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SAFETY DATA SHEET

Hardtop AX K Comp B
(In accordance with Article 41, Paragraph 1, of Industrial Safety and Health Act)

Section 1. Chemical product and company identification
A. Product name

: Hardtop AX K Comp B

Label No.

: 22800

Product description

: Paint.

Product type

: Liquid.

B. Recommended use of the chemical
Identified uses
Uses in Coatings - Professional use
Professional applications, Used by spraying.

C. Supplier/Manufacturer

Emergency telephone
number

: Chokwang Jotun Ltd.
96, Gwahaksandan 1-ro
Gangseo-gu, Busan
South Korea
Tel: +82 51 797 6000
Fax: +82 51 711 7735
SDSJotun@jotun.com
: H.G.LEE Chokwang Jotun Ltd.
Tel: +82 51 797 6000

1,2

22800

^(ValidationDate).

1

Approved

Section 2. Hazards identification
A. Hazard classification

: FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
RESPIRATORY SENSITIZATION - Category 1
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
LONG-TERM AQUATIC HAZARD - Category 3
B. GHS label elements, including precautionary statements
Symbol

:

Signal word

: Danger.

Hazard statements

: Flammable liquid and vapour.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
Harmful to aquatic life with long lasting effects.

Precautionary statements
Prevention

: Wear protective gloves. Wear eye or face protection. In case of inadequate
ventilation wear respiratory protection. Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking. Use explosion-proof electrical,
ventilating, lighting and all material-handling equipment. Use only non-sparking
tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Avoid release to the
environment. Avoid breathing vapour. Contaminated work clothing should not be
allowed out of the workplace.

Date of issue/Date of revision : 16.02.2016.

Low boiling point naphtha — unspecified Butyl Acetate. not result in classification Section 3.02. Disposal : Dispose of contents and container in accordance with all local. 1. within the current knowledge of the supplier and in the concentrations applicable. light arom. Hexamethylene-1. If skin irritation or rash occurs: Get medical attention. HDI. homopolymer. petroleum. light aromatic. .2016. 1. n-Butyl-acetate. Other hazards which do : None known. Call a POISON CENTER or physician if you feel unwell. Hexamethylene diisocyanate. Solvent naphtha (petroleum).5-10 822-06-0 0. Solvent naphtha. Butyl ethanoate. Solvent naphtha (petroleum). : Store locked up. 1. Occupational exposure limits. light aromatic n-butyl acetate hexamethylene-di-isocyanate There are no additional ingredients present which. 1. IF ON SKIN (or hair): Take off immediately all contaminated clothing. 6-Diisocyanatohexane. 1. n-Butyl ester of acetic acid.6-diisocyanato-. Solvent naphtha. Acetic acid. light aromatic. light aromatic. Date of issue/Date of revision : 16. 6-diisocyanate. hexamethylene ester. Rinse skin with water or shower. Hexamethylenediisocyanate 28182-81-2 80-90 64742-95-6 2. homopolymer. 6-diisocyanato-. Hexamethylene diisocyanate (HDI) homopolymer Low boiling point naphtha unspecified. C. if available. regional. HEXAMETHYLENE DIISOCYANATE. Normal butyl acetate.Hardtop AX K Comp B Page: 2/10 Section 2. Composition/information on ingredients Substance/mixture : Mixture Ingredient name Synonym CAS number % hexane.1-1 Solvent naphtha (petroleum). are listed in Section 8. Acetic acid. Store in a well-ventilated place. butyl ester. IF ON SKIN: Wash with plenty of soap and water. Hazards identification Response Storage : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Light aromatic solvent naphtha. Hexamethylene diisocyanate polymer. homopolymer Hexane. Acetic acid. Keep cool. 6-Hexamethylene diisocyanate. are classified as hazardous to health or the environment and hence require reporting in this section. HMDI.6-diisocyanato-. Butyl ester. Hexane. If experiencing respiratory symptoms: Call a POISON CENTER or physician.5-10 123-86-4 2. nbutyl ester hexamethylene diisocyanate. Isocyanic acid. national and international regulations.

