

35

37

ax

4eq

= 2 forms
31

ii)

31

Cl Cl
35

37

iii)

31

iv)

31

Cl
35

37

31

3 =

31

forms

31

Cl3

Cl
37

eq

ax

Cl Cl
P Cl Cl Cl Cl
P Cl Cl Cl
Pax

35

37

35

eq

37

35

37

2 eq

ax

37

35

ax

37
2

eq

Cl Cl 3 forms ; same as (ii)

P Cl Cl 2 forms ; same as (ii)
P

35

37

35

37

Similarly with 30P atom as central Atom, 10 forms will be there. Total = 24.

6) SF4 has 4 G.P + 1 L. P ; Hence (C).

7) (C)

IF2 Sp3d has 2B.P + 3 L.P

8) (C)

In Sp3d hybridized, dz2 orbital is utilized.

Passage 2:
1) A)

i)
ii)

iii)
iv)

2)

3) (A)

I3+ : 2B.P 2L.P;Sp3 hybridization

S
S
SO2 can be represented as
and
. It is considered that S being in 3rd
O
O
O
O
period can utilized its d orbitals to form pz dx bonds with O atoms.
XeF2 : 3 L.P and 2 B.P Sp3d hybridization.
CO2 : Sp hybridization 2 B.P
SF4 : Sp3d hybridization 4 B.P + 1 L.P
ICl3 : Sp 3d hybridization 3 B.P + 2 L.P

I3 : L.P 3;

B.P 2

Ratio 1.5

XeF4 : L.P = 2 ;

B.P = 4

Ratio 0.5

NO2 linear 1800

NO 2 odd e system bent 1340
NO 2 1 L.P bent 115 0

4) (B)

Bond angle PF3> PCl3< PBr3< PI3.

Due to dx px bonds in PF3, double bond character develops increase in B.P B.P repulsions
lead to increase is Bond Angle.

5) (D)

B.O of O2 2.5; O2 1.5;O2 2, O22 3; O2 2 1

Bond length O22 O2 O2 O22 O22

6) (D)

B.O of N2 2.5
B.O of N2 2.5; e s occupy non bonding Molecular orbitals.

bond strength of N2 Bond strength of N 2+

7) (C)

CN

NC

i)

C
NC

C
NC

CN

bonds = 8
bonds = 8
ii)

C
CN

bonds = 9
bonds = 9
H

CH CH CHO = H C
3 2
H

C
H

P ropan al

CN

NC

O
C H

CH COCH = H C
3
3
H

C H

Propauone

ii)

XeF4 is square planar in shape.

SF4 has See saw Shape.
Due to smaller orbital size, effective overlapping take place in u u bond.

iv)
Passage 3:
1) (D)
2) (A)

In HF2 H bonding exists between HF and I .

3) (B)
Passage 4:
1) A)

BeCl2 has maximum covalent character because of smallest size of cation Be2

2) D)

I is the largest Anion.

It has maximum polar ability.

3) C)

Highest positive change and smallest size of cation (Al 3 ), hence maximum polarization and
covalent character.

4) B)

Liu has maximum covalent character, hence it will be most soluble in non polar solvent ether.

5) D)

CaI2 has maximum covalent character hence least M.pt

Passage 5:
1) A) and B) These are planar molecules. XeF4 has square planar shape.
XeF4 has trigonal planar shape.
2) p q l

p 1.2 1018 esu cm

l
108 cm
q 1.2 1010 esu.
q

Fraction of change
3)

(C)

o-dichloco

benxene

1.2 1010 1
0.25 .
4.8 1010 4

CH3

m -dichlone
b en zene

toluene

u
p-dichloro
ben zen e

4)

(D)

H H H

F F F

5) % Ionic character

1.5 10 29 C.m
100 62.5%
1.6 10-19 C 150 10 12 m

Passage 6:
1) B
2) A
3) A.

Window To IIT JEE Advance

C. Multiple Choice Questions with ONE correct answer :

1) (C)

Sp2 hybridized, p = 0.

