PROBLEM BAB 6

6.1 In a water solution in equilibrium with PbCl2 the concentration of Pb2+ and

Cl- are

related by the expression:

(conc. Pb2+) (conc. Cl-)2 = 1.7 x 10-5
a. If the concentration of Cl- is 1.0 x 10-2, what is the concretation of Pb2+....
b. What is the concentration of Cl- when that of Pb2+ is 1.0 x 10-1...
c. What is the concentration of Pb2+ in a solution in which:
(conc. Cl-) = 2 (conc. Pb2+)...
Answer:
a. (conc. Pb2+) (conc. Cl-)2 = 1.7 x 10-5
(conc. Pb2+). 1.0 x 10-2 = 1.7 x 10-5
(conc. Pb2+) =

= 0,17
b. (conc. Pb2+) (conc. Cl-)2 = 1.7 x 10-5
1,0 x 10-1 . (conc. Cl-)2 = 1.7 x 10-5
(conc. Cl-)2 = 1,3 x 10-2

c. (conc. Pb2+) (2 conc Pb2+)2 = 1.7 x 10-5

(conc. Pb2+) = 1,6 x 10-2

Annisa Rayhanny Jannah

6.2 The freezing point lowering of a water solution is given by the equation:

f.p.l =

where M is moleculer weight, calculate M if a solution containing 10,0 g of solute in

90,0 g of water freezes at -0,372
Answer:

M=

6.3 The mole fraction X2, of a solute in water solution is related to its molality, m, by the
equation:
X2 =

Answer:
m = m X2 + 55,6.X2

m=

6.4 For the reaction: 2HI(g)

I2(g) + H2(g)

The following relation holds at equilibrium:

= 0,20

If ine start with a concentration of HI of 0,50 mole/liters, what is the equilibrium

concentration of H2? (note that every mole of H2 formed, one mole of if I2 is formed
and two moles of HI are consumed)

Annisa Rayhanny Jannah

Answer:

X = 0,12
6.5 in water solution saturated with both NiS and H2S the following relationship exist:
(conc. Ni2+)(conc. S2-) = 1 x 10-22
(conc. H+)2 (conc. S2-) = 1 x 10-23
Answer:
Conc. S2- =

Conc. Ni2+ =

6.6 for a water solution of accetic acid:

Calculate the concentration of H+ when the concentration of Ac- is five times that of
Hac
Answer:
(Conc. H+) x 5 = 1,80 x 10-5
Conc. H+ = 3,60 x 10-6

Annisa Rayhanny Jannah

6.7 For the reaction: HF

H+ + F- at equilibrium:

If the original concentration of HF is 1,0 M:

a. Calculate the equilibrium concentration of H+ making the approximation 1,0

b. Estimate the error involved in making this approxiamation

c. Calculate the equilibrium concentration of H+, using quadratic formula
Answer:
a.

X = 2,6 x 10-2
b. % error = 50
= 1,3 %
c.

7,0

Annisa Rayhanny Jannah

6.8 For the reaction: NH3 + H2O

NH4+ + OH-

At equilibrium:

If the original concentration of NH3 is 0,0100 M:

a. Calculate the equilibrium concentration of NH4+, neglecting the x in the
demonimator
b. Use the value of concentration NH4+ calculated in part (a) to carry out a second
approximation to obtain a more accurate value
c. Estimate the percent error in the values calculated in part (a) (b)
Answer:

a.

b.

c. Percent error in (a) = 50 (1,8 x 10-3)1/2 = 2,1%

d. Percent error in (b) = 0,021 x 0,021 = 0,00044 = 0,044%

Annisa Rayhanny Jannah

6.9 For the reaction : H+ + NH3

NH4+

At equilibrium:
If one starts with a solution in which the concentration of both H+ and NH3 are 1,0
M, calculate the concentration of H+ at equilibrium...
Answer:

conc.

6.10 For the reaction: 2SO2(g)+O2(g)

2SO3(g)

At equilibrium:

If the original concentration of SO2 and O2 are 2,0 and 1,0 mole/liters respectively ,
what is the concentration of SO3 at equilibrium? Note that for every mole SO3
formed, one mole of SO2 and

mole of O2 are consumed.

Answer:

Annisa Rayhanny Jannah

Conc. SO3= 2,0

Annisa Rayhanny Jannah