belt or waistband. Indication of immediate medical attention and special treatment needed. tie. C. Eye contact : No known significant effects or critical hazards. if necessary Specific treatments : Not available. : Immediately flush eyes with plenty of water. Never give anything by mouth to an unconscious person. Maintain an open airway. If it is suspected that fumes are still present. Continue to rinse for at least 10 minutes. avoid further exposure. Notes to physician : In case of inhalation of decomposition products in a fire. In the event of any complaints or symptoms.2016. Loosen tight clothing such as a collar. symptoms may be delayed. F. If necessary. If unconscious. Clean shoes thoroughly before reuse. avoid further exposure. Get medical attention if irritation occurs. Get medical attention. Eye contact B. E. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. acute and delayed Potential acute health effects Inhalation Ingestion : Harmful if inhaled. symptoms may be delayed. Skin contact : Wash with plenty of soap and water. Over-exposure signs/symptoms Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma Ingestion : No specific data. the rescuer should wear an appropriate mask or self-contained breathing apparatus. In the event of any complaints or symptoms. Loosen tight clothing such as a collar. See toxicological information (Section 11) Date of issue/Date of revision : 16. The exposed person may need to be kept under medical surveillance for 48 hours. Maintain an open airway. call a poison center or physician. May cause respiratory irritation. If material has been swallowed and the exposed person is conscious. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If unconscious. First-aid measures A. If vomiting occurs. place in recovery position and get medical attention immediately. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If it is suspected that fumes are still present. the rescuer should wear an appropriate mask or self-contained breathing apparatus. tie. occasionally lifting the upper and lower eyelids. or wear gloves. Check for and remove any contact lenses. If not breathing. Wash contaminated clothing thoroughly with water before removing it. Skin Eyes : Adverse symptoms may include the following: irritation redness : No specific data. if breathing is irregular or if respiratory arrest occurs. Stop if the exposed person feels sick as vomiting may be dangerous. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash clothing before reuse. D. The exposed person may need to be kept under medical surveillance for 48 hours. Remove contaminated clothing and shoes. provide artificial respiration or oxygen by trained personnel. Skin contact : May cause an allergic skin reaction. Ingestion : Wash out mouth with water. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. : No known significant effects or critical hazards.Hardtop AX K Comp B Page: 3/10 Section 4. give small quantities of water to drink. belt or waistband. Most important symptoms/effects. In case of inhalation of decomposition products in a fire. May cause allergy or asthma symptoms or breathing difficulties if inhaled. place in recovery position and get medical attention immediately. Wash contaminated clothing thoroughly with water before removing it. Continue to rinse for at least 10 minutes. Get medical attention.02. the head should be kept low so that vomit does not enter the lungs. or wear gloves. . Remove dentures if any. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if adverse health effects persist or are severe.

Wash spillages into an effluent treatment plant or proceed as follows.g. Extinguishing media Suitable Not suitable B. CO₂. sand. waterways. Shut off all ignition sources. absorbent material e. Provide adequate ventilation. Approach the release from upwind. stored and processed. B. Handling and storage A. with the risk of a subsequent explosion.02. Use spark-proof tools and explosion-proof equipment. Runoff to sewer may create fire or explosion hazard. Store in original container protected from direct sunlight in a dry. Large spill : Stop leak if without risk. Do not store in unlabelled containers. This material is harmful to aquatic life with long lasting effects. : Do not use water jet. Accidental release measures A. Workers should wash hands and face before eating. smoking or flames in hazard area. In a fire or if heated. Fire-fighting measures A. protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. water spray (fog) or foam. Keep container tightly closed and sealed until ready for use. water courses.2016. vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). soil or air). earth. . No flares. Move containers from spill area. May be harmful to the environment if released in large quantities. a pressure increase will occur and the container may burst. Date of issue/Date of revision : 16. Do not touch or walk through spilt material. including any incompatibilities : Store in accordance with local regulations. Section 6. basements or confined areas. : Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. drinking and smoking. or if water-insoluble. Contaminated absorbent material may pose the same hazard as the spilt product. Remove contaminated clothing and protective equipment before entering eating areas. Keep unnecessary and unprotected personnel from entering. waterways. Section 7. sewer or drain. Prevent entry into sewers. absorb with an inert dry material and place in an appropriate waste disposal container. See also Section 8 for additional information on hygiene measures. Contain and collect spillage with noncombustible. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway. Store in a segregated and approved area. B. away from incompatible materials (see Section 10) and food and drink. Evacuate surrounding areas. cool and wellventilated area. Inform the relevant authorities if the product has caused environmental precautions pollution (sewers. Personal precautions. : Flammable liquid and vapour. Specific hazards arising from the chemical Hazardous thermal decomposition products C. Dispose of via a licensed waste disposal contractor. Use appropriate containment to avoid environmental contamination. Environmental : Avoid dispersal of spilt material and runoff and contact with soil. Special protective equipment for firefighters Special precautions for fire-fighters : Use dry chemical. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Use water spray to keep fire-exposed containers cool. Precautions for safe handling : Eating. Dispose of via a licensed waste disposal contractor. C. Use spark-proof tools and explosion-proof equipment. drinking and smoking should be prohibited in areas where this material is handled. Water polluting material. No action shall be taken involving any personal risk or without suitable training. Put on appropriate personal protective equipment.Hardtop AX K Comp B Page: 4/10 Section 5. : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Alternatively. Wear appropriate respirator when ventilation is inadequate. drains and sewers. Avoid breathing vapour or mist. Move containers from spill area. Conditions for safe storage. Separate from oxidizing materials. Eliminate all ignition sources. Dilute with water and mop up if water-soluble. Move containers from fire area if this can be done without risk. Store locked up. Methods and material for containment and cleaning up Small spill : Stop leak if without risk. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