2) (A)

CO and CN 14 e systems.

3) (A)

CO2. Sp hybridized

4) (B)

CCl4 Sp3 hybridized with tetrahedral geometry.

5) (B)
6) (D)
7) (A)

NO 15 e system ; has 1 unpaired e .

O2 16 e system ; has 2 unpaired e s.

8) (C)

More than bond forms stronger H Bonds.

9) (C)
8-

10) (A)

CH 3 CH 2 O H

11) (C)

C
H

Sp 2.

12) (A)
13) (A)

trigonal planar, Sp2 hybridized p = 0.

14) (A) PCl3 has 3 B.P + 1 L.P

u

CH 3
15) (C)

OH

H 3C

CH 3
16) (A)

2 B.P + 2 L. P ; Sp3 hybridized.

17) (B)

18) (C)

Least oxidation state, least polarization, least covalent character.

19) (D)

O2 : / s 2

20) (C)

N
F

x / s2

B
F

21) (B)

Ca +2 C C

22) (C)

O2

1 2

superoxide ion.

25) (D)

23) (A)

24) (C)

H H H

2s2 2s 2 2pz 2 2pn 2

Sp 2

2pn1 x 2pz 2py 2

2py1

26) (B)

27) (A)

28) (C)

29) (D)

B. O of CO = 3 ; CO2 = 2 ; CO32 1.5 .

Bond Length : CO32 CO2 CO.

30) (A)

H
31) (D)

33) (B)

32)

F F

4 BP + 1 L.P

Xe

4 B.P + 0 L.P
+

NO+2 Sp

ONO
O

NO3 Sp2

4 B.P + 2 L.P

NH 4 Sp3
H

N
O

34) (A)
35) (B)
36) (A)
H
H

F
F
F

N B

37) (C)
38) O+2 B.O is 25
39) (D)

(B)

I3 has 3 L.P,

XeF4 has 2 L.P

SF4 has 1 L.P,

ClO3 has 1 L.P

H H

D.Multiple Choice Questions with ONE or MORE THAN ONE correct answer :
(1)

(A)

and

(C).

Cl Hg Cl ;

HC CH

(2) (B), (C), (D) .

+

S=C=S ;

O=NO

CN and NO has B.O = 3.

(3) A, (C)
(4) B, C.

CH 2
C

CH 3

H 3C

H 3C CH 2

CH 2 CH 3

cis-3 -H e x e n e

tra n s -2 -p e n te n e

(5) (D)

H3O+, NH3 and CH3 have Sp3 hybridization.

(6) (B)
(7) (A)
(8) (B)
(9) (B), (D)
(10) B, C, D
(11) A, B, D
(12) A, B, C. HF and H2O have abnormallyhigh B.pt due to H Bonds
(13) A, C, D Cl Hg Cl ;

u I u

S=C=S

14) B, D
15)

A, D

16)

A, B, C

FC CF

H H H
17) A, B, C, D.
18) B, C

SF4 4 B.P + 1 L.P

PF5 5 B.P Zero L.P .

19) A, C

F
C

20)

Al OH 3 NaOH Al OH 4

Sp 3
SiF4 2HF SiF6

Sp3

Solid

Sp3

Sp 3d2

Hence, A, C, D.

Sp 3d 2

21) A, C

22)

Pu 5 Pu 4 Pu 6

Only O2 and B2 are paramagnetic.

O
O

C, D HCO 2 H C
HCO 2 H C
O
O
B.O of HCl 2 1.5 B.O of CO 32 1.33

H C O H C O

formate ion Carbonate ion

23)

Bond length of HCO2 Bond length of CO32

F
H
A, C F
S C
H
F
F

24)

A, B

H
B
H

u
Al

B
H

Al

u
2

N N O
N N N O
Resonating Shushes with formal charges.

u
u

25)

A, C, D

26)

A, B, C, D.

27)

A, B, C, D
More electronegative element in each case, i.e. O and F occupy axial position in I & II respectively.