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DOI 10.1007/s12393-012-9049-9
SHORT COMMUNICATION
Received: 3 November 2011 / Accepted: 15 January 2012 / Published online: 15 February 2012
Springer Science+Business Media, LLC 2012
123
108
Tg
T
IT
TRT
Tref
t
Time zero
tg
z
Introduction
Thermal processing is an important method of food
preservation used in the manufacture of shelf-stable
sterilized foods. The basic function of a thermal process is
to inactivate microorganisms to produce microbiologically
safe products in sealed containers by applying heat
treatment at temperatures well above the ambient boiling
point of water in pressurized steam retorts (autoclaves).
Excessive heat treatment should be avoided because it is
detrimental to food quality and underutilizes the capacity
of the plant.
The first procedure to calculate thermal processes was
developed by Bigelow [5] in the early part of the 20th
century and is usually known as the General Method. The
General Method makes direct use of the timetemperature
history at the coldest point within a sealed food container to
obtain the lethality value of a thermal process. The lack of
programmable calculators or personal computers until the
latter part of the 20th century made this method very timeconsuming, tedious and impractical for most routine
applications, and it soon gave way to methods offering
shortcuts. In response to this need, a semi-analytic method
for thermal processing calculations was developed and
proposed to the scientific community by Ball [2]. This
method is the well-known Balls Formula Method, and it
works in a different way from the General Method. Balls
Method makes use of the difference between retort and
cold spot temperatures, which decays exponentially over
process time, after an initial lag period. Therefore, a semilogarithmic plot of the temperature difference over time
(after the initial lag) appears as a straight line that can be
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109
Ztg
10
TTref
z
dt
Zt
10
TTref
z
dt
tg
Where: j TRTTA
TRTIT
Equation 3 has been critically analyzed by Merson et al.
[13]. As was shown by Datta [7], the latter expression is
valid not only for finite cylinders but also for arbitrary
shapes (rectangular, oval shape, infinite slab, etc.). The
main limitation is that for food heated by conduction, the
expression is only valid for heating times beyond the initial
lag period (when the Fourier number [ 0.6). Although in
the majority of sterilized food products, the heat transfer
process is not strictly conduction or forced convection, as
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110
123
111
Standard contribution of
come-up time (42%) introduced
in Balls Formula Method
Standard contribution of
come-up time (42%) introduced
in Balls Formula Method
% of CUT
Table 2 Prediction of
operators process time (Pt)
using different zero time
locations for an experimental
run of tuna fish product
jh
fh
B (min)
Pt (min)
100
55.5
2.33
92.0
82.0
70
55.5
2.06
89.0
82.0
42a
20
55.5
55.5
1.84
1.67
86.2
84.0
82.0
82.0
55.5
1.51
82.0
82.0
100
55.4
2.14
97.6
87.6
70
55.4
1.89
94.6
87.6
42a
55.4
1.68
91.8
87.6
20
55.4
1.53
89.6
87.6
55.4
1.41
87.6
87.6
100
55.4
2.41
100.6
90.6
70
55.4
2.13
97.6
90.6
42a
55.4
1.90
94.8
90.6
20
55.4
1.73
92.6
90.6
55.4
1.59
90.6
90.6
CUT (min)
% of CUT
fh
jh
B (min)
Pt (min)
29
100
70
30.9
30.9
4.43
2.32
81.0
72.3
52.0
52.0
42a
30.9
1.26
64.2
52.0
20
30.9
0.79
57.8
52.0
30.9
0.51
52.0
52.0
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112
Table 3 Prediction of
operators process time (Pt)
using different time zero
locations for both a simulated
run and an experimental run of a
retortable pouch
% of CUT
Simulated CUT 10 (min)
Standard contribution of
come-up time (42%) introduced
in Balls Formula Method
fh
jh
B (min)
Pt (min)
100
12.4
3.73
25.0
15.0
70
12.4
2.14
22.0
15.0
42a
12.4
1.27
19.2
15.0
20
12.4
0.85
17.0
15.0
12.4
0.58
15.0
15.0
100
6.6
2.47
24.0
18.0
70
6.6
1.32
22.2
18.0
42a
6.6
0.74
20.5
18.0
20
6.6
0.47
19.2
18.0
6.6
0.31
18.0
18.0
Table 4 Calculations of heating lethality (FHeating) and Tg through Balls Formula Method and General Method for a wide variety of processes
with fh ranging from *20 to *160 min and CUT length from 5 to 30 min
fh (min)
CUT (min)
5
21.6
55
93
159.6
10
20
30
4.2a
117.7b
3.8
117.6
4.2
117.6
3.7
117.5
4.2
117.7d
3.8
117.5
4.2
117.7
3.7
117.5
3.1
114.7
3.2
114.8
3.1
114.7
3.1
114.7
3.1
114.7
3.2
114.8
3.1
114.7
3.1
114.7
3.0
113.2
3.1
113.5
3.1
113.6
3.1
113.5
3.0
113.4
3.1
113.5
3.1
113.6
3.1
113.5
2.1
110.3
2.0
110.3
2.0
110.2
2.1
110.3
2.1
110.3
2.0
110.3
2.0
110.3
2.1
110.3
a and b are the FHeating and Tg calculated by the Balls Formula Method and c and d the respective values calculated by the General Method. The
results in each cell follow the same left-to-right a, b, c, d sequence shown in upper left for CUT 5 and fh 21.6
123
Final Remarks
The prediction of operators process time (Pt) by Balls
Formula Method was the same regardless of where time
zero was placed within the come-up time (or the CUT
contribution). This result is due to the linear regression of
heat penetration data along the straight-line portion of the
semi-log heat penetration curve, which produces a mathematical expression (Balls Formula Method) that predicts
the same timetemperature history independent of the time
zero location. In addition, given that high correlations were
obtained in all cases, the calculation of the F-value from
the regressed data (Balls procedure) was essentially
identical to the F-value calculated by the General Method,
which is based directly on the experimental data points. It
has also been shown that temperaturetime histories predicted by Eq. 3 always have a high correlation (implicitly
confirmed by the results of Table 4) with experimental data
points, independent of the CUT shape and length, meaning
that the F-value at the end of heating is well estimated.
Finally, it was concluded that inaccuracies in Balls
Formula Method could be attributed in almost 100% of
cases to the cooling calculations.
Acknowledgments We kindly appreciate the contribution made by
Dr. Alik Abakarov (Universidad Politecnica de Madrid, Spain).
Authors Ricardo Simpson and Sergio Almonacid are grateful for the
financial support provided by CONICYT through FONDECYT project number 1090689.
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