02. The performance or effectiveness of the glove may be reduced by physical/chemical damage and poor maintenance. 8/2013). air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. TWA: 150 ppm 8 hours.034 mg/m³ 8 hours. maintenance and replacement must be followed. C.005 ppm 8 hours. TWA: 0. The instructions and information provided by the glove manufacturer on use. TWA: 710 mg/m³ 8 hours. Environmental : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. By other operations than spraying.Hardtop AX K Comp B Page: 5/10 Section 8. Control parameters Occupational exposure limits Ingredient name Exposure limits Solvent naphtha (petroleum). even when good ventilation is provided. in well ventilated areas. The user must check that the final choice of type of glove selected for handling this product is the most appropriate and takes into account the particular conditions of use. fume scrubbers. The engineering controls also need to keep gas. B. The breakthrough time must be greater than the end use time of the product. Gloves should be replaced regularly and if there is any sign of damage to the glove material. 5/2002). For right choice of glove materials. storage. Appropriate : Use only with adequate ventilation. Reference should be made to appropriate monitoring standards. . Reference to national guidance documents for methods for the determination of hazardous substances will also be required. TWA: 125 mg/m³ 8 hours. Skin protection : Personnel should wear antistatic clothing made of natural fibres or of hightemperature-resistant synthetic fibres. Use process enclosures. Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has occurred. Always ensure that gloves are free from defects and that they are stored and used correctly. Personal protective equipment Respiratory protection : Self-contained respiratory equipment must be worn by spray operator. seek advice by the supplier of chemical resistant gloves. Ministry of Labor (Republic of Korea. Use explosion-proof ventilation equipment. Eye protection : Use safety eyewear designed to protect against splash of liquids. STEL: 950 mg/m³ 15 minutes. Form: All forms Ministry of Labor (Republic of Korea. 8/2013). local exhaust ventilation or other engineering controls to keep worker exposure to airborne engineering controls contaminants below any recommended or statutory limits.2016. vapour or dust concentrations below any lower explosive limits. with focus on chemical resistance and time of penetration. Date of issue/Date of revision : 16. STEL: 200 ppm 15 minutes. TWA: 0. personal. Hand protection : There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. as included in the user's risk assessment. n-butyl acetate hexamethylene-di-isocyanate Recommended monitoring procedures : If this product contains ingredients with exposure limits. In some exposure controls cases. light aromatic Ministry of Labor (Republic of Korea. Exposure controls/personal protection A. Form: All forms TWA: 25 ppm 8 hours.

weld. braze. Melting/freezing point : Characteristic. Odour C. Decomposition temperature : Not available. Hazardous decomposition products Date of issue/Date of revision : 16. Burning rate : Not applicable. Partition coefficient: noctanol/water : Not available. Wash contaminated clothing before reusing. Uncontrolled exothermic reactions occur with amines and alcohols.08 kPa (0. Physical and chemical properties A. Chemical stability : The product is stable. P. drill. B. Vapour density N. : Not applicable. F.02. SADT : Not available. G. Relative density : Highest known value: 4 (Air = 1) (n-butyl acetate). Exposure controls/personal protection Hygiene measures : Wash hands. L. Molecular weight : Not applicable. alcohols.6°F) Burning time : Not applicable. strong alkalis.13 g/cm³ O. Possibility of hazardous reactions : Under normal conditions of storage and use. smoking and using the lavatory and at the end of the working period. : Under normal conditions of storage and use. Appearance Physical state : Liquid. amines. Contaminated work clothing should not be allowed out of the workplace.5 kPa (11.4 . : Not available. Viscosity : Kinematic (40°C): >0. Vapour pressure : Highest known value: 1. R. Do not pressurise. Stability and reactivity A. water. Conditions to avoid : Avoid all possible sources of ignition (spark or flame).8°F) (n-butyl acetate). Auto-ignition temperature : Lowest known value: 280 to 470°C (536 to 878°F) (Solvent naphtha (petroleum). Flash point : Closed cup: 47°C (116. B. . strong acids. before eating. Solubility M. Boiling point/boiling range : Lowest known value: 126°C (258.2016. Weighted average: 0. gas) J. Lower and upper explosive (flammable) limits : 1. solder. H.Hardtop AX K Comp B Page: 6/10 Section 8.5 mm2/s) S.6% K. C. Colour : Clear. Odour threshold D. Q. pH E.7. : 1. Section 10.225 cm2/s (>22. Ensure that eyewash stations and safety showers are close to the workstation location. light aromatic ).6 mm Hg) (at 20°C) : Insoluble in the following materials: cold water and hot water. : Keep away from: oxidising agents. forearms and face thoroughly after handling chemical products. Appropriate techniques should be used to remove potentially contaminated clothing. Evaporation rate : 1 (n-butyl acetate) compared with butyl acetate I. : Not available. Incompatible materials E. : Not applicable. cut. hazardous decomposition products should not be produced. Section 9. hazardous reactions will not occur. grind or expose containers to heat or sources of ignition.3 mm Hg) (at 20°C) (n-butyl acetate). D. Flammability (solid.

1.2016. Delayed and immediate effects and also chronic effects from short and long term exposure Acute toxicity Product/ingredient name Result Species Dose Exposure hexane. Toxicological information A. homopolymer Eyes . Chronic toxicity Not available.6-diisocyanato-.1 mg/l >17600 mg/kg 13100 mg/kg 4 hours - Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation hexane. 1. homopolymer n-butyl acetate LC50 Inhalation Dusts and mists LC50 Inhalation Vapour LD50 Dermal LD50 Oral Rat 18500 mg/m³ 1 hours Rat Rabbit Rat >21. a severe allergic reaction may occur when subsequently exposed to very low levels.6-diisocyanato-.Moderate irritant Rabbit - - Skin . May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin : May cause an allergic skin reaction. Oral : No known significant effects or critical hazards. Mutagenicity Not available. . a severe allergic reaction may occur when subsequently exposed to very low levels. Potential chronic health effects General Inhalation Ingestion Skin contact : Once sensitized. Reproductive toxicity Not available. : Once sensitized. Teratogenicity Not available. Fertility effects : No known significant effects or critical hazards. May cause respiratory irritation. Information on the likely routes of exposure Respiratory : Harmful if inhaled. Developmental effects : No known significant effects or critical hazards. : No known significant effects or critical hazards. Specific target organ toxicity (single exposure) Date of issue/Date of revision : 16. Carcinogenicity : No known significant effects or critical hazards. Eye contact : Once sensitized. B. : No known significant effects or critical hazards. a severe allergic reaction may occur when subsequently exposed to very low levels. Eyes : No known significant effects or critical hazards. Carcinogenicity Not available.Hardtop AX K Comp B Page: 7/10 Section 11.02. Mutagenicity : No known significant effects or critical hazards.Moderate irritant Rabbit - 100 milligrams 500 milligrams - Sensitisation Not available. Teratogenicity : No known significant effects or critical hazards.

6-diisocyanato-.2016. Ecological information A. Bioaccumulative potential D.6-diisocyanato-. light aromatic Category 3 Not applicable.02. Toxicological information Name Category Route of exposure Target organs hexane. Aspiration hazard Name Result Solvent naphtha (petroleum).02 57.7 low - 10 to 2500 high 2.3 0. .Category 1 C. Persistence/degradability Product/ingredient name Aquatic half-life Photolysis Biodegradability Solvent naphtha (petroleum). 1. 1.84 mg/l 357.Hardtop AX K Comp B Page: 8/10 Section 11. light aromatic ASPIRATION HAZARD . : No known significant effects or critical hazards. n-butyl acetate hexamethylene-di-isocyanate Category 3 Category 3 Not applicable. Date of issue/Date of revision : 16.1 mg/l Section 12.63 low low C. homopolymer Category 3 Not applicable. light aromatic n-butyl acetate hexamethylene-diisocyanate 5. Other adverse effects : Not available. ATE value Route Result Inhalation (gases) Inhalation (vapours) Inhalation (dusts and mists) 500000 ppm 11. light aromatic Acute EC50 <10 mg/l Daphnia 48 hours Acute IC50 <10 mg/l Acute LC50 <10 mg/l Algae Fish 72 hours 96 hours B. light aromatic - - Not readily Product/ingredient name LogPow BCF Potential hexane. Not applicable. Solvent naphtha (petroleum). homopolymer Solvent naphtha (petroleum). Respiratory tract irritation Respiratory tract irritation and Narcotic effects Narcotic effects Respiratory tract irritation Specific target organ toxicity (repeated exposure) Not available.54 367. Product/ingredient name Result Species Exposure Solvent naphtha (petroleum). Aquatic and terrestrial toxicity Ecotoxicity : This material is harmful to aquatic life with long lasting effects. Mobility in soil Soil/water partition coefficient (KOC) E.

Avoid dispersal of spilt material and runoff and contact with soil.Hardtop AX K Comp B Page: 9/10 Section 13. Transport information Transport within user’s premises: always transport in closed containers that are upright and secure. Section 14. Waste packaging should be recycled. Dangerous Materials : Class: Class 4 . Disposal considerations A. International transport regulations Proper shipping name : Resin solution.Flammable Liquid Item: 4. B. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.02. C. Transport in accordance with ADR/RID. Class 2 petroleums . waterways. ISHA Article 38 : None of the components are listed. Do not cut. Regulation according to ISHA ISHA Article 37 : None of the components are listed. S-E Marine pollutant: No. Korea inventory : All components are listed or exempted. Disposal of this product. : This material and its container must be disposed of in a safe way. . drains and sewers. TCCA Article 17 (TRI) : None of the components are listed. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. IMDG/IMO and ICAO/IATA and national regulation. Section 15. Incineration or landfill should only be considered when recycling is not feasible. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Empty containers or liners may retain some product residues. Disposal precautions : The generation of waste should be avoided or minimised wherever possible. Ensure that persons transporting the product know what to do in the event of an accident or spillage.Water-insoluble liquid Safety Management Act Threshold: 1000 L Danger category: III Signal word: Contact with sources of ignition prohibited Date of issue/Date of revision : 16. Disposal methods B. TCCA Article 32 (Banned) : None of the components are listed. weld or grind used containers unless they have been cleaned thoroughly internally. solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Regulatory information A. flammable UN Number : 1866 Class : 3 Packing group Label : III : Additional information ADR / RID IMDG : Tunnel restriction code: (D/E) Hazard identification number: 30 : Emergency schedules (EmS): F-E.2016. TCCA Article 32 (Restricted) : None of the components are listed. Regulation according to TCCA TCCA Toxic chemicals : Not applicable TCCA Observational chemicals : None of the components are listed.

References : Not available. national and international regulations. The product is not to be used for purposes other than those specified under section 1 without first obtaining written handling instructions. Version : 5 Date of printing : 16. Safety.Hardtop AX K Comp B Page: 10/10 Section 15. The information in this SDS is meant to be a description of the safety requirements for our product. C. B. Date of issue/Date of revision : 16. It is not to be considered a guarantee of the product's properties. Regulatory information D. Wastes regulation : Dispose of contents and container in accordance with all local.2016. Date of issue/Date of revision : 16. United States inventory (TSCA 8b) : All components are listed or exempted. health and environmental regulations specific for the product : No known specific national and/or regional regulations applicable to this product (including its ingredients). regional.02.2016. Japan inventory : Not determined.2016. Section 16. . Regulation according to other foreign laws Europe inventory : All components are listed or exempted.02. D. Other information A. Notice to reader The information in this SDS is based on the present state of our knowledge and on current laws.02. Other Indicates information that has changed from previously issued version. It is always the responsibility of the user to take all necessary steps to fulfil the demands set out in the local rules and legislation. E.